Separation of Radioactive Elements from Ethiopian Kenticha Pegmatite Ore by Hydrometallurgical Methods

The leaching and extraction behavior of uranium and thorium from a high-grade Ethiopian pegmatite ore in a mixture of hydrofluoric acid and sulfuric acid has been investigated. The effects of variables such as the temperature, particle size, acid concentration, and leaching time were studied. The leaching efficiency of uranium increased with increasing temperature to 150°C, at which 96% removal of uranium was achieved. Particles in the size range of − 100 + 75 μm resulted in the highest leaching of uranium, while formation of a colloidal suspension was observed when using a fine particle size fraction (− 75 μm). The dissolution of uranium increased with increasing leaching time. No significant systematic dependence of the leachability of thorium on the above variables was observed. Optimum extraction of uranium and thorium using D2EHPA was obtained when using aqueous/organic phase volume ratio of 1:1, solvent concentration of 0.3 M, and contact time of 20 min

High field superconducting properties of Ba(Fe1−xCox)2As2 thin films

In general, the critical current density, J(c), of type II superconductors and its anisotropy with respect to magnetic field orientation is determined by intrinsic and extrinsic properties. The Fe-based superconductors of the ‘122’ family with their moderate electronic anisotropies and high yet accessible critical fields (H(c2) and H(irr)) are a good model system to study this interplay. In this paper, we explore the vortex matter of optimally Co-doped BaFe(2)As(2) thin films with extended planar and c-axis correlated defects. The temperature and angular dependence of the upper critical field is well explained by a two-band model in the clean limit. The dirty band scenario, however, cannot be ruled out completely. Above the irreversibility field, the flux motion is thermally activated, where the activation energy U(0) is going to zero at the extrapolated zero-kelvin H(irr) value. The anisotropy of the critical current density J(c) is both influenced by the H(c2) anisotropy (and therefore by multi-band effects) as well as the extended planar and columnar defects present in the sample