Luminescent coordination polymers based on Ca²⁺ and octahedral cluster anions [{M₆Clⁱ₈}Clᵃ₆}²⁻ (M = Mo, W) : synthesis and thermal stability studies

Luminescent coordination polymers (CPs) based of inexpensive stable precursors are attractive materials for applications. Here we report the synthesis and evaluation of the stability and photophysical characteristics of the first examples of phosphorescent CPs based on octahedral molybdenum and tungsten cluster anions. Specifically 1D CP trans-[{Ca(OPPh₃)₄}{{M₆Clⁱ₈}Clᵃ₆}]∞ (M = Mo, W) can be obtained either directly at increased temperature or via intermediate phases [cis-Ca(OPPh₃)₄(H₂O)₂][{M₆Clⁱ₈}Clᵃ₆]∙2CH₃CN that are stable at room-temperature, but convert to the titled CP at temperatures above 100 °C

IgG4-RELATED DISEASE. CLINICAL NOTES

IgG4-related diseases are a new nosological entity that encompasses a few previously known diseases. IgG4-related systemic disease is diagnosed if two or more affected organs are detected. This group of diseases has two similar signs: serological (elevated serum IgG4 subclass concentrations) and histological (organ and tissue infiltration from plasmo-cytes secreting IgG4, and eosinophils, and the development of fibrosclerosis and phlebitis obliterans). The paper describes two cases. In one case, a multisystemic disease was observed virtually at its onset whereas in the other this lesion was diagnosed several years after the natural course of the disease

Resource conservation as a condition for preserving non-renewable natural capital

The article overviews the problem of slowing down the rates of natural non-renewable sources depletion in the process of resources development. The goal of the presented research is to justify the implementation of the most appropriate method of carrying out a complete resource development process by incorporating the mining and raw material extraction facilities available in the country. The study provides scientific evidence of a large-scale harmful impact caused by the raw materials development to all the elements of the biosphere and their interdependence. The presented research also demonstrates that solving the problem of resource-conservation is a first-hand priority due to the fact that there is in a close interconnection between the levels of environmental pollution and the levels of natural resources extraction. The solution to the problem of natural resources conservation is based on the concept of implementing environmentally clean technology (ECT); this technology gives an opportunity for developing a concept of the best available technology (BAT) and the concept of a closed-loop supply, the latter of which has become widely-used as a form of circular economy. The authors of the article have also suggested a systematic range of techniques aimed at extracting following resources in full capacity: commercial resources, non¬commercial resources, overburden rocks and man-made mineral formations. The authors of the article suggest the necessity for enlarging the scope of available mineral resources by ensuring governmental support and developing small deposits, first and foremost focusing on the territories with a developed infrastructure and which had previously been developed. The ideas presented in the article express and support the necessity for prospective implementation of the mining factories waste products as a reserve for mineral and raw materials resources; as well as the necessity for increasing their production rates from the circular economy perspective. Some measures which would help to accelerate this process are: improving the legislative system, developing mechanisms for economic incentive and providing various forms of state-business co¬operation

Mechanochemical production of lignin-containing powder fuels from biotechnical industry waste: A review

In biotechnological processing of plant raw materials, carbohydrates that are soluble and accessible for microorganisms are the only usable components. The lignin-rich part of the plant raw materials usually ends up in the waste. Lignin transferred into water suspensions cannot be used efficiently as a fuel. In this review, a new processing scheme of plant raw materials is presented, which includes mechanochemical treatment of the plant raw materials and separation of the powder product into particles of lignified and non-lignified tissues rich in lignin and cellulose, respectively. The cellulose-rich powders can then be used in biotechnological processes. Lignin-rich powder aerodynamically separated using cyclone-type apparatus can be used as a powder fuel to satisfy the needs of the main biotechnological plant in heat and steam

The ‘Edge Effect’ Phenomenon in Plants: Morphological, Biochemical and Mineral Characteristics of Border Tissues

The ‘edge’ effect is considered one of the fundamental ecological phenomena essential for maintaining ecosystem integrity. The properties of plant outer tissues (root, tuber, bulb and fruit peel, tree and shrub bark, leaf and stem trichomes) mimic to a great extent the ‘edge’ effect properties of different ecosystems, which suggests the possibility of the ‘edge’ effect being applicable to individual plant organisms. The most important characteristics of plant border tissues are intensive oxidant stress, high variability and biodiversity of protection mechanisms and high adsorption capacity. Wide variations in morphological, biochemical and mineral components of border tissues play an important role in the characteristics of plant adaptability values, storage duration of roots, fruit, tubers and bulbs, and the diversity of outer tissue practical application. The significance of outer tissue antioxidant status and the accumulation of polyphenols, essential oil, lipids and minerals, and the artificial improvement of such accumulation is described in connection with plant tolerance to unfavorable environmental conditions. Methods of plant ‘edge’ effect utilization in agricultural crop breeding, production of specific preparations with powerful antioxidant value and green nanoparticle synthesis of different elements have been developed. Extending the ‘edge’ effect phenomenon from ecosystems to individual organisms is of fundamental importance in agriculture, pharmacology, food industry and wastewater treatment processes