Prototyping a Gas Sensors Using CeO2 as a Matrix or Dopant in Oxide Semiconductor Systems

In this chapter, two important aspects of using CeO2 in the field of gas sensors are presented. Firstly, for CO2 detection in the range of 0–5000 ppm, a binary semiconductor oxides CeO2-Y2O3 was used. Secondly, as a dopants, in oxide semiconductor systems, used to detect the NO2. In this case, CeO2 is used as a dopant in hybride composite, consisting of reduced graphene oxide/ZnO, in order to increase the sensibility in NO2 detection at low concentration in the range of 0–10 ppm. The structural and morphological characterization of sensitive materials by X-ray diffraction, SEM, adsorption desorption isotherms, thermal analysis and RAMAN spectroscopy are presented. Also, the sensing element of the sensor that detects the NO2 is achieved by depositing the nanocomposite material on the interdigital grid. The electronic conditioning signal from the sensing element is achieved by using a Wheatstone bridge together with an instrumentation operational amplifier

Enantioselective Decarboxylative Alkylation Reactions: Catalyst Development, Substrate Scope, and Mechanistic Studies

α-Quaternary ketones are accessed through novel enantioselective alkylations of allyl and propargyl electrophiles by unstabilized prochiral enolate nucleophiles in the presence of palladium complexes with various phosphinooxazoline (PHOX) ligands. Excellent yields and high enantiomeric excesses are obtained from three classes of enolate precursor: enol carbonates, enol silanes, and racemic β-ketoesters. Each of these substrate classes functions with nearly identical efficiency in terms of yield and enantioselectivity. Catalyst discovery and development, the optimization of reaction conditions, the exploration of reaction scope, and applications in target-directed synthesis are reported. Experimental observations suggest that these alkylation reactions occur through an unusual inner-sphere mechanism involving binding of the prochiral enolate nucleophile directly to the palladium center

Polymer Composites with Self-Regulating Temperature Behavior: Properties and Characterization

A novel conductive composite material with homogeneous binary polymer matrix of HDPE (HD) and LLDPE (LLD), mixed with conductive filler consisting of carbon black (CB) and graphite (Gr), was tested against a HDPE composite with a similar conductive filler. Even the concentration of the conductive filler was deliberately lower for (CB + Gr)/(LLD + HD), and the properties of this composite are comparable or better to those of (CB + Gr)/HD. The kinetic parameters of the ρ-T curves and from the DSC curves indicate that the resistivity peak is obtained when the polymer matrix is fully melted. When subjected to repeated thermal cycles, the composite (CB + Gr)/(LLD + HD) presented a better electrical behavior than composite CB + Gr)/HD, with an increase in resistivity (ρmax) values with the number of cycles, as well as less intense NTC (Negative Temperature Coefficient) effects, both for the crosslinked and thermoplastic samples. Radiation crosslinking led to increased ρmax values, as well as to inhibition of NTC effects in both cases, thus having a clear beneficial effect. Limitation effects of surface temperature and current intensity through the sample were observed at different voltages, enabling the use of these materials as self-regulating heating elements at various temperatures below the melting temperature. The procedure based on physical mixing of the components appears more efficient in imparting lower resistivity in solid state and high PTC (Positive Temperature Coefficient) effects to the composites. This effect is probably due to the concentration of the conductive particles at the surface of the polymer domains, which would facilitate the formation of the conductive paths. Further work is still necessary to optimize both the procedure of composite preparation and the properties of such materials

Chitosan and Chitosan Modified with Glutaraldehyde Microparticles for Pb(II) Biosorption I. Microparticles preparation and characterization

This paper presents the physical and chemical changes in chitosan flake