Kruskal coordinates as canonical variables for Schwarzschild black holes

We derive a transformation from the usual ADM metric-extrinsic curvature variables on the phase space of Schwarzschild black holes, to new canonical variables which have the interpretation of Kruskal coordinates. We explicitly show that this transformation is non-singular, even at the horizon. The constraints of the theory simplify in terms of the new canonical variables and are equivalent to the vanishing of the canonical momenta. Our work is based on earlier seminal work by Kuchar in which he reconstructed curvature coordinates and a mass function from spherically symmetric canonical data. The key feature in our construction of a nonsingular canonical transformation to Kruskal variables, is the scaling of the curvature coordinate variables by the mass function rather than by the mass at left spatial infinity.Comment: 18 pages, no figure

Dehydrogenation of Isopropyl Alcohol on Zinc Molybdate (ZnMoO4)

851-85

Catalytic Decomposition of Formic Acid on Zinc Molybdate

202-20

Polymer Parametrised Field Theory

Free scalar field theory on 2 dimensional flat spacetime, cast in diffeomorphism invariant guise by treating the inertial coordinates of the spacetime as dynamical variables, is quantized using LQG type `polymer' representations for the matter field and the inertial variables. The quantum constraints are solved via group averaging techniques and, analogous to the case of spatial geometry in LQG, the smooth (flat) spacetime geometry is replaced by a discrete quantum structure. An overcomplete set of Dirac observables, consisting of (a) (exponentials of) the standard free scalar field creation- annihilation modes and (b) canonical transformations corresponding to conformal isometries, are represented as operators on the physical Hilbert space. None of these constructions suffer from any of the `triangulation' dependent choices which arise in treatments of LQG. In contrast to the standard Fock quantization, the non- Fock nature of the representation ensures that the algebra of conformal isometries as well as that of spacetime diffeomorphisms are represented in an anomaly free manner. Semiclassical states can be analysed at the gauge invariant level. It is shown that `physical weaves' necessarily underly such states and that such states display semiclassicality with respect to, at most, a countable subset of the (uncountably large) set of observables of type (a). The model thus offers a fertile testing ground for proposed definitions of quantum dynamics as well as semiclassical states in LQG.Comment: 44 pages, no figure

Polymer quantization of the free scalar field and its classical limit

Building on prior work, a generally covariant reformulation of free scalar field theory on the flat Lorentzian cylinder is quantized using Loop Quantum Gravity (LQG) type `polymer' representations. This quantization of the {\em continuum} classical theory yields a quantum theory which lives on a discrete spacetime lattice. We explicitly construct a state in the polymer Hilbert space which reproduces the standard Fock vacuum- two point functions for long wavelength modes of the scalar field. Our construction indicates that the continuum classical theory emerges under coarse graining. All our considerations are free of the "triangulation" ambiguities which plague attempts to define quantum dynamics in LQG. Our work constitutes the first complete LQG type quantization of a generally covariant field theory together with a semi-classical analysis of the true degrees of freedom and thus provides a perfect infinite dimensional toy model to study open issues in LQG, particularly those pertaining to the definition of quantum dynamics.Comment: 58 page

Alkylation of aromatic substrates with methanol on heteropolyoxometalate

246-25

I/O-Efficient Algorithms for Contour Line Extraction and Planar Graph Blocking

For a polyhedral terrain C, the contour at z-coordinate h, denoted Ch, is defined to be the intersection of the plane z = h with C. In this paper, we study the contour-line extraction problem, where we want to preprocess C into a data structure so that given a query z-coordinate h, we can report Ch quickly. This is a central problem that arises in geographic information systems (GIS), where terrains are often stored as Triangular Irregular Networks (TINS). We present an I/O-optimal algorithm for this problem which stores a terrain C with N vertices using O(N/B) blocks, where B is the size of a disk block, so that for any query h, the contour ch can be computed using o(log, N + I&l/B) I/O operations, where l&l denotes the size of Ch. We also present en improved algorithm for a more general problem of blocking bounded-degree planar graphs such as TINS (i.e., storing them on disk so that any graph traversal algorithm can traverse the graph in an I/O-efficient manner), and apply it to two problms that arise in GIS

Synthetic experiments in the benzopyrone series. Part XXI. Isomerisation of C-(6 or 8)-methyl-5: 7-dihydroxy chromones

This article does not have an abstract

The graviton vacuum as a distributional state in kinematic Loop Quantum Gravity

The quantum behaviour of weak gravitational fields admits an adequate, albeit approximate, description by those graviton states in which the expectation values and fluctuations of the linearised gravitational field are small. Such states must approximate corresponding states in full quantum gravity. We analyse the nature of this approximation for the graviton vacuum state in the context of kinematical Loop Quantum Gravity (LQG) wherein the constraints are ignored. We identify the graviton vacuum state with kinematically non-normalizable, distributional states in LQG by demanding that relations between linearised operator actions on the former are mirrored by those of their non-linear counterparts on the latter. We define a semi- norm on the space of kinematical distributions and show that the identification is approximate upto distributions which are small in this semi-norm. We argue that our candidate states are annihilated by the linearised constraints (expressed as operators in the full theory) to leading order in the parameter characterising the approximation. This suggests the possibility, in a scheme such as ours, of solving the full constraints order by order in this parameter. The main drawback of our considerations is that they depend on certain auxilliary constructions which, though mathematically well defined, do not arise from physical insight. Our work is an attempt to implement an earlier proposal of Iwasaki and Rovelli.Comment: 44 pages, no figure

Dirac Constraint Quantization of a Dilatonic Model of Gravitational Collapse

We present an anomaly-free Dirac constraint quantization of the string-inspired dilatonic gravity (the CGHS model) in an open 2-dimensional spacetime. We show that the quantum theory has the same degrees of freedom as the classical theory; namely, all the modes of the scalar field on an auxiliary flat background, supplemented by a single additional variable corresponding to the primordial component of the black hole mass. The functional Heisenberg equations of motion for these dynamical variables and their canonical conjugates are linear, and they have exactly the same form as the corresponding classical equations. A canonical transformation brings us back to the physical geometry and induces its quantization.Comment: 37 pages, LATEX, no figures, submitted to Physical Review