Synthesis and properties of Co-doped titanate nanotubes and their optical sensitization with methylene blue

Here we report on a novel chemical route to synthesize homogenous cobalt doped titanate nanotubes (CoTNT), using an amorphous Co-doped precursor. The influence of the synthesis temperature, autoclave dwell time and metal doping on the structural and microstructural as well as on the optical properties of the synthesized titanate nanotubes is studied and discussed. The optical band gaps of the CoTNT samples are red shifted in comparison with the values determined for the undoped samples, such red shifts bringing the absorption edge of the CoTNT samples into the visible region. CoTNT materials also demonstrate particular high adsorption ability for methylene blue, the amount of the adsorbed dye being higher than the one predictable for a monolayer formation. This suggests the possibility of intercalation of the dye molecule between the TiO6 layers of the TNT structure. It is also shown that the methylene blue sensitized Co-doped nanostructures are highly stable under UV radiation and present a strong and broad absorption in the visible region.Comment: 31 pages, 3 tables, 7 figure

Integrable theories and loop spaces: fundamentals, applications and new developments

We review our proposal to generalize the standard two-dimensional flatness construction of Lax-Zakharov-Shabat to relativistic field theories in d+1 dimensions. The fundamentals from the theory of connections on loop spaces are presented and clarified. These ideas are exposed using mathematical tools familiar to physicists. We exhibit recent and new results that relate the locality of the loop space curvature to the diffeomorphism invariance of the loop space holonomy. These result are used to show that the holonomy is abelian if the holonomy is diffeomorphism invariant. These results justify in part and set the limitations of the local implementations of the approach which has been worked out in the last decade. We highlight very interesting applications like the construction and the solution of an integrable four dimensional field theory with Hopf solitons, and new integrability conditions which generalize BPS equations to systems such as Skyrme theories. Applications of these ideas leading to new constructions are implemented in theories that admit volume preserving diffeomorphisms of the target space as symmetries. Applications to physically relevant systems like Yang Mills theories are summarized. We also discuss other possibilities that have not yet been explored.Comment: 64 pages, 8 figure

Lorentz-breaking effects in scalar-tensor theories of gravity

In this work, we study the effects of breaking Lorentz symmetry in scalar-tensor theories of gravity taking torsion into account. We show that a space-time with torsion interacting with a Maxwell field by means of a Chern-Simons-like term is able to explain the optical activity in syncrotron radiation emitted by cosmological distant radio sources. Without specifying the source of the dilaton-gravity, we study the dilaton-solution. We analyse the physical implications of this result in the Jordan-Fierz frame. We also analyse the effects of the Lorentz breaking in the cosmic string formation process. We obtain the solution corresponding to a cosmic string in the presence of torsion by keeping track of the effects of the Chern-Simons coupling and calculate the charge induced on this cosmic string in this framework. We also show that the resulting charged cosmic string gives us important effects concerning the background radiation.The optical activity in this case is also worked out and discussed.Comment: 10 pages, no figures, ReVTex forma

Avaliação participativa de acessos de bucha vegetal.

Publicado também na Revista Brasileira de Agroecologia, v. 4, n. 2, 2009

Facing the complexity of grape quality management and delivering an highthroughput device: VinePAT

The physiological response of plants to external perturbation is complex and occurs at different levels of their metabolism. This is a multivariate and multi-scale phenomena, therefore high-throughput methodologies are required to extract relevant information. The nonexistence of a device with such characteristics constitutes a barrier to the interpretation of the consequences of external inputs. Spectroscopy is a multivariate methodology with greatest interest for metabolic studies in biological systems. In fact, this technique provides detailed information on the molecular structure and reaction mechanisms. Moreover due to its non-destructive character, this methodology is currently used to characterize proteins, peptides, lipids, membranes, carbohydrates in pharmaceuticals and food products as well as plants and animal tissues. VinePAT is a vineyard management system based in the Process Analytical Technologies (PAT) methodologies to provide winemakers with state-of-the-art metabolic images of vineyards for precision winemaking by using UV-VIS-SWNIR spectroscopy techniques. The system hardware is based on miniaturized fiber-optics spectrometer adapted for grape and leaves measurements and suited for outdoor data acquisition. Combining these georeferenced outdoor measurements collected at the vineyard with state-of-the-art spectroscopy signal processing, the winemaker will be able to observe vine metabolism by using a non-destructive 'in-vivo' methodology, as well as, the global-picture of the vineyard for implementing precision winemaking technologies based on process analytical technology. Here we demonstrate the potential of the VinePAT technology for grape-growers by presenting: i) spectroscopy equipment in action; ii) the variance imaging and zone diagnostics; iii) metabolic imaging with especial incidence in key metabolites for grape maturation; iv) how to use multivariate control charts; and v) the full potential of the technology deployed by process analytical technology.info:eu-repo/semantics/publishedVersio

Is it really possible to grow isotropic on-lattice diffusion-limited aggregates?

In a recent paper (Bogoyavlenskiy V A 2002 \JPA \textbf{35} 2533), an algorithm aiming to generate isotropic clusters of the on-lattice diffusion-limited aggregation (DLA) model was proposed. The procedure consists of aggregation probabilities proportional to the squared number of occupied sites ($k^2$). In the present work, we analyzed this algorithm using the noise reduced version of the DLA model and large scale simulations. In the noiseless limit, instead of isotropic patterns, a $45^\circ$ ($30^\circ$) rotation in the anisotropy directions of the clusters grown on square (triangular) lattices was observed. A generalized algorithm, in which the aggregation probability is proportional to $k^\nu$, was proposed. The exponent $\nu$ has a nonuniversal critical value $\nu_c$, for which the patterns generated in the noiseless limit exhibit the original (axial) anisotropy for $\nu<\nu_c$ and the rotated one (diagonal) for $\nu>\nu_c$. The values $\nu_c = 1.395\pm0.005$ and $\nu_c = 0.82\pm 0.01$ were found for square and triangular lattices, respectively. Moreover, large scale simulations show that there are a nontrivial relation between noise reduction and anisotropy direction. The case $\nu=2$ (\bogo's rule) is an example where the patterns exhibit the axial anisotropy for small and the diagonal one for large noise reduction.Comment: 12 pages, 8 figure