Synthesis of 2-azidoethyl α-d-mannopyranoside orthogonally protected and selective deprotections

4 páginas, 1 figura, 2 esquemas.We present the synthesis of a fully orthogonally protected mannosyl glycoside 1 and the corresponding methods for selective deprotections. Mannosyl glycoside 1 contains a functionalized linker at the anomeric position to allow for the attachment of carbohydrate units to scaffolds in order to prepare carbohydrate multivalent systems.We would like to thank FIS (PI030093), for financial supportPeer reviewe

Working passionately does not always pay off : the negative moderating role of passion on the relationship between deliberate practice and venture performance

Deliberate practice, an iterative process that leads to expertise, is found to be positively associated with superior performance in domains such as sports, education, and entrepreneurship. At the same time, deliberate practice is also seen as being less than enjoyable and difficult to pursue consistently. As such, passion is considered to be a vital motivator of engagement in and maintenance of deliberate practice. Despite the evident importance of passion, the relationship between passion and deliberate practice in entrepreneurship has not been subject to sufficient empirical evaluation. Therefore, in this study, we consider the way in which passion moderates the relationship between deliberate practice and venture performance. We hypothesize that deliberate practice is positively related to venture performance and that passion positively moderates this relationship. We find support for our first hypothesis, in line with previous studies. However, contrary to our second hypothesis, we find that entrepreneurial passion negatively moderates the deliberate practice-venture performance relationship. In response to this finding, we provide possible explanations as to why this negative moderation effect was observed by drawing on Kolb’s experiential learning cycle

π - ω interference in the reactions K- p → π+ π- (Λ, ε{lunate}0) at 4.2 GeV/ c

π - ω interference is studied in the reactions K- p → π+ π- (Λ0, ε{lunate}) at 4.2 GeV/c using data from a high statistics experiments in the CERN 2m HBC. The phenomenon is analysed in terms of the conventional formalism as well as in terms of a new model for π - ω interference proposed by Earles and Srivastava. Satisfactory agreement with the data is found for both models. The rate of ω → 2π obtained in the latter model is in agreement with the VMD (Vector Meson Dominance) prediction for ω → γ → ρ{variant} → 2π. © 1977

π - ω interference in the reactions K- p → π+ π- (Λ, ε{lunate}0) at 4.2 GeV/ c

π - ω interference is studied in the reactions K- p → π+ π- (Λ0, ε{lunate}) at 4.2 GeV/c using data from a high statistics experiments in the CERN 2m HBC. The phenomenon is analysed in terms of the conventional formalism as well as in terms of a new model for π - ω interference proposed by Earles and Srivastava. Satisfactory agreement with the data is found for both models. The rate of ω → 2π obtained in the latter model is in agreement with the VMD (Vector Meson Dominance) prediction for ω → γ → ρ{variant} → 2π. © 1977

Ω- produced in K-p reactions at 4.2 GeV/c

Forty Ω- events have been observed in a large (133 events/βb) experiment at 4.2 GeV/c incident K- momentum. Thirty nine of the events come from the three-body reaction K-p→Ω-K+K0. The Ω- is mainly produced in the forward hemisphere (direction of the incident K-). The lifetime is measured to be τ = (0.75 +0.14-0.11 × 10-10 sec substantially less than the Particle Data Group value of (1.3 -0.3+0.2) × 10-10 sec. The mass is determined to be 1671.7 ± 0.6 MeV, in good agreement with other determinations. The decay asymmetry parameter α (for the decay mode Ω- → ΛK-) is found to be -0.2 ± 0.4. © 1978

Ω- produced in K-p reactions at 4.2 GeV/c

Forty Ω- events have been observed in a large (133 events/βb) experiment at 4.2 GeV/c incident K- momentum. Thirty nine of the events come from the three-body reaction K-p→Ω-K+K0. The Ω- is mainly produced in the forward hemisphere (direction of the incident K-). The lifetime is measured to be τ = (0.75 +0.14-0.11 × 10-10 sec substantially less than the Particle Data Group value of (1.3 -0.3+0.2) × 10-10 sec. The mass is determined to be 1671.7 ± 0.6 MeV, in good agreement with other determinations. The decay asymmetry parameter α (for the decay mode Ω- → ΛK-) is found to be -0.2 ± 0.4. © 1978