1,593 research outputs found
First evidence for molecular interfaces between outflows and ambient clouds in high-mass star-forming regions?
We present new observations of the Cep A East region of massive star formation and describe an extended and dynamically distinct feature not previously recognized. This feature is present in emission from H2CS, OCS, CH3OH, and HDO at −5.5 km s−1 but is not traced by the conventional tracers of star-forming regions, H2S, SO2, SO, and CS. The feature is extended up to at least 0.1 pc. We show that the feature is neither a hot core nor a shocked outflow. However, the chemistry of the feature is consistent with predictions from a model of an eroding interface between a fast wind and a dense core; mixing between the two media occurs in the interface on a timescale of 10–50 yr. If these observations are confirmed by detailed maps and by detections in species also predicted to be abundant (e.g., HCO+, H2CO, and NH3), this feature would be the first detection of such an interface in regions of massive star formation. An important implication of the model is that a significant reservoir of sulfur in grain mantles is required to be in the form of OCS
The influence of normal stress and sliding velocity on the frictional behaviour of calcite at room temperature. Insights from laboratory experiments and microstructural observations
The presence of calcite in and near faults, as the dominant material, cement, or vein fill,
indicates that the mechanical behaviour of carbonate-dominated material likely plays an important role in shallow- and mid-crustal faulting. To better understand the behaviour of calcite,
under loading conditions relevant to earthquake nucleation, we sheared powdered gouge of
Carrara Marble, >98 per cent CaCO3, at constant normal stresses between 1 and 100 MPa
under water-saturated conditions at room temperature. We performed slide-hold-slide tests,
1–3000 s, to measure the amount of static frictional strengthening and creep relaxation, and
velocity-stepping tests, 0.1–1000 µm s–1, to evaluate frictional stability. We observe that the
rates of frictional strengthening and creep relaxation decrease with increasing normal stress
and diverge as shear velocity is increased from 1 to 3000 µm s–1 during slide-hold-slide experiments. We also observe complex frictional stability behaviour that depends on both normal
stress and shearing velocity. At normal stresses less than 20 MPa, we observe predominantly
velocity-neutral friction behaviour. Above 20 MPa, we observe strong velocity-strengthening
frictional behaviour at low velocities, which then evolves towards velocity-weakening friction
behaviour at high velocities. Microstructural analyses of recovered samples highlight a variety
of deformation mechanisms including grain size reduction and localization, folding of calcite grains and fluid-assisted diffusion mass transfer processes promoting the development of
calcite nanograins in the highly deformed portions of the experimental fault. Our combined
analyses indicate that calcite fault gouge transitions from brittle to semi-brittle behaviour at
high normal stress and slow sliding velocities. This transition has important implications for
earthquake nucleation and propagation on faults in carbonate-dominated lithologies
A study of methanol and silicon monoxide production through episodic explosions of grain mantles in the Central Molecular Zone
Methanol (CHOH) is found to be abundant and widespread towards the
Central Molecular Zone, the inner few hundred parsecs of our Galaxy. Its origin
is, however, not fully understood. It was proposed that the high cosmic ray
ionisation rate in this region could lead to a more efficient non-thermal
desorption of this species formed on grain surfaces, but it would also mean
that this species is destroyed in a relatively short timescale. In a first
step, we run chemical models with a high cosmic ray ionisation rate and find
that this scenario can only reproduce the lowest abundances of methanol derived
in this region (10-10). In a second step, we investigate
another scenario based on episodic explosions of grain mantles. We find a good
agreement between the predicted abundances of methanol and the observations. We
find that the dominant route for the formation of methanol is through
hydrogenation of CO on the grains followed by the desorption due to the grain
mantle explosion. The cyclic aspect of this model can explain the widespread
presence of methanol without requiring any additional mechanism. We also model
silicon monoxide (SiO), another species detected in several molecular clouds of
the Galactic Centre. An agreement is found with observations for a high
depletion of Si (Si/H 10) with respect to the solar abundance.Comment: Accepted in MNRA
The L1157-B1 astrochemical laboratory: testing the origin of DCN
L1157-B1 is the brightest shocked region of the large-scale molecular
outflow, considered the prototype of chemically rich outflows, being the ideal
laboratory to study how shocks affect the molecular gas. Several deuterated
