Electrodeposition of Zn-​Ni alloy from an acid sulfate bath containing ethanolamines

Electrodeposition of Zn-​Ni alloy contg. 10-​15​% Ni was carried out from an acid sulfate bath contg. ethanolamines. The effect of plating variables - such as metal ion ratio in the bath, pH, c.d., temp., stirring, concn. of ethanolamines in the bath and thickness - on the alloy compn. and cathodic c.d. was studied. The phase structure and the surface morphol. of electrodeposited Zn-​Ni alloy (SEM) and harness (on Vicker's scale) are reported

Ethyl 4-(3-hydroxy­phen­yl)-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexa­hydro­quinoline-3-carboxyl­ate

In the mol­ecular structure of the title compound, C21H25NO4, the dihydro­pyridine ring adopts a flattened boat conformation while the cyclo­hexenone ring is in an envelope conformation. In the crystal structure, mol­ecules are linked into a two-dimensional network parallel to (10) by N—H⋯O and O—H⋯O hydrogen bonds. The network is generated by R 4 4(30) and R 4 4(34) graph-set motifs

3-Ethyl-4-methyl-1H-pyrazol-2-ium-5-olate

The title compound, C6H10N2O, is a zwitterionic pyrazole derivative. The crystal packing is predominantly governed by a three-center iminium–amine N+—H⋯O−⋯H—N inter­action, leading to an undulating sheet-like structure lying parallel to (100)

Dimethyl 4-(3-hydroxy­phen­yl)-2,6-dimethyl-1,4-dihydro­pyridine-3,5-dicarboxyl­ate

The 1,4-dihydro­pyridine ring in the title compound, C17H19NO5, has a flattened-boat conformation, and the benzene ring is almost orthogonal to it [dihedral angle = 82.98 (12)°]. The hydr­oxy group is disordered over two positions in a 0.780 (4):0.220 (4) ratio. In the crystal, hydrogen-bonding inter­actions of the type Na—H⋯Oc and Oh—H⋯Oc (a = amine, c = carbonyl and h = hydr­oxy) link the mol­ecules into a three-dimensional network

(2E)-3-(4-Bromo­phen­yl)-1-(2-methyl-4-phenyl-3-quinol­yl)prop-2-en-1-one

The conformation about the ethene bond [1.316 (3) Å] in the title compound, C25H18BrNO, is E. The quinoline ring forms dihedral angles of 67.21 (10) and 71.68 (10)° with the benzene and bromo-substituted benzene rings, respectively. Highlighting the non-planar arrangement of aromatic rings, the dihedral angle formed between the benzene rings is 58.57 (12)°

Ethyl 2-acetyl-3-(4-chloro­anilino)butanoate

The title compound, C14H18ClNO3, adopts an extended conformation, with all of the main chain torsion angles associated with the ester and amino groups trans. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds are observed

4-(4-Chloro­phen­yl)-N-[(E)-4-(dimethyl­amino)­benzyl­idene]-1,3-thia­zol-2-amine

The title compound, C18H16ClN3S, adopts an extended mol­ecular structure. The thia­zole ring is inclined by 9.2 (1) and 15.3 (1)° with respect to the chloro­phenyl and 4-(dimethyl­amino)­phenyl rings, respectively, while the benzene ring planes make an angle of 19.0 (1)°. A weak inter­molecular C—H⋯π contact is observed in the crystal structure

1,1′-(p-Phenyl­enedimethyl­ene)dipiperidin-4-one

In the mol­ecule of the title compound, C18H24N2O2, the piperidine rings are in chair conformations. The crystal structure is stabilized by inter­molecular C—H⋯O hydrogen bonding. There are neither C—H⋯π nor π–π inter­actions in the structure

1,1′-[4-(2-Methoxyphenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-diyl]diethanone

In the title compound, C18H21NO3, the 1,4-dihydro­pyridine ring exhibits a flattened boat conformation. The methoxy­phenyl ring is nearly planar [r.m.s. deviation = 0.0723 (1) Å] and is perpendicular to the base of the boat [dihedral angle = 88.98 (4)°]. Inter­molecular N—H⋯O and C—H⋯O hydrogen bonds exist in the crystal structure

3,3,6,6-Tetra­methyl-9-phenyl-3,4,5,6-tetra­hydro-9H-xanthene-1,8(2H,7H)-dione

In the title compound, C23H26O3, the three six-membered rings of the xanthene system are non-planar, having total puckering amplitudes, Q T, of 0.443 (2), 0.202 (2) and 0.449 (2) Å. The central ring adopts a boat conformation and the outer rings adopt sofa conformations. The crystal structure is stabilized by van der Waals inter­actions