Proposal for an Experiment to Test a Theory of High Temperature Superconductors

A theory for the phenomena observed in Copper-Oxide based high temperature superconducting materials derives an elusive time-reversal and rotational symmetry breaking order parameter for the observed pseudogap phase ending at a quantum-critical point near the composition for the highest $T_c$. An experiment is proposed to observe such a symmetry breaking. It is shown that Angle-resolved Photoemission yields a current density which is different for left and right circularly polarized photons. The magnitude of the effect and its momentum dependence is estimated. Barring the presence of domains of the predicted phase an asymmetry of about 0.1 is predicted at low temperatures in moderately underdoped samples.Comment: latex, 2 figure

Phosphorus-containing imide resins

Bis- and tris-imides derived from tris (m-aminophenyl) phosphine oxides by reaction with maleic anhydride or its derivatives, and addition polymers of such imides, including a variant in which a mono-imide is condensed with a dianhydride and the product is treated with a further quantity of maleic anhydride. Such monomers or their oligomes may be used to impregnate fibers and fabrics which when cured, are flame resistant. Also an improved method of producing tris (m-aminophenyl) phosphine oxides from the nitro analogues by reduction with hydrazine hydrate using palladized charcoal or Raney nickel as the catalyst is described

Elastomer-modified phosphorus-containing imide resins

Phosphine oxide-containing polyimide resins modified by elastomers, are disclosed which have improved mechanical properties. These products are particularly useful in the production of fiber or fabric-reinforced composites or laminates

Phosphorus-containing imide resins

Cured polymers of bis and tris-imides derived from tris(m-aminophenyl) phosphine oxides by reaction with maleic anhydride or its derivatives, and addition polymers of such imides, including a variant in which a monoimide is condensed with a dianhydride and the product is treated with a further quantity of maleic anhydride prior to curing are disclosed and claimed. Such polymers are flame resistant. Also disclosed are an improved method of producing tris(m-aminophenyl) phosphine oxides from the nitro analogues by reduction with hydrazine hydrate using palladized charcoal or Raney nickel as the catalyst and fiber reinforced cured resin composites

Phosphorus-containing bisimide resins

The production of fire-resistant resins particularly useful for making laminates with inorganic fibers such as graphite fibers is discussed. The resins are by (1) condensation of an ethylenically unsaturated cyclic anhydride with a bis(diaminophenyl) phosphine oxide, and (2) by addition polymerization of the bisimide so obtained. Up to about 50%, on a molar basis, of benzophenonetetracarboxylic acid anhydride can be substituted for some of the cyclic anhydride to alter the properties of the products. Graphite cloth laminates made with these resins show 800 C char yields greater than 70% by weight in nitrogen. Limiting oxygen indexes of more than 100% are determined for these resins

Collective Modes in the Loop Current Ordered Phase of Cuprates

Recently two branches of weakly dispersive collective modes have been discovered in under-doped cuprates by inelastic neutron scattering. Polarization analysis reveals that the modes are magnetic excitations. They are only visible for temperatures below the transition temperature to a broken symmetry phase which was discovered earlier and their intensity increases as temperature is further decreased. The broken symmetry phase itself has symmetries consistent with ordering of orbital current loops within a unit-cell without breaking translational symmetry. In order to calculate the collective modes of such a state we add quantum terms to the Ashkin-Teller (AT) model with which the classical loop current order has been described. We derive that the mean field ground state of the quantum model is a product over all unit-cells of linear combination of the four possible classical configurations of the loop current order in each unit-cell. The collective modes are calculated by using a generalized Holstein-Primakoff boson representation of orbital moment operators and lead to three branches of gapped weakly dispersive collective modes. The experimental results are consistent with the two lower energy branches; the third mode is at a higher energy than looked for by present neutron scattering experiments and might also be over-damped. Implications of the discovery of the collective modes are discussed.Comment: 16 pages, 6 figure

Heavy-Fermions in a Transition-Metal Compound: LiV2O4LiV_2O_4

The recent discovery of heavy-Fermion properties in Lithium Vanadate and the enormous difference in its properties from the properties of Lithium Titanate as well as of the manganite compounds raise some puzzling questions about strongly correlated Fermions. These are disscussed as well as a solution to the puzzles provided.Comment: late

Only Fermi-Liquids are Metals

Any singular deviation from Landau Fermi-liquid theory appears to lead, for arbitrarily small concentration of impurities coupling to a non-conserved quantity, to a vanishing density of states at the chemical potential and infinite resistivity as temperature approaches zero. Applications to copper-oxide metals including the temperature dependence of the anisotropy in resistivity, and to other cases of non Fermi-liquids are discussed.Comment: 11 pages,revtex, 1 Postscript figur

A Theory of the Pseudogap State of the Cuprates

The phase diagram for a general model for Cuprates is derived in a mean-field approximation. A phase violating time-reversal without breaking translational symmetry is possible when both the ionic interactions and the local repulsions are large compared to the energy difference between the Cu and O single-particle levels. It ends at a quantum critical point as the hole or electron doping is increased. Such a phase is necessarily accompanied by singular forward scattering such that, in the stable phase, the density of states at the chemical potential, projected to a particular point group symmetry of the lattice is zero producing thereby an anisotropic gap in the single-particle spectrum. It is suggested that this phase occupies the "pseudogap" region of the phase diagram of the cuprates. The temperature dependence of the single-particle spectra, the density of states, the specific heat and the magnetic susceptibility are calculated with rather remarkable correspondence with the experimental results. The importance of further direct experimental verification of such a phase in resolving the principal issues in the theory of the Cuprate phenomena is pointed out. To this end, some predictions are provided.Comment: 41 pages, 8 figure