147 research outputs found
Managing the life cycles of the document and library collections in Finnish academic libraries, case Aalto and UEF
Version of RecordPublishe
Non-Arrhenius Behavior of Surface Diffusion Near a Phase Transition Boundary
We study the non-Arrhenius behavior of surface diffusion near the
second-order phase transition boundary of an adsorbate layer. In contrast to
expectations based on macroscopic thermodynamic effects, we show that this
behavior can be related to the average microscopic jump rate which in turn is
determined by the waiting-time distribution W(t) of single-particle jumps at
short times. At long times, W(t) yields a barrier that corresponds to the
rate-limiting step in diffusion. The microscopic information in W(t) should be
accessible by STM measurements.Comment: 4 pages, Latex with RevTeX macro
Density profile evolution and nonequilibrium effects in partial and full spreading measurements of surface diffusion
We study the nature of nonequilibrium effects in the collective diffusion coefficient DC(θ) vs the coverage θ as extracted from Boltzmann–Matano analysis of spreading coverage profiles. We focus on the temporal behavior of the profiles and study how the corresponding nonequilibrium effects in DC(θ) depend on the initial density gradient and the initial state from which the spreading starts. To this end, we carry out extensive Monte Carlo simulations for a lattice-gas model of the O/W(110) system. Studies of submonolayer spreading from an initially ordered p(2×1) phase at θ=12 reveal that the spreading and diffusion rates in directions parallel and perpendicular to rows of oxygen atoms are significantly different within the ordered phase. Aside from this effect, we find that the degree of ordering in the initial phase has a relatively small impact on the overall behavior of DC(θ). Also, although we find that nonequilibrium effects are clearly present in submonolayer spreading profiles, DC(θ) determined from such data approaches its asymptotic equilibrium behavior much more rapidly than in the case of full spreading. Nevertheless, in both cases there are noticeable deviations from equilibrium results that persist even at very long times and are strongest in ordered phases and in the vicinity of phase boundaries. These conclusions are confirmed by complementary studies of the temporal behavior of the order parameter φ(θ). Finally, we use DC(θ) and φ(θ) to determine the locations of phase boundaries and find such data to be clearly time dependent during full spreading. We conclude that nonequilibrium effects seem to be an inherent feature in profile evolution studies of surface diffusion in all cases where ordering plays a prominent role. This warrants particular care to be taken with profile spreading experiments.Peer reviewe
Enhanced dielectrophoresis of nanocolloids by dimer formation
We investigate the dielectrophoretic motion of charge-neutral, polarizable
nanocolloids through molecular dynamics simulations. Comparison to analytical
results derived for continuum systems shows that the discrete charge
distributions on the nanocolloids have a significant impact on their coupling
to the external field. Aggregation of nanocolloids leads to enhanced
dielectrophoretic transport, provided that increase in the dipole moment upon
aggregation can overcome the related increase in friction. The dimer
orientation and the exact structure of the nanocolloid charge distribution are
shown to be important in the enhanced transport
Hurst's Rescaled Range Statistical Analysis for Pseudorandom Number Generators used in Physical Simulations
The rescaled range statistical analysis (R/S) is proposed as a new method to
detect correlations in pseudorandom number generators used in Monte Carlo
simulations. In an extensive test it is demonstrated that the RS analysis
provides a very sensitive method to reveal hidden long run and short run
correlations. Several widely used and also some recently proposed pseudorandom
number generators are subjected to this test. In many generators correlations
are detected and quantified.Comment: 12 pages, 12 figures, 6 tables. Replaces previous version to correct
citation [19
How would you integrate the equations of motion in dissipative particle dynamics simulations?
In this work we assess the quality and performance of several novel
dissipative particle dynamics integration schemes that have not previously been
tested independently. Based on a thorough comparison we identify the respective
methods of Lowe and Shardlow as particularly promising candidates for future
studies of large-scale properties of soft matter systems
Effects of quenched impurities on surface diffusion, spreading, and ordering of O/W(110)
We study how quenched impurities affect the surfacediffusion and ordering of strongly interactingadsorbate atoms on surfaces. To this end, we carry out Monte Carlo simulations for a lattice-gas model of O/W(110), including small concentrations of immobile impurities which block their adsorption sites. We examine the behavior of the diffusion coefficients and order parameters as a function of coverage corresponding to various ordered phases at low temperatures. The effects of impurities are examined under both equilibrium and nonequilibrium conditions, and the results are compared to recent studies on a completely clean surface. We find that even minute impurity concentrations affect the diffusion behavior considerably in equilibrium. The effects are strongest in ordered phases and close to phase boundaries, where quenched impurities lead to a reduction of order, which in turn leads to significant changes in the collective diffusion and phase behavior. As the impurity concentration is increased to a level of a few percent of the total surface area, the reduction in order becomes particularly prominent at high coverages. Further studies under nonequilibrium conditions reveal that nonequilibrium effects are strong in the absence of impurities, while for surfaces covered by impurities the nonequilibrium effects are relatively weaker.Peer reviewe
- …