molecules have been previously detected with the IRAM 30m, most of them formed
on grain mantles and then released into the gas phase due to the shock. We aim
to observationally investigate the role of the different chemical processes at
work that lead to formation the of DCN and test the predictions of the chemical
models for its formation. We performed high-angular resolution observations
with NOEMA of the DCN(2-1) and H13CN(2-1) lines to compute the deuterated
fraction, Dfrac(HCN). We detected emission of DCN(2-1) and H13CN(2-1) arising
from L1157-B1 shock. Dfrac(HCN) is ~4x10 and given the uncertainties, we
did not find significant variations across the bow-shock. Contrary to HDCO,
whose emission delineates the region of impact between the jet and the ambient
material, DCN is more widespread and not limited to the impact region. This is
consistent with the idea that gas-phase chemistry is playing a major role in
the deuteration of HCN in the head of the bow-shock, where HDCO is undetected
as it is a product of grain-surface chemistry. The spectra of DCN and H13CN
match the spectral signature of the outflow cavity walls, suggesting that their
emission result from shocked gas. The analysis of the time dependent gas-grain
chemical model UCL-CHEM coupled with a C-type shock model shows that the
observed Dfrac(HCN) is reached during the post-shock phase, matching the
dynamical timescale of the shock. Our results indicate that the presence of DCN
in L1157-B1 is a combination of gas-phase chemistry that produces the
widespread DCN emission, dominating in the head of the bow-shock, and
sputtering from grain mantles toward the jet impact region.Comment: Accepted for publication in A&A. 7 pages, 5 Figures, 1 Tabl
Desorption From Interstellar Ices
The desorption of molecular species from ice mantles back into the gas phase
in molecular clouds results from a variety of very poorly understood processes.
We have investigated three mechanisms; desorption resulting from H_2 formation
on grains, direct cosmic ray heating and cosmic ray induced photodesorption.
Whilst qualitative differences exist between these processes (essentially
deriving from the assumptions concerning the species-selectivity of the
desorption and the assumed threshold adsorption energies, E_t) all three
processes are found to be potentially very significant in dark cloud
conditions. It is therefore important that all three mechanisms should be
considered in studies of molecular clouds in which freeze-out and desorption
are believed to be important.
Employing a chemical model of a typical static molecular core and using
likely estimates for the quantum yields of the three processes we find that
desorption by H_2 formation probably dominates over the other two mechanisms.
However, the physics of the desorption processes and the nature of the dust
grains and ice mantles are very poorly constrained. We therefore conclude that
the best approach is to set empirical constraints on the desorption, based on
observed molecular depletions - rather than try to establish the desorption
efficiencies from purely theoretical considerations. Applying this method to
one such object (L1689B) yields upper limits to the desorption efficiencies
that are consistent with our understanding of these mechanisms.Comment: 11 pages, 5 figures, accepted by MNRAS subject to minor revision
which has been carried ou
Molecules, ices and astronomy
Molecules in interstellar gas and in interstellar ices play a fundamental role in astronomy. However, the formation of the simplest molecule, molecular hydrogen, is still not fully understood. Similarly, although interstellar ice analogues have received much attention in the laboratory, the evolution of ices in the interstellar medium still requires further study. At UCL we have developed two separate experiments to address these issues and explore the following questions: How is H formed on dust-grain surfaces? What is the budget between internal, kinetic and surface energies in the formation process? What are the astronomical consequences of these results? For ices, we ask: How do molecules desorb from pure and from mixed ices in regions warmed by newly formed stars? What can molecules released from ices tell us about the star-formation process? We put our results in the context of other laboratory work and we describe their application to current problems in astronomy
Chemistry in Evaporating Ices: Unexplored Territory
We suggest that three-body chemistry may occur in warm high density gas
evaporating in transient co\textendash desorption events on interstellar ices.
Using a highly idealised computational model we explore the chemical conversion
from simple species of the ice to more complex species containing several heavy
atoms, as a function of density and of adopted three body rate coefficients. We
predict that there is a wide range of densities and rate coefficients in which
a significant chemical conversion may occur. We discuss the implications of
this idea for the astrochemistry of hot cores.Comment: Accepted in Ap
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