Palynology, organic geochemistry and carbon isotope analysis of a latest Ordovician through Silurian clastic succession from borehole Tt1, Ghadamis Basin, southern Tunisia, North Africa: Palaeoenvironmental interpretation

Palynological and palynofacies analyses combined with organic carbon isotope measurements have been performed on terminal Ordovician through Silurian clastic sediments from the North African margin of Gondwana (southern Tunisia). A first carbon isotopic signal (delta(13)C(org)) from Gondwanan Silurian sedimentary sequences is presented, showing interesting correlation with existing coeval isotopic curves from other areas. Changes in lithology, palynofacies characteristics, palynomorph diversity, carbon isotope developments, and organic geochemistry parameters appear to be all causally linked, and to reflect changes in palaeoceano-graphic conditions. In particular, the detailed chronostratigraphic correlation and the observed similarities in patterns of carbon isotopic developments and (palyno- and litho-) facies changes through the study section has permitted to identify the supposedly global earliest Wenlock ("Ireviken Event") and late Ludlow ("Lau Event") isotopic excursions for the first time in high-latitude Gondwana. This confirms that these excursions were linked to global changes in the oceanic system. The present results suggest that from Rhuddanian to early Wenlock times, an extended period of black shale deposition occurred over the North African Gondwanan margin, progressively transgressing from basin palaeodepressions to basin palaeohighs. Palynofacies and organic geochemistry support a coastal upwelling-promoted productivity increase during this interval, associated to a decrease in diversity of the marine microplanktonic communities. The earliest Wenlock strong positive isotopic shift appears associated with this protracted period of massive black shale deposition, and thus of organic carbon burial, on continental platforms located in high-latitude settings. This could well explain the apparent paradox between excessive carbonate deposition simultaneous to a carbon isotopic shift towards lighter values observed in low palaeolatitude localities (Laurentia and Baltica). the strong, distinct isotope excursion occurring in late Ludlow times is possibly linked to the well know Lau Event. Evidence for extensive organic carbon burial is lacking to explain this strong excursion. Some significant changes in the marine palynomorph communities are recorded in connection to the increase in stable isotope values (delta(13)C(org)). Additionally, a strong correlation between abundance of terrestrially derived palynomorphs (miospores) and delta(13)C(org) development is recorded which seems to support increased clastic input from a terrestrial source. (C) 2008 Elsevier B.V. All rights reserved

Occurrence of retene in upper Silurian-lower Devonian sediments from North Africa: Origin and implications

The biomarkers retene, cadalene, tetrahydroretene and isohexylalkylnaphthalene have been identified in the extracts of Silurian-Devonian clastic sediments from southern Tunisia. The occurrence of retene is unexpected as it is generally considered to be a diagenetic product of the conifer constituent abietic acid; however, conifers evolved only after the Devonian. The retene shows a strong correlation with the abundant terrestrial signal from bryophyte-derived cryptospores in the palynofacies, suggesting that it derives from a terrestrial source. Accordingly, we propose that either abietic acid synthesis evolved prior to the appearance of conifers or retene is a diagenetic product of precursors other than abietic acid, which were synthesized by the earliest land plants. Without excluding the first possibility, it appears likely that retene derives here from the diagenesis of compounds with a kaurane-type skeleton, which were abundantly produced by the early Palaeozoic bryophytes. (C) 2009 Elsevier Ltd. All rights reserved

Aliphatic and aromatic biomarkers from Gondwanan sediments of Late Ordovician to Early Devonian age: An early terrestrialization approach

