Relation of short-range and long-range lithium ion dynamics in glass-ceramics: Insights from Li-7 NMR field-cycling and field-gradient studies

We use various Li-7 NMR methods to investigate lithium ion dynamics in 70Li(2)S-30P(2)S(5) glass and glass-ceramic obtained from this glass after heat treatment. We employ Li-7 spin-lattice relaxometry, including field-cycling measurements, and line-shape analysis to investigate short-range ion jumps as well as Li-7 field-gradient approaches to characterize long-range ion diffusion. The results show that ceramization substantially enhances the lithium ion mobility on all length scales. For the 70Li(2)S-30P(2)S(5) glass-ceramic, no evidence is found that bimodal dynamics result from different ion mobilities in glassy and crystalline regions of this sample. Rather, Li-7 field-cycling relaxometry shows that dynamic susceptibilities in broad frequency and temperature ranges can be described by thermally activated jumps governed by a Gaussian distribution of activation energies g( E-a) with temperature-independent mean value E-m = 0.43 eV and standard deviation sigma = 0.07 eV. Moreover, use of this distribution allows us to rationalize Li-7 line-shape results for the local ion jumps. In addition, this information about short-range ion dynamics further explains Li-7 field-gradient results for long-range ion diffusion. In particular, we quantitatively show that, consistent with our experimental results, the temperature dependence of the self-diffusion coefficient D is not described by the mean activation energy E-m of the local ion jumps, but by a significantly smaller apparent value whenever the distribution of correlation times G( log tau) of the jump motion derives from an invariant distribution of activation energies and, hence, continuously broadens upon cooling. This effect occurs because the harmonic mean, which determines the results of diffusivity or also conductivity studies, continuously separates from the peak position of G( log tau) when the width of this distribution increases

Environmental Federalism in the European Union and the United States

The United States (US) and the European Union (EU) are federal systems in which the responsibility for environmental policy-making is divided or shared between the central government and the (member) states. The attribution of decision-making power has important policy implications. This chapter compares the role of central and local authorities in the US and the EU in formulating environmental regulations in three areas: automotive emissions for health related (criteria) pollutants, packaging waste, and global climate change. Automotive emissions are relatively centralised in both political systems. In the cases of packaging waste and global climate change, regulatory policy-making is shared in the EU, but is primarily the responsibility of local governments in the US. Thus, in some important areas, regulatory policy-making is more centralised in the EU. The most important role local governments play in the regulatory process is to help diffuse stringent local standards through more centralised regulations, a dynamic which has become recently become more important in the EU than in the US.

Observations of Chemically Enriched QSO Absorbers near z ~ 2.3 Galaxies: Galaxy-Formation Feedback Signatures in the IGM

We present a study of galaxies and intergalactic gas toward the z=2.73 quasar HS1700+6416, to explore the effects of galaxy formation feedback on the IGM. Our observations and ionization simulations indicate that the volume within 100-200 h_71^{-1} physical kpc of high-redshift galaxies contains very small, dense, and metal-rich absorption-line regions. These systems often contain shock-heated gas seen in OVI, and may exhibit [Si/C] abundance enhancements suggestive of Type II supernova enrichment. We argue that the absorbers resemble thin sheets or bubbles, whose physical properties can be explained with a simple model of radiatively efficient shocks propegating through the IGM. Their high metallicities suggest that these shocks are being expelled from--rather than falling into--star forming galaxies. There is a dropoff in the IGM gas density at galaxy impact parameters beyond ~300 physical kpc that may trace boundaries of gas structures where the galaxies reside. The local heavy-element enhancement covers 100-200 kpc; beyond this the observed abundances blend into the general IGM. Supernova-driven winds or dynamical stripping of interstellar gas appears to affect the IGM near massive galaxies, even at R>~100 kpc. However, these feedback systems represent only a few percent of the Lya forest mass at z~2.5. Their mass could be larger if the more numerous metal-poor CIV systems at >~200 kpc are tepid remnants of very powerful winds. Based on present observations it is not clear that this scenario is to be favored over one involving pre-enrichment by smaller galaxies at z>~6.Comment: Accepted for publication in the Astrophysical Journal. 26 pages emulateapj, incl. 5 pages tables, 15 figure

