18 research outputs found
Synthesis and characterization of SiO2/Bi2WO6 based on biogenic silica synthesized by sol-gel method
SiO2/Bi2WO6 photocatalyst with Si/Bi/W=1:2:1 molar ratio was obtained by the sol-gel method from bismuth nitrate, sodium tungstate and biogenic silica from rice husk biomass followed by calcination. Bi2WO6 was used as a control sample. FT-IR, SEM, XRD, EDXRF, UV-Vis methods were used to systematically characterize the as-obtained materials. Photodegradation of Indigo Carmine in exposure to UV, sunlight and xenon light was studied to evaluate their photocatalytic activities in the presence of SiO2/Bi2WO6 and Bi2WO6. It was shown that the degradation degree of Indigo Carmine in the presence of SiO2/Bi2WO6 under the action of UV irradiation and sunlight reaches 36% and 14%, respectively. The SiO2/Bi2WO6 sample is stable during photocatalytic studies
Individual Differences in Studentsβ Effort Source Beliefs Predict Their Judgments of Ability
A recent set of studies (Muenks, Miele, & Wigfield, 2016) introduced the concept of perceived effort source to better explain how students reason about the relation between effort and ability when evaluating the academic abilities of other students. These studies showed that participants who were induced to perceive effort as task-elicited (i.e., as being primarily due to the subjective difficulty of the task) were more likely to view effort and ability as inversely related than participants who were induced to perceive effort as self-initiated (i.e., as being due to studentsβ motivation to go beyond the basic demands of the task). The current studies expanded on this research by demonstrating that, in the absence of an effort source manipulation, college students spontaneously invoked beliefs about the source of effort when evaluating their own (Study 2) and other studentsβ (Studies 1β3) abilities. The three studies also showed that our novel measure of individual differences in effort source beliefs was a better predictor of participantsβ judgments of math ability (Studies 1 and 2) and verbal ability (Study 3) than a standard measure of their ability mindsets (i.e., beliefs about the extent to which intelligence is malleable). Specifically, participants who naturally tended to perceive effort as task-elicited generally rated students who expended relatively little effort as having more ability than did participants who tended to perceive effort as self-initiated. Implications for research on student motivation and for education practice are discussed
