10,134 research outputs found
Phosphorus-containing imide resins
Bis- and tris-imides derived from tris (m-aminophenyl) phosphine oxides by reaction with maleic anhydride or its derivatives, and addition polymers of such imides, including a variant in which a mono-imide is condensed with a dianhydride and the product is treated with a further quantity of maleic anhydride. Such monomers or their oligomes may be used to impregnate fibers and fabrics which when cured, are flame resistant. Also an improved method of producing tris (m-aminophenyl) phosphine oxides from the nitro analogues by reduction with hydrazine hydrate using palladized charcoal or Raney nickel as the catalyst is described
Elastomer-modified phosphorus-containing imide resins
Phosphine oxide-containing polyimide resins modified by elastomers, are disclosed which have improved mechanical properties. These products are particularly useful in the production of fiber or fabric-reinforced composites or laminates
Phosphorus-containing imide resins
Cured polymers of bis and tris-imides derived from tris(m-aminophenyl) phosphine oxides by reaction with maleic anhydride or its derivatives, and addition polymers of such imides, including a variant in which a monoimide is condensed with a dianhydride and the product is treated with a further quantity of maleic anhydride prior to curing are disclosed and claimed. Such polymers are flame resistant. Also disclosed are an improved method of producing tris(m-aminophenyl) phosphine oxides from the nitro analogues by reduction with hydrazine hydrate using palladized charcoal or Raney nickel as the catalyst and fiber reinforced cured resin composites
Phosphorus-containing bisimide resins
The production of fire-resistant resins particularly useful for making laminates with inorganic fibers such as graphite fibers is discussed. The resins are by (1) condensation of an ethylenically unsaturated cyclic anhydride with a bis(diaminophenyl) phosphine oxide, and (2) by addition polymerization of the bisimide so obtained. Up to about 50%, on a molar basis, of benzophenonetetracarboxylic acid anhydride can be substituted for some of the cyclic anhydride to alter the properties of the products. Graphite cloth laminates made with these resins show 800 C char yields greater than 70% by weight in nitrogen. Limiting oxygen indexes of more than 100% are determined for these resins
Collective Modes in the Loop Current Ordered Phase of Cuprates
Recently two branches of weakly dispersive collective modes have been
discovered in under-doped cuprates by inelastic neutron scattering.
Polarization analysis reveals that the modes are magnetic excitations. They are
only visible for temperatures below the transition temperature to a broken
symmetry phase which was discovered earlier and their intensity increases as
temperature is further decreased. The broken symmetry phase itself has
symmetries consistent with ordering of orbital current loops within a unit-cell
without breaking translational symmetry. In order to calculate the collective
modes of such a state we add quantum terms to the Ashkin-Teller (AT) model with
which the classical loop current order has been described. We derive that the
mean field ground state of the quantum model is a product over all unit-cells
of linear combination of the four possible classical configurations of the loop
current order in each unit-cell. The collective modes are calculated by using a
generalized Holstein-Primakoff boson representation of orbital moment operators
and lead to three branches of gapped weakly dispersive collective modes. The
experimental results are consistent with the two lower energy branches; the
third mode is at a higher energy than looked for by present neutron scattering
experiments and might also be over-damped. Implications of the discovery of the
collective modes are discussed.Comment: 16 pages, 6 figure
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