63 research outputs found
Temporal variability of major and trace elements concentrations in the groundwaters of Mt. Etna (Italy): effects of transient input of magmatic fluids highlighted by means of Cluster Analysis
Data for major, minor and trace elements in groundwaters from Mt. Etna volcano collected in 1994, 1995 and 1997 were analysed using Cluster Analysis (CA). Two groups of sampling sites were identified (named clusters A and B), mainly on the basis of their different salinity and content of dissolved CO2. The highest levels of both of these parameters were observed in the sites of cluster A, located in the lower south-western and central eastern flanks of the volcano. For both of the statistical groups, CA was repeated taking into account the mean values of each parameter in time, and the results allowed us to recognize four distinct groups of parameters for each group of sites on the basis of their temporal patterns. Four different types of temporal patterns were recognised: concave, convex, increasing, decreasing. The observed changes were basically interpreted as a result of the different response of dissolved chemical elements to changes in the aqueous environment and/or in their solubility/mobility in water due to different rates of input of magmatic gases to Etna’s aquifers. The main changes occurred in 1995, when Etna’s volcanic activity resumed after a two-year period of rest. The temporal changes of the majority of the studied parameters (water temperature, water conductivity, Eh, pH, Al, Mg, B, Ca, Cl-, Hg, Mn, Mo, Na, Ni, Se, Si, Sr, Cr Zn and pCO2) were not cluster-dependent, therefore they were not apparently affected by differences in water salinity between the two groups of sampling sites. A limited number of parameters (Ti, K, Li, HCO3-, As, Fe, SO42-, Cu and V), however, showed different behaviours depending on the cluster of sites which they belonged to, thus suggesting their apparent dependency on water salinity
Water safety in healthcare facilities. The Vieste Charter
The Study Group on Hospital Hygiene of the Italian Society of Hygiene, Preventive Medicine and Public Health (GISIO-SItI) and the Local Health Authority of Foggia, Apulia, Italy, after the National Convention "Safe water in healthcare facilities" held in Vieste-Pugnochiuso on 27-28 May 2016, present the "Vieste Charter", drawn up in collaboration with experts from the National Institute of Health and the Ministry of Health. This paper considers the risk factors that may affect the water safety in healthcare facilities and reports the current regulatory frameworks governing the management of installations and the quality of the water. The Authors promote a careful analysis of the risks that characterize the health facilities, for the control of which specific actions are recommended in various areas, including water safety plans; approval of treatments; healthcare facilities responsibility, installation and maintenance of facilities; multidisciplinary approach; education and research; regional and national coordination; communication
GC models for separation optimization in pressure-tunable tandem capillary columns operated isothermally. Part 2: Control experiments using a new capillary column interface
Use of the same capillary column for both sampling and gas chromatographic analysis of aqueous organic pollutants
New methodology in trace analysis of aqueous organic compounds. An innovative technique for solute sampling using gas chromatographic capillary columns
Trapping efficiency of aqueous micropollutants sampled and analyzed using the same capillary column. Theoretical aspects and experimental results
Temporal variability of major and trace elements concentrations in the groundwaters of Mt. Etna (Italy): effects of transient input of magmatic fluids highlighted by means of Cluster Analysis
Data for major, minor and trace elements in groundwaters from Mt. Etna volcano collected in 1994, 1995 and 1997 were analysed using Cluster Analysis (CA). Two groups of sampling sites were identified (named clusters A and B), mainly on the basis of their different salinity and content of dissolved CO2. The highest levels of both of these parameters were observed in the sites of cluster A, located in the lower south-western and central eastern flanks of the volcano. For both of the statistical groups, CA was repeated taking into account the mean values of each parameter in time, and the results allowed us to recognize four distinct groups of parameters for each group of sites on the basis of their temporal patterns. Four different types of temporal patterns were recognised: concave, convex, increasing, decreasing. The observed changes were basically interpreted as a result of the different response of dissolved chemical elements to changes in the aqueous environment and/or in their solubility/mobility in water due to different rates of input of magmatic gases to Etna’s aquifers. The main changes occurred in 1995, when Etna’s volcanic activity resumed after a two-year period of rest. The temporal changes of the majority of the studied parameters (water temperature, water conductivity, Eh, pH, Al, Mg, B, Ca, Cl-, Hg, Mn, Mo, Na, Ni, Se, Si, Sr, Cr Zn and pCO2) were not cluster-dependent, therefore they were not apparently affected by differences in water salinity between the two groups of sampling sites. A limited number of parameters (Ti, K, Li, HCO3-, As, Fe, SO42-, Cu and V), however, showed different behaviours depending on the cluster of sites which they belonged to, thus suggesting their apparent dependency on water salinity.Unpublished1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attiveJCR Journalope
Direct determination of halogenated POPs in aqueous samples by in-tube SPME, focalization and GC-ECD analysis
Temporal variability of major and trace elements concentrations in the groundwaters of Mt. Etna (Italy): effects of transient input of magmatic fluids highlighted by means of Cluster Analysis.
Data for major, minor and trace elements in groundwaters from Mt. Etna volcano collected in 1994, 1995 and 1997 were analysed using Cluster Analysis (CA). Two groups of sampling sites were identified (named clusters A and B), mainly on the basis of their different salinity and content of dissolved CO2. The highest levels of both of these parameters were observed in the sites of cluster A, located in the lower south-western and central eastern flanks of the volcano. For both of the statistical groups, CA was repeated taking into account the mean values of each parameter in time, and the results allowed us to recognize four distinct groups of parameters for each group of sites on the basis of their temporal patterns. Four different types of temporal patterns were recognised: concave, convex, increasing, decreasing. The observed changes were basically interpreted as a result of the different response of dissolved chemical elements to changes in the aqueous environment and/or in their solubility/mobility in water due to different rates of input of magmatic gases to Etna’s aquifers. The main changes occurred in 1995, when Etna’s volcanic activity resumed after a two-year period of rest. The temporal changes of the majority of the studied parameters (water temperature, water conductivity, Eh, pH, Al, Mg, B, Ca, Cl-, Hg, Mn, Mo, Na, Ni, Se, Si, Sr, Cr Zn and pCO2) were not cluster-dependent, therefore they were not apparently affected by differences in water salinity between the two groups of sampling sites. A limited number of parameters (Ti, K, Li, HCO3-, As, Fe, SO42-, Cu and V), however, showed different behaviours depending on the cluster of sites which they belonged to, thus suggesting their apparent dependency on water salinity.Published2523–25471.2. TTC - Sorveglianza geochimica delle aree vulcaniche attiveJCR Journalreserve
Capillary columns used in gas chromatographic analysis and as alternative technique in sampling of organic pollutants
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