Muoniated radical states in the organic semiconductor phthalocyanine

Phthalocyanine samples of ZnPc, H2Pc and CuPc were investigated by the muon spin rotation amp; 956;SR technique. In ZnPc and H2Pc, three muoniated radical states of paramagnetic origin were identified, two of which having hyperfine interactions in the range 110 150 MHz and correspondign to muonium addition at the outer benzene rings. The third state presents a smaller hyperfine interaction about 25 MHz , and is tentatively assigned to addition at bridging nitrogen atoms. CuPc has an unpaired electron from the Cu atom, which originates a diamagnetic like signal upon muonium addition. The signal exhibits two components with very different relaxation rates, corresponding to two different spatial couplings of the Cu electron with the muonium s electro

Location of the H[+/-] level: Experimental limits for muonium

The defect energy levels for muonium, a light pseudo-isotope of hydrogen, are investigated to define the equivalent of the H[+/-] level which is predicted to be fixed at a universal energy. Existing results for Mu at donor and acceptor sites in silicon tentatively place Mu[+/-] approximately 0.5 eV above the predicted hydrogen level. Measured donor ionization energies in other materials in which two neutral Mu centers are observed define a range for the Mu acceptor energies. We discuss possible reinterpretation of known energies and the current state of investigations to obtain these muonium acceptor levels in order to further refine a determination of the Mu[+/-] energy.http://www.sciencedirect.com/science/article/B6TVH-4J3NYBD-15/1/4a9b436914b8289c0cb949279f64cb8