1,911 research outputs found
CORAL REEF STUDIES. II. THE DEPTH OF CORAL REEFS IN RELATION TO THEIR OXYGEN CONSUMPTION AND THE PENETRATION OF LIGHT IN THE WATER
abstract not availabl
CORAL REEF STUDIES. III. GEOMORPHOLOGICAL NOTES ON THE CORAL REEFS OF BATAVIA BAY
abstract not availabl
CORAL REEF STUDIES . I. THE SYMBIOSIS BETWEEN DAMSELFISHES AND SEA ANEMONES IN BATAVIA BAY.
abstract not availableÂ
Attraction between like-charged colloidal particles induced by a surface a density - functional analysis
We show that the first non-linear correction to the linearised
Poisson-Boltzman n (or DLVO) theory of effective pair interactions between
charge-stabilised, co lloidal particles near a charged wall leads to an
attractive component of entro pic origin. The position and depth of the
potential compare favourably with rec ent experimental measurementsComment: 12 pages including 2 figures. submitted to physical review letter
Quenched Charge Disorder and Coulomb Interactions
We develop a general formalism to investigate the effect of quenched fixed
charge disorder on effective electrostatic interactions between charged
surfaces in a one-component (counterion-only) Coulomb fluid. Analytical results
are explicitly derived for two asymptotic and complementary cases: i)
mean-field or Poisson-Boltzmann limit (including Gaussian-fluctuations
correction), which is valid for small electrostatic coupling, and ii)
strong-coupling limit, where electrostatic correlations mediated by counterions
become significantly large as, for instance, realized in systems with
high-valency counterions. In the particular case of two apposed and ideally
polarizable planar surfaces with equal mean surface charge, we find that the
effect of the disorder is nil on the mean-field level and thus the plates
repel. In the strong-coupling limit, however, the effect of charge disorder
turns out to be additive in the free energy and leads to an enhanced long-range
attraction between the two surfaces. We show that the equilibrium inter-plate
distance between the surfaces decreases for elevated disorder strength (i.e.
for increasing mean-square deviation around the mean surface charge), and
eventually tends to zero, suggesting a disorder-driven collapse transition.Comment: 13 pages, 2 figure
A closed form for the electrostatic interaction between two rod-like charged objects
We have calculated the electrostatic interaction between two rod-like charged
objects with arbitrary orientations in three dimensions. we obtained a closed
form formula expressing the interaction energy in terms of the separation
distance between the centers of the two rod-like objects, , their lengths
(denoted by and ), and their relative orientations (indicated by
and ). When the objects have the same length (),
for particular values of separations, i.e for , two types of
minimum are appeared in the interaction energy with respect to . By
employing the closed form formula and introducing a scaled temperature , we
have also studied the thermodynamic properties of a one dimensional system of
rod-like charged objects. For different separation distances, the dependence of
the specific heat of the system to the scaled temperature has been studied. It
is found that for , the specific heat has a maximum.Comment: 10 pages, 9 figures, 1 table, Accepted by J. Phys.: Condens. Matte
Non-monotonic density dependence of the diffusion of DNA fragments in low-salt suspensions
The high linear charge density of 20-base-pair oligomers of DNA is shown to
lead to a striking non-monotonic dependence of the long-time self-diffusion on
the concentration of the DNA in low-salt conditions. This generic non-monotonic
behavior results from both the strong coupling between the electrostatic and
solvent-mediated hydrodynamic interactions, and from the renormalization of
these electrostatic interactions at large separations, and specifically from
the dominance of the far-field hydrodynamic interactions caused by the strong
repulsion between the DNA fragments.Comment: 4 pages, 2 figures. Physical Review E, accepted on November 24, 200
Many-Body Electrostatic Forces Between Colloidal Particles at Vanishing Ionic Strength
Electrostatic forces between small groups of colloidal particles are measured
using blinking optical tweezers. When the electrostatic screening length is
significantly larger than the particle radius, forces are found to be
non-pairwise additive. Both pair and multi-particle forces are well described
by the linearized Poisson-Boltzmann equation with constant potential boundary
conditions. These findings may play an important role in understanding the
structure and stability of a wide variety of systems, from micron-sized
particles in oil to aqueous nanocolloids.Comment: 5 pages 2 figure
Properties of alkali-halide salt solutions about polarizable nanoparticle solutes for different ion models
Effective interactions in the colloidal suspensions from HNC theory
The HNC Ornstein-Zernike integral equations are used to determine the
properties of simple models of colloidal solutions where the colloids and ions
are immersed in a solvent considered as a dielectric continuum and have a size
ratio equal to 80 and a charge ratio varying between 1 and 4000. At an infinite
dilution of colloids, the effective interactions between colloids and ions are
determined for ionic concentrations ranging from 0.001 to 0.1 mol/l and
compared to those derived from the Poisson-Boltzmann theory. At finite
concentrations, we discuss on the basis of the HNC results the possibility of
an unambiguous definition of the effective interactions between the colloidal
molecules.Comment: 26 pages, 15 figure
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