Generalised state spaces and non-locality in fault tolerant quantum computing schemes

We develop connections between generalised notions of entanglement and quantum computational devices where the measurements available are restricted, either because they are noisy and/or because by design they are only along Pauli directions. By considering restricted measurements one can (by considering the dual positive operators) construct single particle state spaces that are different to the usual quantum state space. This leads to a modified notion of entanglement that can be very different to the quantum version (for example, Bell states can become separable). We use this approach to develop alternative methods of classical simulation that have strong connections to the study of non-local correlations: we construct noisy quantum computers that admit operations outside the Clifford set and can generate some forms of multiparty quantum entanglement, but are otherwise classical in that they can be efficiently simulated classically and cannot generate non-local statistics. Although the approach provides new regimes of noisy quantum evolution that can be efficiently simulated classically, it does not appear to lead to significant reductions of existing upper bounds to fault tolerance thresholds for common noise models.Comment: V2: 18 sides, 7 figures. Corrected two erroneous claims and one erroneous argumen

Entanglement enhancement and postselection for two atoms interacting with thermal light

The evolution of entanglement for two identical two-level atoms coupled to a resonant thermal field is studied for two different families of input states. Entanglement enhancement is predicted for a well defined region of the parameter space of one of these families. The most intriguing result is the possibility of probabilistic production of maximally entangled atomic states even if the input atomic state is factorized and the corresponding output state is separable.Comment: accepted for publication in J. Phys.

Topology and Phases in Fermionic Systems

There can exist topological obstructions to continuously deforming a gapped Hamiltonian for free fermions into a trivial form without closing the gap. These topological obstructions are closely related to obstructions to the existence of exponentially localized Wannier functions. We show that by taking two copies of a gapped, free fermionic system with complex conjugate Hamiltonians, it is always possible to overcome these obstructions. This allows us to write the ground state in matrix product form using Grassman-valued bond variables, and show insensitivity of the ground state density matrix to boundary conditions.Comment: 4 pages, see also arxiv:0710.329

Light scattering and phase behavior of Lysozyme-PEG mixtures

Measurements of liquid-liquid phase transition temperatures (cloud points) of mixtures of a protein (lysozyme) and a polymer, poly(ethylene glycol) (PEG) show that the addition of low molecular weight PEG stabilizes the mixture whereas high molecular weight PEG was destabilizing. We demonstrate that this behavior is inconsistent with an entropic depletion interaction between lysozyme and PEG and suggest that an energetic attraction between lysozyme and PEG is responsible. In order to independently characterize the lysozyme/PEG interactions, light scattering experiments on the same mixtures were performed to measure second and third virial coefficients. These measurements indicate that PEG induces repulsion between lysozyme molecules, contrary to the depletion prediction. Furthermore, it is shown that third virial terms must be included in the mixture's free energy in order to qualitatively capture our cloud point and light scattering data. The light scattering results were consistent with the cloud point measurements and indicate that attractions do exist between lysozyme and PEG.Comment: 5 pages, 2 figures, 1 tabl

Operator monotones, the reduction criterion and the relative entropy

We introduce the theory of operator monotone functions and employ it to derive a new inequality relating the quantum relative entropy and the quantum conditional entropy. We present applications of this new inequality and in particular we prove a new lower bound on the relative entropy of entanglement and other properties of entanglement measures.Comment: Final version accepted for publication, added references in reference [1] and [13

Protonation of Pyruvic Acid - Synthesis of a plain Superelectrophile

The syntheses of [H3C(O)CC(OH)(2)][MF6] and [H3C(OH)CC-(OH)(2)][MF6](2) (M=As, Sb) by reacting pyruvic acid in the superacidic systems HF/AsF, and HF/SbF5 are reported. The salts were characterized by low-temperature vibrational spectroscopy and in the cases of [H3C(O)CC(OH)(2)][SbF6] and [H3C(OH)CC-(OH)(2)][SbF6](2)center dot HF by X-ray crystal structure analyses. The exper- imental results are discussed together with quantum chemical calculations. Remarkably, the bond distance and the twisting angle around the central C-C bond are unaffected by the protonations despite increasing coulombic repulsion. The crystal structure reveals short interionic interactions that have a considerable influence on the C-C bond

Distinguishing two-qubit states using local measurements and restricted classical communication

The problem of unambiguous state discrimination consists of determining which of a set of known quantum states a particular system is in. One is allowed to fail, but not to make a mistake. The optimal procedure is the one with the lowest failure probability. This procedure has been extended to bipartite states where the two parties, Alice and Bob, are allowed to manipulate their particles locally and communicate classically in order to determine which of two possible two-particle states they have been given. The failure probability of this local procedure has been shown to be the same as if the particles were together in the same location. Here we examine the effect of restricting the classical communication between the parties, either allowing none or eliminating the possibility that one party's measurement depends on the result of the other party's. These issues are studied for two-qubit states, and optimal procedures are found. In some cases the restrictions cause increases in the failure probability, but in other cases they do not. Applications of these procedures, in particular to secret sharing, are discussed.Comment: 18 pages, two figure

Tripartite entanglement and quantum relative entropy

We establish relations between tripartite pure state entanglement and additivity properties of the bipartite relative entropy of entanglement. Our results pertain to the asymptotic limit of local manipulations on a large number of copies of the state. We show that additivity of the relative entropy would imply that there are at least two inequivalent types of asymptotic tripartite entanglement. The methods used include the application of some useful lemmas that enable us to analytically calculate the relative entropy for some classes of bipartite states.Comment: 7 pages, revtex, no figures. v2: discussion about recent results, 2 refs. added. Published versio