Metal-Organic Frameworks for Metal-Ion Batteries: Towards Scalability

Metal-organic frameworks (MOFs), being a family of highly crystalline and porous materials, have attracted particular attention in material science due to their unprecedented chemical and structural tunability. Next to their application in gas adsorption, separation, and storage, MOFs also can be utilized for energy transfer and storage in batteries and supercapacitors. Based on recent studies, this review describes the latest developments about MOFs as structural elements of metal-ion battery with a focus on their industry-oriented and large-scale production

Multifold Emission Enhancement in Nanoimprinted Hybrid Perovskite Metasurfaces

Recent developments in the physics of high-index resonant dielectric nanostructures suggest alternative mechanisms for subwavelength light control driven by Mie resonances with a strong magnetic response that can be employed for the design of novel optical metasurfaces. Here we demonstrate metasurfaces based on nanoimprinted perovskite films optimized by alloying the organic cation part of perovskites. We reveal that such metasurfaces can exhibit a significant enhancement of both linear and nonlinear photoluminescence (up to 70 times) combined with advanced stability. Our results suggest a cost-effective approach based on nanoimprint lithography and combined with simple chemical reactions for creating a new generation of functional metasurfaces that may pave the way toward highly efficient planar optoelectronic metadevicesThe work was partially supported by the Australian Research Council. Partial financial support from the Ministry of Education and Science of the Russian Federation (Grant No. 14.Y26.31.0010 for optical measurements) and in the framework of Increase Competitiveness Program of NUST “MISiS” (No. K2-2015-014 for sample preparation) is acknowledged. We also appreciate the partial support from the Welch Foundation grant AT 16-17 and CONACYT for academic opportunities and support (visiting research of A.C.P.)

Nanoscale Generation of White Light for Ultrabroadband Nanospectroscopy

Achieving efficient localization of white light at the nanoscale is a major challenge due to the diffraction limit, and nanoscale emitters generating light with a broadband spectrum require complicated engineering. Here we suggest a simple, yet highly efficient, nanoscale white-light source based on a hybrid Si/Au nanoparticle with ultrabroadband (1.3-3.4 eV) spectral characteristics. We incorporate this novel source into a scanning-probe microscope and observe broadband spectrum of photoluminescence that allows fast mapping of local optical response of advanced nanophotonic structures with submicron resolution, thus realizing ultrabroadband near-field nanospectroscopy.The work was partially supported by the Russian Science Foundation (Grant 17-19-01532 for nanoparticles fabrication), the Ministry of Education and Science of Russian Federation (Project 14.Y26.31.0010 for optical measurements), the Australian Research Council, and A*STAR SERC Pharos program, Grant 152 73 00025 (Singapore)

Response to comment “On the existence of excitonic signatures in the optical response of metal–organic frameworks”

\u3cp\u3eThis is a response to a comment on the interpretation of the origin of the nonlinear changes of optical properties of van der Waals' metal–organic frameworks (MOFs). The concerns are addressed by clarifying potential pitfalls in density functional theory (DFT) simulations, careful analysis of prior literature, and additionally discussing the previous experimental results to emphasize the applicability of the excitonic concept in molecular crystals, such as MOFs.\u3c/p\u3