Synthesis and characterization of SiO
SiO2/Bi2WO6 photocatalyst with Si/Bi/W=1:2:1 molar ratio was obtained by the sol-gel method from bismuth nitrate, sodium tungstate and biogenic silica from rice husk biomass followed by calcination. Bi2WO6 was used as a control sample. FT-IR, SEM, XRD, EDXRF, UV-Vis methods were used to systematically characterize the as-obtained materials. Photodegradation of Indigo Carmine in exposure to UV, sunlight and xenon light was studied to evaluate their photocatalytic activities in the presence of SiO2/Bi2WO6 and Bi2WO6. It was shown that the degradation degree of Indigo Carmine in the presence of SiO2/Bi2WO6 under the action of UV irradiation and sunlight reaches 36% and 14%, respectively. The SiO2/Bi2WO6 sample is stable during photocatalytic studies
Synthesis and characterization of SiO
SiO2/Bi2WO6 photocatalyst with Si/Bi/W=1:2:1 molar ratio was obtained by the sol-gel method from bismuth nitrate, sodium tungstate and biogenic silica from rice husk biomass followed by calcination. Bi2WO6 was used as a control sample. FT-IR, SEM, XRD, EDXRF, UV-Vis methods were used to systematically characterize the as-obtained materials. Photodegradation of Indigo Carmine in exposure to UV, sunlight and xenon light was studied to evaluate their photocatalytic activities in the presence of SiO2/Bi2WO6 and Bi2WO6. It was shown that the degradation degree of Indigo Carmine in the presence of SiO2/Bi2WO6 under the action of UV irradiation and sunlight reaches 36% and 14%, respectively. The SiO2/Bi2WO6 sample is stable during photocatalytic studies
Electrochemical Properties of Bismuth Oxide Films on Titanium Formed by Plasma Electrolytic Oxidation
ΠΠ° ΠΏΠΎΠ²Π΅ΡΡ
Π½ΠΎΡΡΠΈ ΡΠΈΡΠ°Π½Π° ΠΌΠ΅ΡΠΎΠ΄ΠΎΠΌ ΠΏΠ»Π°Π·ΠΌΠ΅Π½Π½ΠΎ-ΡΠ»Π΅ΠΊΡΡΠΎΠ»ΠΈΡΠΈΡΠ΅ΡΠΊΠΎΠ³ΠΎ ΠΎΠΊΡΠΈΠ΄ΠΈΡΠΎΠ²Π°Π½ΠΈΡ (ΠΠΠ)
ΡΡΠΎΡΠΌΠΈΡΠΎΠ²Π°Π½Ρ Π²ΠΈΡΠΌΡΡΠΎΡΠΎΠ΄Π΅ΡΠΆΠ°ΡΠΈΠ΅ ΠΎΠΊΡΠΈΠ΄Π½ΡΠ΅ ΠΏΠΎΠΊΡΡΡΠΈΡ ΠΈΠ· ΡΠ»Π΅ΠΊΡΡΠΎΠ»ΠΈΡΠΎΠ², ΡΠΎΠ΄Π΅ΡΠΆΠ°ΡΠΈΡ
