Periodic nano-textures enhance efficiency in multi-junction silicon thin-film solar cells

n this work, we report on the prototyping of thin-film silicon tandem solar cells with periodic light-trapping textures. Our approach combines an industrial applicable nano-imprint process, for the fabrication of advanced light management concepts, with state-of-the-art thin film silicon solar cell technology. In a joint experimental effort between project partners of the European thin-film silicon project “Fast-Track”, we demonstrate that optimal periodic light-trapping nano-textures at the front-side of a multi-junction solar cell enhance the power conversion efficiency of the device in comparison to solar cells with conventional textured TCO (transparent conductive oxide) front contacts from 11.7% to 12.1%. This improved power conversion efficiency is mainly driven by an enhancement of the short-circuit current density through the use of periodic light-trapping nano-textures

Methanethiol Consumption and Hydrogen Sulfide Production by the Thermoacidophilic Methanotroph Methylacidiphilum fumariolicum SolV

Methanotrophs aerobically oxidize methane to carbon dioxide to make a living and are known to degrade various other short chain carbon compounds as well. Volatile organic sulfur compounds such as methanethiol (CH3SH) are important intermediates in the sulfur cycle. Although volatile organic sulfur compounds co-occur with methane in various environments, little is known about how these compounds affect methanotrophy. The enzyme methanethiol oxidase catalyzing the oxidation of methanethiol has been known for decades, but only recently the mtoX gene encoding this enzyme was identified in a methylotrophic bacterium. The presence of a homologous gene in verrucomicrobial methanotrophs prompted us to examine how methanotrophs cope with methanethiol. Here, we show that the verrucomicrobial methanotroph Methylacidiphilum fumariolicum SolV consumes methanethiol and produces H2S, which is concurrently oxidized. Consumption of methanethiol is required since methanethiol inhibits methane oxidation. Cells incubated with ∼15 μM methanethiol from the start clearly showed inhibition of growth. After depletion of methanethiol, growth resumed within 1 day. Genes encoding a putative methanethiol oxidase were found in a variety of methanotrophs. Therefore, we hypothesize that methanethiol degradation is a widespread detoxification mechanism in methanotrophs in a range of environments.ISSN:1664-302

2-D Periodic and Random-on-Periodic Front Textures for Tandem Thin-Film Silicon Solar Cells

We evaluate the performance of thin-film silicon micromorph tandem solar cells deposited on transparent superstrates with embossed micrometer-scale 2-D gratings. Once coated with a thin conductive layer of hydrogenated indium oxide, the textured superstrates can be used as 2-D periodic single-texture front electrodes. Combining these almost loss-free front electrodes with a highly transparent, random self-textured zinc oxide layer (with a thickness 1 um) deposited by low-pressure chemical vapor deposition (LPCVD), we obtain double-texture transparent front electrodes. The potential of both single- and double-texture front electrodes is estimated by varying the illumination spectrum of the solar simulator, thereby assessing the maximum efficiency of the tandem cells under optimal current-matching conditions. Our results demonstrate the complementary roles of the 2-D gratings and the LPCVD-ZnO layers in double textures: Cell efficiencies as high as with our state-of-the-art 2.3-um-thick LPCVD-ZnO front electrode are obtained with significantly reduced ZnO layer thicknesses. Additionally, we show that equivalent efficiencies are also within reach with 2-D periodic single textures if the proper cell configuration is applied