Spin-Dependent Phenomena in Semiconductor Micro-and Nanoparticles - From Fundamentals to Applications

The present overview of spin-dependent phenomena in nonmagnetic semiconductor microparticles (MPs) and nanoparticles (NPs) with interacting nuclear and electron spins is aimed at covering a gap between the basic properties of spin behavior in solid-state systems and a tremendous growth of the experimental results on biomedical applications of those particles. The first part of the review represents modern achievements of spin-dependent phenomena in the bulk semiconductors from the theory of optical spin orientation under indirect optical injection of carriers and spins in the bulk crystalline silicon (c-Si)—via numerous insightful findings in the realm of characterization and control through the spin polarization—to the design and verification of nuclear spin hyperpolarization in semiconductor MPs and NPs for magnetic resonance imaging (MRI) diagnostics. The second part of the review is focused on the electron spin-dependent phenomena in Si-based nanostructures, including the photosensitized generation of singlet oxygen in porous Si and design of Si NPs with unpaired electron spins as prospective contrast agents in MRI. The experimental results are analyzed by considering both the quantum mechanical approach and several phenomenological models for the spin behavior in semiconductor/molecular systems. Advancements and perspectives of the biomedical applications of spin-dependent properties of Si NPs for diagnostics and therapy of cancer are discussed

Phonon spectrum engineering in rolled-up micro- and nano-architectures

We report on a possibility of efficient engineering of the acoustic phonon energy spectrum in multishell tubular structures produced by a novel high-tech method of self-organization of micro- and nano-architectures. The strain-driven roll-up procedure paved the way for novel classes of metamaterials such as single semiconductor radial micro- and nano-crystals and multi-layer spiral micro- and nano-superlattices. The acoustic phonon dispersion is determined by solving the equations of elastodynamics for InAs and GaAs material systems. It is shown that the number of shells is an important control parameter of the phonon dispersion together with the structure dimensions and acoustic impedance mismatch between the superlattice layers. The obtained results suggest that rolled up nano-architectures are promising for thermoelectric applications owing to a possibility of significant reduction of the thermal conductivity without degradation of the electronic transport

Phonon Spectrum Engineering in Rolled-up Nano- and Micro-Architectures

We report on a possibility of efficient engineering of the acoustic phonon energy spectrum in multishell tubular structures produced by a novel high-tech method of self-organization of nano- and micro-architectures. The strain-driven roll-up procedure paved the way for novel classes of metamaterials such as single semiconductor radial micro- and nano-crystals and multi-layer spiral micro- and nano-superlattices. The acoustic phonon dispersion is determined by solving the equations of elastodynamics for InAs and GaAs material systems. It is shown that the number of shells is an important control parameter of the phonon dispersion together with the structure dimensions and acoustic impedance mismatch between the superlattice layers. The obtained results suggest that rolled up nano-architectures have potential for thermoelectric applications owing to a possibility of significant reduction of the thermal conductivity without degradation of the electronic transport.Comment: 17 pages; 8 figure

Photoluminescence of tetrahedral quantum-dot quantum wells

Taking into account the tetrahedral shape of a quantum dot quantum well (QDQW) when describing excitonic states, phonon modes and the exciton-phonon interaction in the structure, we obtain within a non-adiabatic approach a quantitative interpretation of the photoluminescence spectrum of a single CdS/HgS/CdS QDQW. We find that the exciton ground state in a tetrahedral QDQW is bright, in contrast to the dark ground state for a spherical QDQW. The position of the phonon peaks in the photoluminescence spectrum is attributed to interface optical phonons. We also show that the experimental value of the Huang-Rhys parameter can be obtained only within the nonadiabatic theory of phonon-assisted transitions.Comment: 4 pages, 4 figures, E-mail addresses: [email protected], [email protected], [email protected], [email protected], to be published in Phys. Rev. Letter

Steering of Vortices by Magnetic Field Tilting in Open Superconductor Nanotubes

In planar superconductor thin films, the places of nucleation and arrangements of moving vortices are determined by structural defects. However, various applications of superconductors require reconfigurable steering of fluxons, which is hard to realize with geometrically predefined vortex pinning landscapes. Here, on the basis of the time-dependent Ginzburg–Landau equation, we present an approach for the steering of vortex chains and vortex jets in superconductor nanotubes containing a slit. The idea is based on the tilting of the magnetic field (Formula presented.) at an angle (Formula presented.) in the plane perpendicular to the axis of a nanotube carrying an azimuthal transport current. Namely, while at (Formula presented.), vortices move paraxially in opposite directions within each half-tube; an increase in (Formula presented.) displaces the areas with the close-to-maximum normal component (Formula presented.) to the close(opposite)-to-slit regions, giving rise to descending (ascending) branches in the induced-voltage frequency spectrum (Formula presented.). At lower B values, upon reaching the critical angle (Formula presented.), the close-to-slit vortex chains disappear, yielding (Formula presented.) of the (Formula presented.) type ((Formula presented.) : an integer; (Formula presented.) : the vortex nucleation frequency). At higher B values, (Formula presented.) is largely blurry because of multifurcations of vortex trajectories, leading to the coexistence of a vortex jet with two vortex chains at (Formula presented.). In addition to prospects for the tuning of GHz-frequency spectra and the steering of vortices as information bits, our findings lay the foundation for on-demand tuning of vortex arrangements in 3D superconductor membranes in tilted magnetic fields

