8 research outputs found
Selective formation of formamidines, carbodiimides and formimidates from isocyanide complexes of Mn(i) mediated by Ag2O
No full textHalf-sandwich iron(II) complexes with protic acyclic diaminocarbene ligands: Synthesis, deprotonation and metalation reactions
No full textBase-Promoted Transmetalation Reactions of Protic N-Heterocyclic Carbenes and Acyclic Diamino Carbenes from MnI to AuI: A Mechanistic Study
No full textD+-pi-A(-) charge-transfer molecules based on tricyanoquinodimethane and diphosphine metal complexes
No full textSynthesis and Se-Se Bond Breaking of Polyselenides Containing Pendant Diphosphine Complexes of Manganese(I)(+)
No full textReaction of [Mn(CO)4{(PPh2)2CH}] (1) with half an equivalent of dipiperidinotetraselane affords the tetraselenide compound [(CO)4Mn{(PPh2)2C-Se4-C(PPh2)2}Mn(CO)4] (2-Se4), which, upon treatment with KOH, is transformed into the corresponding triselenide and diselenide derivatives 2-Se3 and 2-Se2. Full or partial protonation of the methanide carbon atoms can be accomplished by reaction of the above compounds with HBF4, whereas treatment of 2-Se2 with I2 gives rise to the formation of the selenelyl iodide derivative [Mn(CO)4{(PPh2)2C-Se-I}] (5)
