3 research outputs found
Antioxidative, Hemocompatible, Fluorescent Carbon Nanodots from an “End-of-Pipe” Agricultural Waste: Exploring Its New Horizon in the Food-Packaging Domain
The attention of researchers is burgeoning
toward oilseed press-cake
valorization for its high protein content. Protein removal from oil-cakes
generates large quantities of fibrous residue (oil-and-protein spent
meal) as a byproduct, which currently has very limited practical utility.
In the wake of increasing awareness in waste recycling, a simple environmentally
benign hydrothermal carbonization process to convert this “end-of-pipe”
waste (spent meal) into antioxidative, hemocompatible, fluorescent
carbonaceous nanoparticles (FCDs) has been described. In the present
investigation, an interesting application of FCDs in fabricating low-cost
rapeseed protein-based fluorescent film, with improved antioxidant
potential (17.5–19.3-fold) and thermal stability has been demonstrated.
The nanocomposite film could also be used as forgery-proof packaging
due to its photoluminescence property. For assessing the feasibility
of antioxidative FCDs in real food systems, a comparative investigation
was further undertaken to examine the effect of such nanocarbon-loaded
composite film on the oxidative shelf life of rapeseed oil. Oil samples
packed in nanocomposite film sachets showed significant delay in oxidative
rancidity compared to those packed in pristine protein-film sachet
(free fatty acids, peroxide value, and thiobarbituric acid-reactive
substances reduced up to 1.4-, 2-, and 1.2-fold, respectively). The
work presents a new concept of biobased fluorescent packaging and
avenues for harnessing this potent waste
Graphene Derivative in Magnetically Recoverable Catalyst Determines Catalytic Properties in Transfer Hydrogenation of Nitroarenes to Anilines with 2‑Propanol
Here,
we report transfer hydrogenation of nitroarenes to aminoarenes
using 2-propanol as a hydrogen source and Ag-containing magnetically
recoverable catalysts based on partially reduced graphene oxide (pRGO)
sheets. X-ray diffraction and X-ray photoelectron spectroscopy data
demonstrated that, during the one-pot catalyst synthesis, formation
of magnetite nanoparticles (NPs) is accompanied by the reduction of
graphene oxide (GO) to pRGO. The formation of Ag<sup>0</sup> NPs on
top of magnetite nanoparticles does not change the pRGO structure.
At the same time, the catalyst structure is further modified during
the transfer hydrogenation, leading to a noticeable increase of sp<sup>2</sup> carbons. These carbons are responsible for the adsorption
of substrate and intermediates, facilitating a hydrogen transfer from
Ag NPs and creating synergy between the components of the catalyst.
The nitroarenes with electron withdrawing and electron donating substituents
allow for excellent yields of aniline derivatives with high regio
and chemoselectivity, indicating that the reaction is not disfavored
by these functionalities. The versatility of the catalyst synthetic
protocol was demonstrated by a synthesis of an Ru-containing graphene
derivative based catalyst, also allowing for efficient transfer hydrogenation.
Easy magnetic separation and stable catalyst performance in the transfer
hydrogenation make this catalyst promising for future applications
Oriented Attachment Is a Major Control Mechanism To Form Nail-like Mn-Doped ZnO Nanocrystals
Here, we present
a controlled synthesis of Mn-doped ZnO nanoparticles
(NPs) with predominantly nail-like shapes, whose formation occurs
via tip-to-base-oriented attachment of initially formed nanopyramids,
followed by leveling of sharp edges that lead to smooth single-crystalline
“nails”. This shape is prevalent in noncoordinating
solvents such as octadecene and octadecane. Yet, the double bond in
the former promotes oriented attachment. By contrast, Mn-doped ZnO
NP synthesis in a weakly coordinating solvent, benzyl ether, results
in dendritic structures because of random attachment of initial NPs.
Mn-doped ZnO NPs possess a hexagonal wurtzite structure, and in the
majority of cases, the NP surface is enriched with Mn, indicating
a migration of Mn<sup>2+</sup> ions to the NP surface during the NP
formation. When the NP formation is carried out without the addition
of octadecyl alcohol, which serves as a surfactant and a reaction
initiator, large, concave pyramid dimers are formed whose attachment
takes place via basal planes. UV–vis and photoluminescence
spectra of these NPs confirm the utility of controlling the NP shape
to tune electro-optical properties