503 research outputs found
Influence of oxygen ordering kinetics on Raman and optical response in YBa_2Cu_3O_{6.4}
Kinetics of the optical and Raman response in YBa_2Cu_3O_{6.4} were studied
during room temperature annealing following heat treatment. The superconducting
T_c, dc resistivity, and low-energy optical conductivity recover slowly,
implying a long relaxation time for the carrier density. Short relaxation times
are observed for the B_{1g} Raman scattering -- magnetic, continuum, and phonon
-- and the charge transfer band. Monte Carlo simulations suggest that these two
relaxation rates are related to two length scales corresponding to local oxygen
ordering (fast) and long chain and twin formation (slow).Comment: REVTeX, 3 pages + 4 PostScript (compressed) figure
Bandgap and effective mass of epitaxial cadmium oxide
The bandgap and band-edge effective mass of single crystal cadmium oxide, epitaxially grown by metal-organic vapor-phase epitaxy, are determined from infrared reflectivity, ultraviolet/visible absorption, and Hall effect measurements. Analysis and simulation of the optical data, including effects of band nonparabolicity, Moss-Burstein band filling and bandgap renormalization, reveal room temperature bandgap and band-edge effective mass values of 2.16±0.02 eV and 0.21±0.01m0 respectively
Antiferromagnetic Excitations and Van Hove Singularities in YBaCuO
We show that in quasi-two-dimensional -wave superconductors Van Hove
singularities close to the Fermi surface lead to novel magnetic quasi-particle
excitations. We calculate the temperature and doping dependence of dynamical
magnetic susceptibility for YBCO and show that the proposed excitations are in
agreement with inelastic neutron scattering experiments. In addition, the
values of the gap parameter and in-plane antiferromagnetic coupling are much
smaller than usually believed.Comment: REVTeX, 4 pages + 3 PostScript (compressed) figures; to appear in
Phys. Rev. B (Rap. Comm.
X-Ray-Diffraction Study of Charge-Density-Waves and Oxygen-Ordering in YBa2Cu3O6+x Superconductor
We report a temperature-dependent increase below 300 K of diffuse
superlattice peaks corresponding to q_0 =(~2/5,0,0) in an under-doped
YBa_2Cu_3O_6+x superconductor (x~0.63). These peaks reveal strong c-axis
correlations involving the CuO_2 bilayers, show a non-uniform increase below
\~220 K with a plateau for ~100-160 K, and appear to saturate in the
superconducting phase. We interpret this unconventional T-dependence of the
``oxygen-ordering'' peaks as a manifestation of a charge density wave in the
CuO_2 planes coupled to the oxygen-vacancy ordering.Comment: 4 pages, 4 figure
Drivers of success in implementing sustainable tourism policies in urban areas
The existing literature in the field of sustainable tourism highlights a number of barriers that impede the implementation of policies in this area. Yet, not many studies have so far considered the factors that would contribute to putting this concept into practice, and few address the case of urban areas. The concept of sustainability has only received limited attention in urban tourism research, even though large cities are recognised as one of the most important tourist destinations that attract vast numbers of visitors. Adopting a case study approach, this paper discusses a number of drivers of success identified by policy-makers in London to contribute to the implementation of sustainable tourisms policies at the local level, and briefly looks at the relationship between these drivers and the constraints perceived by the respondents to hinder the implementation of such policies in practice. These findings may help policy-makers in other large cities to successfully develop and implement policies towards sustainable development of tourism in their area
Anomalously large oxygen-ordering contribution to the thermal expansion of untwinned YBa2Cu3O6.95 single crystals: a glass-like transition near room temperature
We present high-resolution capacitance dilatometry studies from 5 - 500 K of
untwinned YBa2Cu3Ox (Y123) single crystals for x ~ 6.95 and x = 7.0. Large
contributions to the thermal expansivities due to O-ordering are found for x ~
6.95, which disappear below a kinetic glass-like transition near room
temperature. The kinetics at this glass transition is governed by an energy
barrier of 0.98 +- 0.07 eV, in very good agreement with other O-ordering
studies. Using thermodynamic arguments, we show that O-ordering in the Y123
system is particularly sensitive to uniaxial pressure (stress) along the chain
axis and that the lack of well-ordered chains in Nd123 and La123 is most likely
a consequence of a chemical-pressure effect.Comment: 4 pages, 3 figures, submitted to PR
Thermodynamic properties and structural stability of thorium dioxide
Using density functional theory (DFT) calculations, we have systematically
investigated the thermodynamic properties and structural stabilities of thorium
dioxide (ThO). Based on the calculated phonon dispersion curves, we
calculate the thermal expansion coefficient, bulk modulus, and heat capacities
at different temperatures for ThO under the quasi-harmonic approximation.
All the results are in good agreement with corresponding experiments proving
the validity of our methods. Our theoretical studies can help people more
clearly understand the thermodynamic behaviors of ThO at different
temperatures. In addition, we have also studied possible defect formations and
diffusion behaviors of helium in ThO, to discuss its structural stability.
It is found that in intrinsic ThO without any Fermi energy shifts, the
interstitial Th defect other than oxygen or thorium vacancies,
interstitial oxygen, and any kinds of Frenkel pairs, is most probable to form
with an energy release of 1.74 eV. However, after upshifting the Fermi energy,
the formation of the other defects also becomes possible. For helium diffusion,
we find that only through the thorium vacancy can it happen with the small
energy barrier of 0.52 eV. Otherwise, helium atoms can hardly incorporate or
diffuse in ThO. Our results indicate that people should prevent upshifts of
the Fermi energy of ThO to avoid the formation of thorium vacancies and so
as to prevent helium caused damages.Comment: 11 pages, 11 figure
Relaxation Effects in the Transition Temperature of Superconducting HgBa2CuO4+delta
In previous studies on a number of under- and overdoped high temperature
superconductors, including YBa_{2}Cu_{3}O_{7-y} and Tl_{2}Ba_{2}CuO_{6+\delta},
the transition temperature T_c has been found to change with time in a manner
which depends on the sample's detailed temperature and pressure history. This
relaxation behavior in T_c is believed to originate from rearrangements within
the oxygen sublattice. In the present high-pressure studies on
HgBa_{2}CuO_{4+\delta} to 0.8 GPa we find clear evidence for weak relaxation
effects in strongly under- and overdoped samples () with
an activation energy . For overdoped
HgBa_{2}CuO_{4+\delta} E_{A} increases under pressure more rapidly than
previously observed for YBa_{2}Cu_{3}O_{6.41}, yielding an activation volume of
+11 \pm 5 cm^{3}; the dependence of T_c on pressure is markedly nonlinear, an
anomalous result for high-T_c superconductors in the present pressure range,
giving evidence for a change in the electronic and/or structural properties
near 0.4 GPa
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