The Charge-Transfer Motif in Crystal Engineering. Self-Assembly of Acentric (Diamondoid) Networks from Halide Salts and Carbon Tetrabromide as Electron-Donor/Acceptor Synthons

Unusual strength and directionality for the charge-transfer motif (established in solution) are shown to carry over into the solid state by the facile synthesis of a series of robust crystals of the [1:1] donor/acceptor complexes of carbon tetrabromide with the electron-rich halide anions (chloride, bromide, and iodide). X-ray crystallographic analyses identify the consistent formation of diamondoid networks, the dimensionality of which is dictated by the size of the tetraalkylammonium counterion. For the tetraethylammonium bromide/carbon tetrabromide dyad, the three-dimensional (diamondoid) network consists of donor (bromide) and acceptor (CBr4) nodes alternately populated to result in the effective annihilation of centers of symmetry in agreement with the sphaleroid structural subclass. Such inherently acentric networks exhibit intensive nonlinear optical properties in which the second harmonics generation in the extended charge-transfer system is augmented by the effective electronic (HOMO−LUMO) coupling between contiguous CBr4/halide centers

Representation Theory Approach to the Polynomial Solutions of q - Difference Equations : U_q(sl(3)) and Beyond,

A new approach to the theory of polynomial solutions of q - difference equations is proposed. The approach is based on the representation theory of simple Lie algebras and their q - deformations and is presented here for U_q(sl(n)). First a q - difference realization of U_q(sl(n)) in terms of n(n-1)/2 commuting variables and depending on n-1 complex representation parameters r_i, is constructed. From this realization lowest weight modules (LWM) are obtained which are studied in detail for the case n=3 (the well known n=2 case is also recovered). All reducible LWM are found and the polynomial bases of their invariant irreducible subrepresentations are explicitly given. This also gives a classification of the quasi-exactly solvable operators in the present setting. The invariant subspaces are obtained as solutions of certain invariant q - difference equations, i.e., these are kernels of invariant q - difference operators, which are also explicitly given. Such operators were not used until now in the theory of polynomial solutions. Finally the states in all subrepresentations are depicted graphically via the so called Newton diagrams.Comment: uuencoded Z-compressed .tar file containing two ps files

Pair creation and plasma oscillations

We describe aspects of particle creation in strong fields using a quantum kinetic equation with a relaxation-time approximation to the collision term. The strong electric background field is determined by solving Maxwell's equation in tandem with the Vlasov equation. Plasma oscillations appear as a result of feedback between the background field and the field generated by the particles produced. The plasma frequency depends on the strength of the initial background field and the collision frequency, and is sensitive to the necessary momentum-dependence of dressed-parton masses.Comment: 11 pages, revteX, epsfig.sty, 5 figures; Proceedings of 'Quark Matter in Astro- and Particlephysics', a workshop at the University of Rostock, Germany, November 27 - 29, 2000. Eds. D. Blaschke, G. Burau, S.M. Schmid

Phase Space Evolution and Discontinuous Schr\"odinger Waves

The problem of Schr\"odinger propagation of a discontinuous wavefunction -diffraction in time- is studied under a new light. It is shown that the evolution map in phase space induces a set of affine transformations on discontinuous wavepackets, generating expansions similar to those of wavelet analysis. Such transformations are identified as the cause for the infinitesimal details in diffraction patterns. A simple case of an evolution map, such as SL(2) in a two-dimensional phase space, is shown to produce an infinite set of space-time trajectories of constant probability. The trajectories emerge from a breaking point of the initial wave.Comment: Presented at the conference QTS7, Prague 2011. 12 pages, 7 figure

Mesoscopic to universal crossover of transmission phase of multi-level quantum dots

Transmission phase \alpha measurements of many-electron quantum dots (small mean level spacing \delta) revealed universal phase lapses by \pi between consecutive resonances. In contrast, for dots with only a few electrons (large \delta), the appearance or not of a phase lapse depends on the dot parameters. We show that a model of a multi-level quantum dot with local Coulomb interactions and arbitrary level-lead couplings reproduces the generic features of the observed behavior. The universal behavior of \alpha for small \delta follows from Fano-type antiresonances of the renormalized single-particle levels.Comment: 4 pages, version accepted for publication in PR

Average transmission probability of a random stack

The transmission through a stack of identical slabs that are separated by gaps with random widths is usually treated by calculating the average of the logarithm of the transmission probability. We show how to calculate the average of the transmission probability itself with the aid of a recurrence relation and derive analytical upper and lower bounds. The upper bound, when used as an approximation for the transmission probability, is unreasonably good and we conjecture that it is asymptotically exact.Comment: 10 pages, 6 figure

Influence of radiative damping on the optical-frequency susceptibility

Motivated by recent discussions concerning the manner in which damping appears in the electric polarizability, we show that (a) there is a dependence of the nonresonant contribution on the damping and that (b) the damping enters according to the "opposite sign prescription." We also discuss the related question of how the damping rates in the polarizability are related to energy-level decay rates