4 research outputs found
Diaquabis(propane-1,3-diamine)copper(II) bis[diamminetetrakis(thiocyanato-κN)chromate(III)] dimethyl sulfoxide octasolvate
The ionic title complex, [Cu(C3H10N2)2(H2O)2][Cr(NCS)4(NH3)2]·8C2H6OS, consists of complex [Cu(dipr)2(H2O)2]2+ copper cations (dipr is propane-1,3-diamine), complex [Cr(NCS)4(NH3)2]− anions and uncoordinated solvent dimethyl sulfoxide (DMSO) molecules. All the metal atoms lie on crystallographic centers of symmetry. The cations are connected to the anions through N—H⋯O hydrogen bonds between the NH3 molecules of the anion and the water molecules of the cation. The DMSO molecules are involved in hydrogen-bonded linkage of the [Cr(NCS)4(NH3)2]− anions into supramolecular chains through bridging O atoms. A network of hydrogen bonds as well as short S⋯S contacts [3.5159 (12) and 3.4880 (12) Å] between the NCS groups of the complex anions link the molecules into a three-dimensional supramolecular network
Bis[N-(2-aminoethyl)ethane-1,2-diamine-κ3N,N′,N′′]copper(II) tris[diamminetetrakis(thiocyanato-κN)chromate(III)] thiocyanate dimethyl sulfoxide tetradecasolvate monohydrate
The ionic title complex, [Cu(C4H13N3)2]2[Cr(NCS)4(NH3)2]3(NCS)·14C2H6OS·H2O, consists of complex [Cu(dien)2]2+ cations [dien is N-(2-aminoethyl)ethane-1,2-diamine], complex [Cr(NCS)4(NH3)2]− anions, an NCS− counter-anion and uncoordinated dimethyl sulfoxide (DMSO) and water solvent molecules. One of the Cr atoms lies on an inversion center, while the second Cr atom and the Cu atom lie in general positions. The thiocyanate counter-anion and water molecule are disordered over two positions close to an inversion center. There are several types of hydrogen-bond interactions present in the title compound, which connect the complex cations and anions into bulky [Cu2Cr3] polynuclear species. The four NH3 groups of the complex anions and six bridging DMSO O atoms link the three complex anions via hydrogen bonding into the anionic polynuclear species [Cr(NCS)4(NH3)2]3·6DMSO. The last one is connected by four bridging DMSO O atoms with the two complex copper cations through N—H... O hydrogen bonds between the terminal NH3 groups of the anionic polynuclear species and the NH and NH2 groups of the dien ligand. One additional DMSO molecule is connected via hydrogen bonding to one of the terminal NH3 groups of the anionic polynuclear species. Another DMSO molecule is connected via hydrogen bonding to each Cu(dien)2]2+ cation