Lattice-supported surface solitons in nonlocal nonlinear media

We reveal that lattice interfaces imprinted in nonlocal nonlinear media support surface solitons that do not exist in other similar settings, including interfaces of local and nonlocal uniform materials. We show the impact of nonlocality on the domains of existence and stability of the surface solitons, focusing on new types of dipole solitons residing partially inside the optical lattice. We find that such solitons feature strongly asymmetric shapes and that they are stable in large parts of their existence domain.Comment: 13 pages, 3 figures, to appear in Optics Letter

Soliton emission in amplifying optical lattice surfaces

We address surface solitons supported by the interface of optical lattices imprinted in saturable media with surface-localized gain. The nonlinearity saturation puts restrictions on the maximal energy flow carried by surface solitons. As a consequence, the presence of thin amplifying layer near the surface results in the controllable emission of solitons towards the lattice at angles depending on the amplification rate and on lattice depth.Comment: 14 pages, 4 figures, to appear in Optics Letter

Reassessment of thermochemical energy storage in perovskite-like manganites at comparative studies of RP SrCa3Mn3O10-d vs. orthorhombic Sr0.25Ca0.75MnO3-d

The structural stability, thermal expansion, oxygen exchange thermodynamics, and thermochemical storage (TCS) capacity of perovskite-like Sr0.25Ca0.75MnO3-δ and Ruddlesden-Popper SrCa3Mn3O10-δ manganites are studied by the combined use of experimental techniques, thermodynamic modeling of the defect formation reactions, and energy calculations utilizing density functional theory (DFT). It is argued that conservative estimates of the storage capacity can be made by the use of the Dulong-Petit limit for high-temperature heat capacity and oxygen partial enthalpy independent of both temperature and oxygen content. The respectively recalculated literature data and the obtained results show that the thermodynamic limit for the TCS capacity (~800 kJ/kg) of Sr0.25Ca0.75MnO3-δ is one of the highest at thermal cycling within the oxygen partial pressure range of 10 −4–0.21 atm. At the same time, the storage capacity of SrCa3Mn3O10-δ achieves only about 600 kJ/kg. The TCS cycling tests demonstrate the stability of SrCa3Mn3O10-δ while a decline in the energy storage capacity is observed for Sr0.25Ca0.75MnO3-δ. According to the EDX analysis, this effect may reflect surface degradation of Sr0.25Ca0.75MnO3-δ. The energy storage capacities of SrCa3Mn3O10-δ and Sr0.25Ca0.75MnO3-δ decrease to 510 and 560 kJ/kg, respectively, because of the rather sluggish reduction kinetics. It is concluded that further improvement of manganites as energy storage materials can be achieved using new doping strategies.This work was carried out under support of the state programs № АААА-А19-119031890026-6 and № АААА-А19-119110190048-7. Part of the DFT calculations were performed on the URAN cluster at the Institute of Mathematics and Mechanics, UB RAS.Peer reviewe