Chemistry of dense clumps near moving Herbig-Haro objects

Localised regions of enhanced emission from HCO+, NH3 and other species near Herbig-Haro objects (HHOs) have been interpreted as arising in a photochemistry stimulated by the HHO radiation on high density quiescent clumps in molecular clouds. Static models of this process have been successful in accounting for the variety of molecular species arising ahead of the jet; however recent observations show that the enhanced molecular emission is widespread along the jet as well as ahead. Hence, a realistic model must take into account the movement of the radiation field past the clump. It was previously unclear as to whether the short interaction time between the clump and the HHO in a moving source model would allow molecules such as HCO+ to reach high enough levels, and to survive for long enough to be observed. In this work we model a moving radiation source that approaches and passes a clump. The chemical picture is qualitatively unchanged by the addition of the moving source, strengthening the idea that enhancements are due to evaporation of molecules from dust grains. In addition, in the case of several molecules, the enhanced emission regions are longer-lived. Some photochemically-induced species, including methanol, are expected to maintain high abundances for ~10,000 years.Comment: 7 pages, 3 figure

On the chemistry of hydrides of N atoms and O+^+ ions

Previous work by various authors has suggested that the detection by Herschel/HIFI of nitrogen hydrides along the low density lines of sight towards G10.6-0.4 (W31C) cannot be accounted for by gas-phase chemical models. In this paper we investigate the role of surface reactions on dust grains in diffuse regions, and we find that formation of the hydrides by surface reactions on dust grains with efficiency comparable to that for H$_2$ formation reconciles models with observations of nitrogen hydrides. However, similar surface reactions do not contribute significantly to the hydrides of O$^+$ ions detected by Herschel/HIFI present along many sight lines in the Galaxy. The O$^+$ hydrides can be accounted for by conventional gas-phase chemistry either in diffuse clouds of very low density with normal cosmic ray fluxes or in somewhat denser diffuse clouds with high cosmic ray fluxes. Hydride chemistry in dense dark clouds appears to be dominated by gas-phase ion-molecule reactions.Comment: 19 pages, 4 figures, 4 tables Accepted for publication in Ap

The influence of normal stress and sliding velocity on the frictional behaviour of calcite at room temperature. Insights from laboratory experiments and microstructural observations

The presence of calcite in and near faults, as the dominant material, cement, or vein fill, indicates that the mechanical behaviour of carbonate-dominated material likely plays an important role in shallow- and mid-crustal faulting. To better understand the behaviour of calcite, under loading conditions relevant to earthquake nucleation, we sheared powdered gouge of Carrara Marble, >98 per cent CaCO3, at constant normal stresses between 1 and 100 MPa under water-saturated conditions at room temperature. We performed slide-hold-slide tests, 1–3000 s, to measure the amount of static frictional strengthening and creep relaxation, and velocity-stepping tests, 0.1–1000 µm s–1, to evaluate frictional stability. We observe that the rates of frictional strengthening and creep relaxation decrease with increasing normal stress and diverge as shear velocity is increased from 1 to 3000 µm s–1 during slide-hold-slide experiments. We also observe complex frictional stability behaviour that depends on both normal stress and shearing velocity. At normal stresses less than 20 MPa, we observe predominantly velocity-neutral friction behaviour. Above 20 MPa, we observe strong velocity-strengthening frictional behaviour at low velocities, which then evolves towards velocity-weakening friction behaviour at high velocities. Microstructural analyses of recovered samples highlight a variety of deformation mechanisms including grain size reduction and localization, folding of calcite grains and fluid-assisted diffusion mass transfer processes promoting the development of calcite nanograins in the highly deformed portions of the experimental fault. Our combined analyses indicate that calcite fault gouge transitions from brittle to semi-brittle behaviour at high normal stress and slow sliding velocities. This transition has important implications for earthquake nucleation and propagation on faults in carbonate-dominated lithologies

A study of methanol and silicon monoxide production through episodic explosions of grain mantles in the Central Molecular Zone

Methanol (CH$_3$OH) is found to be abundant and widespread towards the Central Molecular Zone, the inner few hundred parsecs of our Galaxy. Its origin is, however, not fully understood. It was proposed that the high cosmic ray ionisation rate in this region could lead to a more efficient non-thermal desorption of this species formed on grain surfaces, but it would also mean that this species is destroyed in a relatively short timescale. In a first step, we run chemical models with a high cosmic ray ionisation rate and find that this scenario can only reproduce the lowest abundances of methanol derived in this region ($\sim$10$^{-9}$-10$^{-8}$). In a second step, we investigate another scenario based on episodic explosions of grain mantles. We find a good agreement between the predicted abundances of methanol and the observations. We find that the dominant route for the formation of methanol is through hydrogenation of CO on the grains followed by the desorption due to the grain mantle explosion. The cyclic aspect of this model can explain the widespread presence of methanol without requiring any additional mechanism. We also model silicon monoxide (SiO), another species detected in several molecular clouds of the Galactic Centre. An agreement is found with observations for a high depletion of Si (Si/H $\sim$ 10$^{-8}$) with respect to the solar abundance.Comment: Accepted in MNRA

The clumpiness of molecular clouds: HCO+ (3--2) survey near Herbig-Haro objects

Some well-studied Herbig Haro objects have associated with them one or more cold, dense, and quiescent clumps of gas. We propose that such clumps near an HH object can be used as a general measure of clumpiness in the molecular cloud that contains that HH object. Our aim is to make a survey of clumps around a sample of HH objects, and to use the results to make an estimate of the clumpiness in molecular clouds. All known cold, dense, and quiescent clumps near HH objects are anomalously strong HCO+ emitters. Our method is, therefore, to search for strong HCO+ emission as an indicator of a clump near to an HH object. The searches were made using JCMT and SEST in the HCO+ 3-2 and also H13CO+ 1-0 lines, with some additional searches for methanol and sulphur monoxide lines. The sources selected were a sample of 22 HH objects in which no previous HCO+ emission had been detected. We find that half of the HH objects have clumps detected in the HCO+ 3-2 line and that all searches in H13CO$+ 1-0 lines show evidence of clumpiness. All condensations have narrow linewidths and are evidently unaffected dynamically by the HH jet shock. We conclude that the molecular clouds in which these HH objects are found must be highly heterogeneous on scales of less than 0.1 pc. An approximate calculation based on these results suggests that the area filling factor of clumps affected by HH objects is on the order of 10%. These clumps have gas number densities larger than 3e4 cm-2.Comment: 11 pages, 14 figures. Accepted for publication in Astronomy and Astrophysic