Twenty one core samples of Late Ordovician to Early Devonian age from sections in southern Tunisia, North African Platform (Gondwana) and containing marine and terrestrial organic matter with microbial input were investigated to link the aliphatic and aromatic hydrocarbon distributions with the terrestrial and marine palynomorph content (e. g. acritarchs, prasinophytes, chitinozoans, cryptospores and trilete spores). In addition to several biomarkers of algal/bacterial origin, long chain n-alkanes that might be derived from land plants, as well as the terrestrial diterpane, norabietane, were found. Several land plant-derived biomarkers, such as retene, cadalene, simonellite, tetrahydroretene and C(19) isohexylalkyl naphthalene were observed in the aromatic fractions. While these terrestrial biomarkers could be clearly recognized in the middle Silurian-lower Devonian samples, their presence in the upper Ordovician-lower Silurian sediments is more doubtful, because of much lower relative abundances. The land plant biomarkers show a fairly good correlation with the occurrence and abundance of cryptospores and trilete spores, derived from bryophytes and tracheophytes, which covered the emerged areas around the Ghadamis Basin during the Silurian and Devonian. The early tracheophytes (e. g. Cooksonia, lycophytes and zosterophylls) are therefore suggested as a new terrestrial source for most of the saturated and aromatic biomarkers found in sediments of Middle Silurian to Early Devonian age. (C) 2011 Elsevier Ltd. All rights reserved

High-resolution last deglaciation record from the Congo fan reveals significance of mangrove pollen and biomarkers as indicators of shelf transgression

High abundances of mangrove pollen have been associated with transgressive cycles on tropical margins, but the detailed relations between systems tracts and the taphonomy of the pollen are unclear. We report here the occurrence and high abundance of Rhizophora pollen, in association with taraxerol, a Rhizophora-sourced biomarker, from a high-resolution Congo fan core covering the last deglaciation. An age model based on 14C dates enables the temporal changes in taraxerol content and the percentage frequencies and flux (pollen grains (pg) cm-2 (10^3 yr)-1) of mangrove pollen to be compared quantitatively with the lateral rate of transgression across the flooding surface (derived from glacio-hydro-isostatic model output and the bathymetry of the margin). Rhizophora pollen concentrations and taraxerol content of the sediment are very strongly positively correlated with the lateral rate of transgression and indicate, independently of any sequence stratigraphic context, that mangrove pollen spikes are associated with the transgressive systems tract rather than the highstand systems tract or maximum flooding surface. Lower-resolution longer-term records from this margin indicate an association between taraxerol concentrations and transgressive rather than regressive phases. The flux of these materials to the Congo fan is interpreted as a function of the erosion of flooded mangrove swamp on the shelf and, less importantly, changing extent of mangrove habitat, during sea-level rise. Congo River palaeoflood events also result in reworking of mangrove pollen and supply to the fan, but this mechanism is subdominant. Rhizophora pollen has been underestimated in many palynological studies undertaken on cores from the African margin because of inappropriate sieve mesh size used during laboratory preparation.

Aliphatic and aromatic biomarkers from Carboniferous coal deposits at Dunbar (East Lothian, Scotland): Palaeobotanical and palaeoenvironmental significance

Carboniferous (Visean) coals from Dunbar, East Lothian, Scotland, contain well-preserved miospore and megaspore assemblages suggesting a lycopod-dominated forest ecosystem with some ferns, sphenopsids and pteridosperms. The low rank of the coals and the well defined microflora permit assessment of the palaeoenvironmental significance of lipid biomarkers during the Early Carboniferous. Rock-Eval, petrographic, and lipid analyses indicate a fully terrestrial depositional environment. Although we also present and discuss a wide diversity of other lipid biomarkers (alkanes, hopanoids, steroids), we focus on the terrestrial-derived biomarkers. Combustion-derived PAHs pyrene, fluoranthene, benzo[a]anthracene, chrysene and triphenylene indicate the occurrence of forest fires in the study areas during Early Carboniferous times. Alkyldibenzofurans are considered to derive from lichen-biomass. Retene, cadalene, simonellite, tetrahydroretene and kaurane are poorly specific and can derive from a variety of early Palaeozoic land plants. Abietane, phyllocladane, ent-beyerane and 4 beta(H)-eudesmane, as well as bisnorsimonellite, diaromatic totarane, diaromatic sempervirane and 2-methylretene, however, as yet had only been reported from conifers, which do not appear in the fossil record until the Late Carboniferous. Within the lower Carboniferous forest ecosystem, arborescent lycopsids and pteridosperms are proposed as alternative sources for these compounds. (C) 2011 Elsevier B.V. All rights reserved