ΠΊΠΎΠΌΠΏΠ»Π΅ΠΊΡΠ½ΡΠ΅ ΠΈΠΎΠ½Ρ ΠΠΠ’Π-Bi3+. ΠΠΏΡΠ΅Π΄Π΅Π»Π΅Π½Ρ ΡΠ»Π΅ΠΊΡΡΠΎΡ
ΠΈΠΌΠΈΡΠ΅ΡΠΊΠΈΠ΅ Ρ
Π°ΡΠ°ΠΊΡΠ΅ΡΠΈΡΡΠΈΠΊΠΈ β
ΡΠΎΠΊΠΈ ΠΎΠ±ΠΌΠ΅Π½Π°, ΠΊΠΎΡΡΡΠΈΡΠΈΠ΅Π½ΡΡ ΠΏΠ΅ΡΠ΅Π½ΠΎΡΠ° Ξ± ΠΈ Ξ², ΠΊΠΎΡΡΡΠΈΡΠΈΠ΅Π½ΡΡ a ΠΈ b Π² ΡΡΠ°Π²Π½Π΅Π½ΠΈΠΈ Π’Π°ΡΠ΅Π»Ρ.
ΠΠ»Ρ ΠΏΠΎΠ»ΡΡΠ΅Π½Π½ΡΡ
ΡΠΈΡΡΠ΅ΠΌ ΡΡΡΠ°Π½ΠΎΠ²Π»Π΅Π½ΠΎ Π²ΠΎΠ·Π½ΠΈΠΊΠ½ΠΎΠ²Π΅Π½ΠΈΠ΅ Π°Π½Π°Π»ΠΈΡΠΈΡΠ΅ΡΠΊΠΎΠ³ΠΎ ΡΠΈΠ³Π½Π°Π»Π° ΠΏΡΠΈ
ΠΊΠΎΠΌΠΏΠ»Π΅ΠΊΡΠΎΠ½ΠΎΠΌΠ΅ΡΡΠΈΡΠ΅ΡΠΊΠΎΠΌ ΡΠΈΡΡΠΎΠ²Π°Π½ΠΈΠΈ ΡΠΎΠ»Π΅ΠΉ ΠΆΠ΅Π»Π΅Π·Π° (III). Π ΡΠ΄ΠΎΠΌ ΡΠΈΠ·ΠΈΡΠ΅ΡΠΊΠΈΡ
ΠΌΠ΅ΡΠΎΠ΄ΠΎΠ²
(ΡΠΊΠ°Π½ΠΈΡΡΡΡΠ°Ρ ΡΠ»Π΅ΠΊΡΡΠΎΠ½Π½Π°Ρ ΠΌΠΈΠΊΡΠΎΡΠΊΠΎΠΏΠΈΡ Ρ ΡΠ½Π΅ΡΠ³ΠΎΠ΄ΠΈΡΠΏΠ΅ΡΡΠ½ΡΠΌ Π°Π½Π°Π»ΠΈΠ·ΠΎΠΌ ΠΈ ΡΠ΅Π½ΡΠ³Π΅Π½ΠΎΠ²ΡΠΊΠ°Ρ
ΡΠΎΡΠΎΡΠ»Π΅ΠΊΡΡΠΎΠ½Π½Π°Ρ ΡΠΏΠ΅ΠΊΡΡΠΎΡΠΊΠΎΠΏΠΈΡ) ΠΈΠ·ΡΡΠ΅Π½Ρ ΠΌΠΎΡΡΠΎΠ»ΠΎΠ³ΠΈΡ ΠΈ ΡΠΎΡΡΠ°Π² ΠΏΠΎΠ²Π΅ΡΡ
Π½ΠΎΡΡΠΈ ΠΎΠΊΡΠΈΠ΄Π½ΡΡ
ΠΏΠΎΠΊΡΡΡΠΈΠΉ. ΠΠ°ΠΉΠ΄Π΅Π½Π° ΠΊΠΎΡΡΠ΅Π»ΡΡΠΈΡ ΠΌΠ΅ΠΆΠ΄Ρ ΠΌΠΎΡΡΠΎΠ»ΠΎΠ³ΠΈΠ΅ΠΉ, ΡΠΎΡΡΠ°Π²ΠΎΠΌ ΠΏΠΎΠ²Π΅ΡΡ
Π½ΠΎΡΡΠΈ ΠΈ
ΡΠ»Π΅ΠΊΡΡΠΎΡ
ΠΈΠΌΠΈΡΠ΅ΡΠΊΠΈΠΌΠΈ ΡΠ²ΠΎΠΉΡΡΠ²Π°ΠΌΠΈ ΠΎΠ±ΡΠ°Π·ΡΠΎΠ²Bismuth oxide layers on a titanium are formed by a plasma electrolytic oxidation (PEO) method from
electrolytes containing complex ions EDTA-Bi3+. Electrochemical characteristics β exchange currents,
transport coefficients Ξ± and Ξ², a and b coefficients in Tafelβs equation are defined. For the obtained
systems occurrence of an analytical signal at complexometric titration of salts of Fe (III) is established.
The structural features of surface electrodes have been investigated by scanning electron microscopy
(SEM) and X-ray photoelectron spectroscopy (XPS) techniques. Correlation between morphology,
structure of a surface and electrochemical properties of samples is foun
Electrochemical Properties of Bismuth Oxide Films on Titanium Formed by Plasma Electrolytic Oxidation
ΠΠ° ΠΏΠΎΠ²Π΅ΡΡ
Π½ΠΎΡΡΠΈ ΡΠΈΡΠ°Π½Π° ΠΌΠ΅ΡΠΎΠ΄ΠΎΠΌ ΠΏΠ»Π°Π·ΠΌΠ΅Π½Π½ΠΎ-ΡΠ»Π΅ΠΊΡΡΠΎΠ»ΠΈΡΠΈΡΠ΅ΡΠΊΠΎΠ³ΠΎ ΠΎΠΊΡΠΈΠ΄ΠΈΡΠΎΠ²Π°Π½ΠΈΡ (ΠΠΠ)
ΡΡΠΎΡΠΌΠΈΡΠΎΠ²Π°Π½Ρ Π²ΠΈΡΠΌΡΡΠΎΡΠΎΠ΄Π΅ΡΠΆΠ°ΡΠΈΠ΅ ΠΎΠΊΡΠΈΠ΄Π½ΡΠ΅ ΠΏΠΎΠΊΡΡΡΠΈΡ ΠΈΠ· ΡΠ»Π΅ΠΊΡΡΠΎΠ»ΠΈΡΠΎΠ², ΡΠΎΠ΄Π΅ΡΠΆΠ°ΡΠΈΡ
ΠΊΠΎΠΌΠΏΠ»Π΅ΠΊΡΠ½ΡΠ΅ ΠΈΠΎΠ½Ρ ΠΠΠ’Π-Bi3+. ΠΠΏΡΠ΅Π΄Π΅Π»Π΅Π½Ρ ΡΠ»Π΅ΠΊΡΡΠΎΡ
ΠΈΠΌΠΈΡΠ΅ΡΠΊΠΈΠ΅ Ρ
Π°ΡΠ°ΠΊΡΠ΅ΡΠΈΡΡΠΈΠΊΠΈ β
ΡΠΎΠΊΠΈ ΠΎΠ±ΠΌΠ΅Π½Π°, ΠΊΠΎΡΡΡΠΈΡΠΈΠ΅Π½ΡΡ ΠΏΠ΅ΡΠ΅Π½ΠΎΡΠ° Ξ± ΠΈ Ξ², ΠΊΠΎΡΡΡΠΈΡΠΈΠ΅Π½ΡΡ a ΠΈ b Π² ΡΡΠ°Π²Π½Π΅Π½ΠΈΠΈ Π’Π°ΡΠ΅Π»Ρ.
