PREPARACIÓN DE COMPLEJOS DE COBRE DE 1-MONOSUSTITUIDOS-3-BENZOILTIOUREA LIGANDOS.

Ligands type 1-monosustituted-3-benzoylthiourea were prepared using the Hartman-Reuther Method. The copper complexes prepared from these ligands were characterized by ESR, 1 R, and Electronic S pectroscopy, Differential Thermical Analysis, and elemental analysis. These ligands have shown unexpected behavior, forming Copper (11) complexes in which their both N-H groups, were probably deprotonized, with a polymeric structure.Ligandos del tipo 3-Be.nzoiltiourea-1-monosustituidas fueron preparados por el Método de Hartman-Reuther. Los complejos de cobre sintetizados a partir de estos ligandos fueron caracterizados por ESR, Espectroscopías IR, Espectroscopía Electrónica, y Análisis Térmico Diferencial. Los ligandos obtenidos presentaron un comportamiento inesperado, al formar complejos de Cobre (II) en los cuales sus dos grupos N-H están probablemente desprotonados con una estructura polimérica

Traffic air pollution monitoring based on an air-water pollutants deposition device

An air water surface sampler device was developed and used to evaluate the atmosphere deposition due to the urban traffic air pollution in the business center of a mid-sized city. The indicator adopted to assess the cumulative air pollutant deposition in the surface of the device was the electric conductivity that was measured on a regular basis during the experiment. Additionally a digital camera was used to count the passing traffic in the road of the study site. Water samples were also taken from the device reservoir and dissolved metals concentrations (Cooper, Iron and Zinc) and acidity/alcalinity were determined in the laboratory. The obtained results were compiled and analyzed in order to evaluate the performance of the device and the relation between the atmospheric deposition and the traffic activity under different meteorological conditions. The research successfully proved that the device was able to evaluate the impact of pollutant emissions related to city traffic. It was also proved that electric conductivity can be used as an indicator to evaluate the cumulative deposition of air pollutants from road traffic. A significant correlation (Spearman rank) between the accumulated traffic and electric conductivity (dry period: ϱ= 0.991626 and wet period: ϱ= 0.810526) was observed.The authors gratefully acknowledge to Erasmus Mundus ECW EUROASIA-lot 12 (REF. 2009-1797) for the financial support granted through a scholarship for the Urban Engineering Master Course, to the Territory Environment and Construction Research Centre of University of Minho for the use of laboratory facilities, and to the school staff of the study site for their cooperation during the installation of equipment for this research. The authors gratefully acknowledge to anonymous reviewers for their important contributions to the final version of the paper