Suppressed superconductivity in ultrathin Mo2N films due to pair-breaking at the interface

A strong disorder characterized by a small product of the Fermi vector kF and the electron mean free l drives superconductors towards insulating state. Such disorder can be introduced by making the films very thin. Here, we present 3-nm Mo2N film with k_F*l ~ 2 with a resistive superconducting transition temperature Tc = 2 K heavily suppressed in comparison with the bulk Tc. Superconducting density of states (DOS) with smeared gap-like peaks and in-gap states, so called Dynes DOS, is observed by the low temperature tunneling spectroscopy despite a sharp resistive transition. By scanning tunneling microscope the spectral maps are obtained and related to the surface topography. The maps show a spatial variation of the superconducting energy gap on the order of 20 % which is not accidental but well correlates with the surface corrugation: protrusions reveal larger gap, smaller spectral smearing and smaller in-gap states. In agreement with our previous measurements on ultrathin MoC films we suggest that the film-substrate interface introducing the local pair-breaking is responsible for the observed effects and generally for the suppression of the superconductivity in these ultrathin films.Comment: Manuscript with 3 Figure

Persistent Oscillations of X-ray Speckles: Pt (001) Step Flow

We have performed coherent x-ray scattering experiments on the hexagonally reconstructed Pt (001) surface to study the temperature-dependent surface dynamics. By correlating speckle patterns collected at the (001) anti-Bragg position we are able to measure surface dynamics when the averaged incoherent x-ray scattering appears static. In the temperature range above the rotational epitaxy transition and below the roughening transition (1750 K - 1830 K), we have observed well-defined oscillatory autocorrelations of speckles that persist for tens of minutes, in addition to the expected thermal decorrelation. The observed oscillations indicate surface dynamics due to "step-flow" motion. This is shown with a simple model in which the phase of the scattered x-rays from the steps within the illumination area is retained in the coherent x-ray scattering. This demonstrates a possibility that x-ray speckles can be used to monitor the real-space real-time evolution of surfaces in addition to the traditional decorrelation measurements.Comment: 12 pages, 3 figure

Disorder- and magnetic field-tuned fermionic superconductor-insulator transition in MoN thin films. Transport and STM studies

Superconductor-insulator transition (SIT) driven by disorder and transverse magnetic field has been investigated in ultrathin MoN films by means of transport measurements and scanning tunneling microscopy and spectroscopy. Upon decreasing thickness, the homogeneously disordered films show increasing sheet resistance Rs, shift of the superconducting transition Tc to lower temperatures with the 3 nm MoN being the last superconducting film and thinner films already insulating. Fermionic scenario of SIT is evidenced by applicability of the Finkelsteins model, by the fact that Tc and the superconducting gap are coupled with a constant ratio, and by the spatial homogeneity of the superconducting and electronic characteristics. The logarithmic anomaly found in the tunneling spectra of the non-superconducting films is further enhanced in increased magnetic field due to the Zeeman spin effects driving the system deeper into the insulating state and pointing also to fermionic SIT.Comment: Manuscript (6 Figures) including Supplemental Materials (7 Figures

Controlling the Transverse Magneto-Optical Kerr Effect in Cr/NiFe Bilayer Thin Films by Changing the Thicknesses of the Cr Layer

Here, we demonstrate the impact of ferromagnetic layer coating on controlling the magneto-optical response. We found that the transverse magneto-optical Kerr effect (TMOKE) signal and TMOKE hysteresis loops of Ni80Fe20 thin layers coated with a Cr layer show a strong dependence on the thickness of the Cr layer and the incidence angle of the light. The transmission and reflection spectra were measured over a range of incidence angles and with different wavelengths so as to determine the layers’ optical parameters and to explain the TMOKE behavior. The generalized magneto-optical and ellipsometry (GMOE) model based on modified Abeles characteristic matrices was used to examine the agreement between the experimental and theoretical results. A comprehensive theoretical and experimental analysis reveals the possibility to create a TMOKE suppression/enhancement coating at specific controllable incidence angles. This has potential for applications in optical microscopy and sensors

CO-induced lifting of Au (001) surface reconstruction

We report CO-induced lifting of the hexagonal surface reconstruction on Au (001). Using in-situ surface x-ray scattering, we determined a pressure-temperature phase diagram for the reconstruction and measured the dynamical evolution of the surface structure in real time. Our observations provide evidence that, under certain conditions, even macroscopic Au surfaces, much larger than catalytic Au nanoparticles [M. Haruta, Catal. Today 36, 153 (1997)], can exhibit some of the reactive properties and surface transitions observed in systems known to be catalytically active such as Pt (001).Comment: 4 Figures. Accepted as a Letter to Journal of Physical Chemistry

Anizotropy of Photoconductivity in BiOCl (X=Cl, Br, I) Single Crystals

Oxyhalides of bismuth BiOX (X = Cl, Br, I) are very interesting materials which find various applications as X-ray luminescent screens, as anti-Stokes converters, photocatalyst, usual luminophors and as photoconductive analyzer of linear polarized radiation in the 0.24 - 1.2 μm spectral region. The great interest for these materials is strongly related to the influence of dimensionality on the behaviour of physical properties (they are 2D structured materials). Bismuth oxyhalides are one of the V-VI-VII group compound semiconductors belonging to the tetragonal system. The structure of BiOX is known to have a layered structure, which is constructed by the combination of the halide ion layer and the bismuth oxygen layer. We present results of the study of photoconductivity spectra anisotropy of the BiOX single crystals