ΠΠ»Ρ ΠΏΠΎΠ»ΡΡΠ΅Π½Π½ΡΡ
ΡΠΈΡΡΠ΅ΠΌ ΡΡΡΠ°Π½ΠΎΠ²Π»Π΅Π½ΠΎ Π²ΠΎΠ·Π½ΠΈΠΊΠ½ΠΎΠ²Π΅Π½ΠΈΠ΅ Π°Π½Π°Π»ΠΈΡΠΈΡΠ΅ΡΠΊΠΎΠ³ΠΎ ΡΠΈΠ³Π½Π°Π»Π° ΠΏΡΠΈ
ΠΊΠΎΠΌΠΏΠ»Π΅ΠΊΡΠΎΠ½ΠΎΠΌΠ΅ΡΡΠΈΡΠ΅ΡΠΊΠΎΠΌ ΡΠΈΡΡΠΎΠ²Π°Π½ΠΈΠΈ ΡΠΎΠ»Π΅ΠΉ ΠΆΠ΅Π»Π΅Π·Π° (III). Π ΡΠ΄ΠΎΠΌ ΡΠΈΠ·ΠΈΡΠ΅ΡΠΊΠΈΡ
ΠΌΠ΅ΡΠΎΠ΄ΠΎΠ²
(ΡΠΊΠ°Π½ΠΈΡΡΡΡΠ°Ρ ΡΠ»Π΅ΠΊΡΡΠΎΠ½Π½Π°Ρ ΠΌΠΈΠΊΡΠΎΡΠΊΠΎΠΏΠΈΡ Ρ ΡΠ½Π΅ΡΠ³ΠΎΠ΄ΠΈΡΠΏΠ΅ΡΡΠ½ΡΠΌ Π°Π½Π°Π»ΠΈΠ·ΠΎΠΌ ΠΈ ΡΠ΅Π½ΡΠ³Π΅Π½ΠΎΠ²ΡΠΊΠ°Ρ
ΡΠΎΡΠΎΡΠ»Π΅ΠΊΡΡΠΎΠ½Π½Π°Ρ ΡΠΏΠ΅ΠΊΡΡΠΎΡΠΊΠΎΠΏΠΈΡ) ΠΈΠ·ΡΡΠ΅Π½Ρ ΠΌΠΎΡΡΠΎΠ»ΠΎΠ³ΠΈΡ ΠΈ ΡΠΎΡΡΠ°Π² ΠΏΠΎΠ²Π΅ΡΡ
Π½ΠΎΡΡΠΈ ΠΎΠΊΡΠΈΠ΄Π½ΡΡ
ΠΏΠΎΠΊΡΡΡΠΈΠΉ. ΠΠ°ΠΉΠ΄Π΅Π½Π° ΠΊΠΎΡΡΠ΅Π»ΡΡΠΈΡ ΠΌΠ΅ΠΆΠ΄Ρ ΠΌΠΎΡΡΠΎΠ»ΠΎΠ³ΠΈΠ΅ΠΉ, ΡΠΎΡΡΠ°Π²ΠΎΠΌ ΠΏΠΎΠ²Π΅ΡΡ
Π½ΠΎΡΡΠΈ ΠΈ
ΡΠ»Π΅ΠΊΡΡΠΎΡ
ΠΈΠΌΠΈΡΠ΅ΡΠΊΠΈΠΌΠΈ ΡΠ²ΠΎΠΉΡΡΠ²Π°ΠΌΠΈ ΠΎΠ±ΡΠ°Π·ΡΠΎΠ²Bismuth oxide layers on a titanium are formed by a plasma electrolytic oxidation (PEO) method from
electrolytes containing complex ions EDTA-Bi3+. Electrochemical characteristics β exchange currents,
transport coefficients Ξ± and Ξ², a and b coefficients in Tafelβs equation are defined. For the obtained
systems occurrence of an analytical signal at complexometric titration of salts of Fe (III) is established.
The structural features of surface electrodes have been investigated by scanning electron microscopy
(SEM) and X-ray photoelectron spectroscopy (XPS) techniques. Correlation between morphology,
structure of a surface and electrochemical properties of samples is foun