The Mass Inflow Rate in the Barred Galaxy NGC 1530

Mass inflow in barred galaxies has been invoked to account for a wide variety of phenomena, but until now direct evidence for inflow has been lacking. We present Fabry-Perot H-alpha observations of the barred spiral galaxy NGC 1530 from which we determine velocities of the ionized gas for the entire region swept by the bar. We compare the velocity field to models of gas flow in barred spirals and show that it is well reproduced by ideal gas hydrodynamic models. Inspection of the models and observations reveals that gas entering the bar dust lanes streams directly down the dust lanes toward the 2 kpc radius nuclear ring. The models predict that approximately 20% of the gas flowing down the dust lane enters the nuclear ring; the remaining gas sprays around the ring to the other bar dust lane. The fraction of the gas entering the ring is relatively insensitive to the shape or size of the bar. Our observations of the velocity field and dust optical depth yield a mass inflow rate into the nuclear ring of 1 solar mass per year.Comment: 13 pages, 3 figures, aastex 4.0, accepted for publication in Ap J Letter

Mobile satellite propagation measurements and modeling: A review of results for systems engineers

An overview of Mobile Satellite Service (MSS) propagation measurements and modeling is intended as a summary of current results. While such research is on-going, the simple models presented here should be useful to systems engineers. A complete summary of propagation experiments with literature references is also included

Inner Molecular Rings in Barred Galaxies: BIMA SONG CO Observations

Although inner star-forming rings are common in optical images of barred spiral galaxies, observational evidence for the accompanying molecular gas has been scarce. In this paper we present images of molecular inner rings, traced using the CO (1-0) emission line, from the Berkeley-Illinois-Maryland-Association Survey of Nearby Galaxies (BIMA SONG). We detect inner ring CO emission from all five SONG barred galaxies classified as inner ring (type (r)). We also examine the seven SONG barred galaxies classified as inner spiral (type (s)); in one of these, NGC 3627, we find morphological and kinematic evidence for a molecular inner ring. Inner ring galaxies have been classified as such based on optical images, which emphasize recent star formation. We consider the possibility that there may exist inner rings in which star formation efficiency is not enhanced. However, we find that in NGC 3627 the inner ring star formation efficiency is enhanced relative to most other regions in that galaxy. We note that the SONG (r) galaxies have a paucity of CO and H alpha emission interior to the inner ring (except near the nucleus), while NGC 3627 has relatively bright bar CO and H alpha emission; we suggest that galaxies with inner rings such as NGC 3627 may be misclassified if there are significant amounts of gas and star formation in the bar.Comment: To be published in the Astrophysical Journal, July 2002 A version of the paper with full resolution figures is available at: http://www.astro.umd.edu/~mregan/ms.ps.g

Persistent Borna Disease Virus (BDV) infection activates microglia prior to a detectable loss of granule cells in the hippocampus

Neonatal Borna Disease Virus (BDV) infection in rats leads to a neuronal loss in the cortex, hippocampus and cerebellum. Since BDV is a non-lytic infection in vitro, it has been suggested that activated microglia could contribute to neuronal damage. It is also conceivable that BDV-induced cell death triggers activation of microglia to remove cell debris. Although an overall temporal association between neuronal loss and microgliosis has been demonstrated in BDV-infected rats, it remains unclear if microgliosis precedes or results from neuronal damage. We investigated the timing of microglia activation and neuronal elimination in the dentate gyrus (DG) of the hippocampus. We found a significant increase in the number of ED1+ microglia cells as early as 10 days post infection (dpi) while a detectable loss of granule cells of the DG was not seen until 30 dpi. The data demonstrate for the first time that a non-lytic persistent virus infection of neurons activates microglia long before any measurable neuronal loss

Properties of entangled photon pairs generated in one-dimensional nonlinear photonic-band-gap structures

We have developed a rigorous quantum model of spontaneous parametric down-conversion in a nonlinear 1D photonic-band-gap structure based upon expansion of the field into monochromatic plane waves. The model provides a two-photon amplitude of a created photon pair. The spectra of the signal and idler fields, their intensity profiles in the time domain, as well as the coincidence-count interference pattern in a Hong-Ou-Mandel interferometer are determined both for cw and pulsed pumping regimes in terms of the two-photon amplitude. A broad range of parameters characterizing the emitted down-converted fields can be used. As an example, a structure composed of 49 layers of GaN/AlN is analyzed as a suitable source of photon pairs having high efficiency.Comment: 14 pages, 23 figure