bending damages in galvanized ductile cast irons

Abstract Ductile cast irons (DCIs) are characterized by mechanical properties close to low and medium carbon steels. Carbon atoms are mainly localized in graphite nodules, which are dispersed in a metallic matrix. The microstructure of metallic matrix can be ferritic, austenitic, pearlitic, martensitic or their mix, depending on chemical composition and heat treatment. Thanks to the high castability and low production costs, DCIs are used in many fields (e.g., automotive and pipes). The wide utilization of DCIs in many fields and critical application leads to particular attention to the corrosion phenomenon. Hot dip galvanizing is one of most important protection process, used to protect metallic materials (mainly steels) against corrosion in many aggressive environments. In this work, a ferritic-pearlitic DCI (GS500) was galvanized by using a pure Zn bath at 440°C to generate a zinc coating. Bending tests on galvanized specimen were performed to generate crack damage in the coating phases. The bending cracks path propagation in zinc coatings were observed using both a light optical microscope and scanning electron microscope. A damage parameter, defined as a number of radial crack for a millimeter of the deformed arc, was evaluated for each zinc coating intermetallic phases

grain size influence on fatigue behaviour in a cuznal pe sma

Abstract Due to their capability to recover the initial shape, Shape Memory Alloys (SMAs) are widely used in many applications. Different grades are commercially available and they can be classified considering either their chemical compositions (Cu based, Ni based, Fe based and so on..) or according to their mechanical behaviour. The most used SMAs are the Ni based alloys thanks to their performances both in terms of mechanical resistance and in terms of fatigue resistance, but their costs are quite high. Cu based alloys are good competitors of the Ni based alloys. The recent optimization of their chemical composition improved both the corrosion resistance in aggressive environments and their mechanical performances. In this work, the influence of the grain size on fatigue crack propagation in two Cu-Zn-Al SMAs focusing on the damaging micromechanisms

Crack path and damage in a CuZnAl SMA

Abstract: Pseudo-elastic (PE) materials are an important class of metallic alloy which exhibit unique features with respect to common engineering metals. In particular, due to these properties PEs are able to recover their original shape after high values of mechanical deformations, by removing the mechanical load (PE). From the microstructural point of view shape memory and pseudo-elastic effects are due to a reversible solid state microstructural diffusionless transitions from austenite to martensite, which can be activated by mechanical and/or thermal loads. Copper-based shape memory alloys are preferred for their good memory properties and low cost of production. In this work the main crack initiation and its propagation in a tensile test is analyzed in order to evaluate crack path and its behavior at low and at high values of deformation. Results are also associated both to grains boundary chemical properties and to X-ray diffraction, in order to correlate structural transition involved in an Cu-Zn-Al alloy characterized by a PE behavior

Spin/orbit moment imbalance in the near-zero moment ferromagnetic semiconductor SmN

SmN is ferromagnetic below 27 K, and its net magnetic moment of 0.03 Bohr magnetons per formula unit is one of the smallest magnetisations found in any ferromagnetic material. The near-zero moment is a result of the nearly equal and opposing spin and orbital moments in the 6H5/2 ground state of the Sm3+ ion, which leads finally to a nearly complete cancellation for an ion in the SmN ferromagnetic state. Here we explore the spin alignment in this compound with X-ray magnetic circular dichroism at the Sm L2,3 edges. The spectral shapes are in qualitative agreement with computed spectra based on an LSDA+U (local spin density approximation with Hubbard-U corrections) band structure, though there remain differences in detail which we associate with the anomalous branching ratio in rare-earth L edges. The sign of the spectra determine that in a magnetic field the Sm 4f spin moment aligns antiparallel to the field; the very small residual moment in ferromagnetic SmN aligns with the 4f orbital moment and antiparallel to the spin moment. Further measurements on very thin (1.5 nm) SmN layers embedded in GdN show the opposite alignment due to a strong Gd-Sm exchange, suggesting that the SmN moment might be further reduced by about 0.5 % Gd substitution

A methodological approach of QRA for slow-moving landslides at a regional scale

Landslides represent a serious worldwide hazard, especially in Italy, where exposure to hydrogeological risk is very high; for this reason, a landslide quantitative risk assessment (QRA) is crucial for risk management and for planning mitigation measures. In this study, we present and describe a novel methodological approach of QRA for slow-moving landslides, aiming at national replicability. This procedure has been applied at the basin scale in the Arno River basin (9100 km(2), Central Italy), where most landslides are slow-moving. QRA is based on the application of the equation risk = hazard (H) × vulnerability (V) × exposure (E) and on the use of open data with uniform characteristics at the national scale. The study area was divided into a grid with a 1 km(2) cell size, and for each cell, the parameters necessary for the risk assessment were calculated. The obtained results show that the total risk of the study area amounts to approximately 7 billion €. The proposed methodology presents several novelties in the risk assessment for the regional/national scale of the analysis, mainly concerning the identification of the datasets and the development of new methodologies that could be applicable over such large areas. The present work demonstrates the feasibility of the methodology and discusses the obtained results

Thoracic surgery in the COVID-19 era: an Italian university hospital experience

BackgroundAims of this study were to assess the results of anti-COVID19 measures applied to maintain thoracic surgery activity at an Italian University institution through a 12-month period and to assess the results as compared with an equivalent non-pandemic time span.MethodsData and results of 646 patients operated on at the department of Thoracic Surgery of the Tor Vergata University Policlinic in Rome between February 2019 and March 2021 were retrospectively analyzed. Patients were divided in 2 groups: one operated on during the COVID-19 pandemic (pandemic group) and another during the previous non-pandemic 12 months (non-pandemic group). Primary outcome measure was COVID-19 infection-free rate.ResultsThree patients developed mild COVID-19 infection early after surgery resulting in an estimated COVID-19 infection-free rate of 98%. At intergroup comparisons (non-pandemic vs. pandemic group), a greater number of patients was operated before the pandemic (352 vs. 294, p = 0.0013). In addition, a significant greater thoracoscopy/thoracotomy procedures rate was found in the pandemic group (97/151 vs. 82/81, p = 0.02) and the total number of chest drainages (104 vs. 131, p = 0.0001) was higher in the same group. At surgery, tumor size was larger (19.5 13 vs. 28.2 +/- 21; p < 0.001) and T3-T4/T1-T2 ratio was higher (16/97 vs. 30/56; p < 0.001) during the pandemic with no difference in mortality and morbidity. In addition, the number of patients lost before treatment was higher in the pandemic group (8 vs. 15; p = 0.01). Finally, in 7 patients admitted for COVID-19 pneumonia, incidental lung (N = 5) or mediastinal (N = 2) tumors were discovered at the chest computed tomography.Conclusions Estimated COVID-19 infection free rate was 98% in the COVID-19 pandemic group; there were less surgical procedures, and operated lung tumors had larger size and more advanced stages than in the non-pandemic group. Nonetheless, hospital stay was reduced with comparable mortality and morbidity. Our study results may help implement efficacy of the everyday surgical care