The 2:1 cycloadducts from [3+2] 1,3-dipolar cycloaddition of nitrile oxide and vinylacetic acid. Synthesis and liquid crystal behaviour

Four liquid crystals (LC) 3,7a-bis(4-alkyloxyphenyl)-7,7a-dihydro-6H-isoxazolo[2,3-d][1,2,4]oxadiazol-6-yl)acetic acid (7a-d) were synthesised and the mesomorphic behaviour reported. The LCs were characterised as 2: 1 bisadducts, which were obtained from a double [3+2] 1,3-dipolar cycloaddition. In the first step, the cycloaddition of 4-alkyloxyphenylnitrile oxide (4a-d) and vinylacetic acid (5) gave the initial unobserved 1:1 cycloadducts 2-[3-(4-alkyloxyphenyl)-4,5-dihydroisoxazol-5-yl]acetic acid (6a-d). In the second step, the addition of a second equivalent of 4 to 6 yielded the 2: 1 bisadducts 7a-d without any traces of 6. All compounds 7a-d were unstable during the transition from the mesophase to the isotropic state upon first heating as evidenced by the large peaks in the differential scanning calorimetry traces. Due to the chemical instability of the compounds upon heating, the transition temperature related to the smectic C to smectic A transitions was acquired by means of an image processing method. X-Ray diffraction experiments were also used to analyse the liquid-crystalline phases. A theoretical calculation was performed using density functional theory (DFT) methods at the PBE1PBE/6-311+G(2d,p) level (with solvent effect) in order to get information about the energetic profile of the 2: 1 cycloaddition. DFT studies revealed that the cycloaddition process is controlled by the HOMO(dipolarophile) - LUMO(1,3-dipole), and that the double [3+2] 1,3-dipolar cycloaddition reaction is quite possible.CNPq [471194-2008-5]CAPESINCT-Catalise[PROCAD-2007/CAPES

DCOOD optically pumped by a13CO2 laser: New terahertz laser lines

In this work, we report new optically pumped terahertz laser lines from DCOOD. An isotopic 13CO2 laser was used for first time as pump source, and a Fabry-Perot open cavity was used as a terahertz laser resonator. Optoacoustic absorption spectra were used as a guide to search for new terahertz laser lines. We could observe six new laser lines in the range from 303.8μm (0.987 THz) to 725.1μm (0.413 THz). The lines were characterized according to wavelength, relative polarization, relative intensity, and optimum working pressure. The transferred Lamb-dip technique was used to measure the frequency absorption transition both for this laser lines. © 2008 American Institute of Physics

Uma abordagem teórica e experimental do oscilador harmônico em duas dimensões utilizando as curvas de Lissajous

The study of oscillatory phenomena is an important topic in several areas of knowledge. The understanding and the solution of many problems that scientists and engineers confront nowadays can be formulated, at least as an analogy, in terms of an oscillatory movement. The description of the motion of this nature has remarkable contributions to the mathematical and conceptual formation of the students and for solving daily problems in several areas. In this paper we propose a theoretical and experimental approach involving the phenomenon of harmonic oscillations in two dimensions. Lissajous curves were used as experimental demonstration of the resulting trajectories. These curves were obtained from relatively simple experimental apparatus, which is affordable in most teaching laboratories of physics.O estudo de fenômenos oscilatórios e de grande importância em diversas áreas do conhecimento. A solução ou o entendimento de muitos problemas que cientistas e engenheiros enfrentam no dia-a-dia sao equacionados, analógica ou literalmente, atraves de um movimento do tipo oscilatório. A descrição de movimentos desta natureza possui notária contribuiçao para a formacao matematica e conceitual do estudante e para a resolução de problemas do dia-a-dia nas mais diversas areas. Neste trabalho, propomos uma abordagem teorica e experimental envolvendo o fenômeno de oscilacoes harmonicas em duas dimensões que pode ser facilmente realizada em sala de aula em curso de mecanica classica. A trajetoria descrita a partir das possíveis solucoes para a equacao do movimento oscilatorio em duas dimensoes foi demonstrada utilizando as curvas de Lissajous. As curvas estudadas foram obtidas atraves de um aparato experimental relativamente simples e acessível na maioria dos laboratórios didaticos de física