Steering of vortices by magnetic-field tilting in superconductor nanotubes

In planar superconductor thin films, the places of nucleation and arrangements of moving vortices are determined by structural defects. However, various applications of superconductors require reconfigurable steering of fluxons, which is hard to realize with geometrically predefined vortex pinning landscapes. Here, on the basis of the time-dependent Ginzburg-Landau equation, we present an approach for steering of vortex chains and vortex jets in superconductor nanotubes containing a slit. The idea is based on tilting of the magnetic field $\mathbf{B}$ at an angle $\alpha$ in the plane perpendicular to the axis of a nanotube carrying an azimuthal transport current. Namely, while at $\alpha=0^\circ$ vortices move paraxially in opposite directions within each half-tube, an increase of $\alpha$ displaces the areas with the close-to-maximum normal component $|B_\mathrm{n}|$ to the close(opposite)-to-slit regions, giving rise to descending (ascending) branches in the induced-voltage frequency spectrum $f_\mathrm{U}(\alpha)$. At lower $B$, upon reaching the critical angle $\alpha_\mathrm{c}$, close-to-slit vortex chains disappear, yielding $f_\mathrm{U}$ of the $nf_1$-type ($n\geq1$: an integer; $f_1$: vortex nucleation frequency). At higher $B$, $f_\mathrm{U}$ is largely blurry because of multifurcations of vortex trajectories, leading to the coexistence of a vortex jet with two vortex chains at $\alpha=90^\circ$. In addition to prospects for tuning of GHz-frequency spectra and steering of vortices as information bits, our findings lay foundations for on-demand tuning of vortex arrangements in 3D superconductor membranes in tilted magnetic fields.Comment: 4 pages, 4 figure

Small Scale Propulsion: How Systematic Studies of Low Reynolds Number Physics Can Bring Micro/Nanomachines to New Horizons

Micromachines are small-scale human-made machines with remarkable potential for medical treatments, microrobotics and environmental remediation applications. However, meaningful real-world applications are missing. This is mainly caused by their small size leading to unintuitive physics of motion. Motivated by the aim of understanding the fundamental physics at the micrometer scale and thereby overcoming resulting challenges, we discuss the importance of robust models supported by experimental data. Our previously performed study on the switching in propulsion mechanisms for conical tubular catalytic micromotors will be summarized and serve as an example for discussion. We emphasize on the need for systematic experimental studies to enable the design of highly application-oriented micromachines, which can be translated into real-world scenarios

Topological transitions in ac/dc-driven superconductor nanotubes

Extending of nanostructures into the third dimension has become a major research avenue in condensed-matter physics, because of geometry- and topology-induced phenomena. In this regard, superconductor 3D nanoarchitectures feature magnetic field inhomogeneity, non-trivial topology of Meissner currents and complex dynamics of topological defects. Here, we investigate theoretically topological transitions in the dynamics of vortices and slips of the phase of the order parameter in open superconductor nanotubes under a modulated transport current. Relying upon the time-dependent Ginzburg–Landau equation, we reveal two distinct voltage regimes when (i) a dominant part of the tube is in either the normal or superconducting state and (ii) a complex interplay between vortices, phase-slip regions and screening currents determines a rich FFT voltage spectrum. Our findings unveil novel dynamical states in superconductor open nanotubes, such as paraxial and azimuthal phase-slip regions, their branching and coexistence with vortices, and allow for control of these states by superimposed dc and ac current stimuli

New magneto-polaron resonances in a monolayer of a transition metal dichalcogenide

Transition metal dichalcogenide (TMD) semiconductors are two-dimensional materials with great potential for the future of nano-optics and nano-optoelectronics as well as the rich and exciting development of basic research. The influence of an external magnetic field on a TMD monolayer raises a new question: to unveil the behavior of the magneto-polaron resonances (MPRs) associated with the phonon symmetry inherent in the system. It is shown that the renormalized Landau energy levels are modified by the interplay of the long-range Pekar–Fröhlich (PF) and short-range deformation potential (DP) interactions. This leads to a new series of MPRs involving the optical phonons at the center of the Brillouin zone. The coupling of the two Landau levels with the LO and A1 optical phonon modes provokes resonant splittings of double avoided-crossing levels giving rise to three excitation branches. This effect appears as bigger energy gaps at the anticrossing points in the renormalized Landau levels. To explore the interplay between the MPRs, the electron-phonon interactions (PF and DP) and the couplings between adjacent Landau levels, a full Green’s function treatment for the evaluation of the energy and its life-time broadening is developed. A generalization of the two-level approach is performed for the description of the new MPR branches. The obtained results are a guideline for the magneto-optical experiments in TMDs, where three MPR peaks should be observable