1 research outputs found
Synthesis, growth and characterization of copper mercury thiocyanate crystal
340-343Synthesis and growth
of nonlinear optical copper mercury thiocyanate, CuHg(SCN)4 (CMTC)
single crystals have been successfully carried out by slow evaporation
technique using water and ethanol as solvents with dimensions up to
12´8´5 mm3. The grown single
crystals have been studied by different characterization techniques in order to
know their suitability for various applications. The lattice parameters of the
crystal have been obtained by single crystal X-ray diffraction analysis. The
presence of functional groups have been identified using FTIR analysis. The
thermal stability and thermal decomposition of CMTC crystals have been investigated by using thermo gravimetric
analysis and differential thermal analysis. The CMTC crystal exhibits good
physio-chemical stability up to 253.8°C. The
optical transparency of the grown crystal has been studied by UV-vis-NIR
analysis. The lower cutoff wavelength of CMTC crystal occurs at 390 nm and has
been discovered as a non linear optical crystal material. The relative second
harmonic generation efficiency of the CMTC crystal has been tested by Kurtz -
Perry powder technique