Preliminary activity on the pyrolysis of a plastic based solid recovered fuel

Plastic is a versatile, lightweight, resistant, and inexpensive material, and an increase of its global demand has been observed in the last years (from 299 milion tonnes in 2013 to 348 in 2017) [1], with the dominant role played by the packaging sector, which absorbs almost 40% of the overall production. Management of post–consumer plastic packaging waste poses a serious environmental problem, and a number of strategies have been devised to reuse/recover these materials, mainly with the aim of recovering useful materials and avoiding landfilling. Among these strategies, pyrolysis can play a significant role for recovering useful products and energy from the post–selection mixed packaging waste, that is not amenable to other uses [1]. A large amount of studies has been developed to assess the possibility to convert waste plastic to oil by pyrolysis processes [1] either catalytic or non catalytic. Nevertheless, only a limited numbers of papers refer to the use of real plastic waste rather than simulated mixtures [2] even if the performances obtained are strongly influenced by the feedstock characteristics. Please click Additional Files below to see the full abstract

Sewage Sludge Gasification in a Fluidized Bed: Experimental Investigation and Modeling

Fluidized bed gasification is a promising process technology to manage the growing amount of sewage sludge (SS) requiring disposal. Two samples of SS, produced in different seasons of the year by a municipal wastewater treatment plant, were subjected to gasification at 850 °C in a bench-scale fluidized bed reactor using, as a gasification agent, a nitrogen/air mixture at different values of oxygen/fuel equivalence ratio (ER = 0.1–0.2). The starting materials and the output streams (syngas, tar, and solid residues) were thoroughly characterized. The fate of specific SS constituents and the characteristics of bottom ashes were addressed, so contributing to the problem of a proper SS management approach in the context of the circular economy. Computer-aided simulations were also performed, which allowed us to predict the composition of the syngas from SS gasification under operating conditions different from those experimentally investigated (i.e., reactor temperature and ER)

Identification of single nucleotide polymorphisms in Toll-like receptor candidate genes associated with tuberculosis infection in water buffalo (Bubalus bubalis)

Toll-like receptors play a key role in innate immunity by recognizing pathogens and activating appropriate responses. Pathogens express several signal molecules (pathogen-associated molecular patterns, PAMPs) essential for survival and pathogenicity. Recognition of PAMPs triggers an array of anti-microbial immune responses through the induction of various inflammatory cytokines. The objective of this work was to perform a case-control study to characterize the distribution of polymorphisms in three candidate genes (toll-like receptor 2, toll-like receptor 4, toll-like receptor 9) and to test their role as potential risk factors for tuberculosis infection in water buffalo (Bubalus bubalis)

3D high-resolution hydrogel structures for biological studies

Hydrogels are widely used as matrices for cell growth due to the similarity of their mechanical and diffusivity properties to the extracellular matrix. The microfabrication of hydrogels into arbitrarily complex 3D structures is becoming essential for numerous biological applications. Among the possible additive manufacturing techniques, two-photon lithography stands out for its unique capacity of a direct 3D writing. We report fabrication of 3D high resolution hydrogel gelatin structures by Nanoscribe GT Photonic Professional. According to the degree of polymerization, variable swelling and structure deformation is observed. As a preliminary investigation to any biological application, the developed 3D hydrogels are tested against the requirements of cytocompatibility, promotion of cell adhesion and diffusion using BJ cell lines

Fatigue in Kidney Transplantation: A Systematic Review and Meta-Analysis

Fatigue is still present in up to 40–50% of kidney transplant recipients (KTR), the results of studies comparing the prevalence among patients on hemodialysis (HD) and KTR led to conflicting results. Fatigue correlates include inflammation, symptoms of depression, sleep disorders and obesity. Fatigue in KTR leads to significant functional impairment, it is common among KTR poorly adherent to immunosuppressive therapy and is associated with a serious deterioration of quality of life. The following databases were searched for relevant studies up to November 2020: Medline, PubMed, Web of Science and the Cochrane Library. Several studies have compared the prevalence and severity of fatigue between KTR and hemodialysis or healthy patients. They have shown that fatigue determines a significant functional deterioration with less chance of having a paid job and a significant change in quality of life. The aim of the review is to report methods to assess fatigue and its prevalence in KTR patients, compared to HD subjects and define the effects of fatigue on health status and daily life. There is no evidence of studies on the treatment of this symptom in KTR. Efforts to identify and treat fatigue should be a priority to improve the quality of life of KTR

Pyrolysis and Gasification of a Real Refuse-Derived Fuel (RDF): The Potential Use of the Products under a Circular Economy Vision

Refuse-Derived Fuels (RDFs) are segregated forms of wastes obtained by a combined mechanical–biological processing of municipal solid wastes (MSWs). The narrower characteristics, e.g., high calorific value (18–24 MJ/kg), low moisture content (3–6%) and high volatile (77–84%) and carbon (47–56%) contents, make RDFs more suitable than MSWs for thermochemical valorization purposes. As a matter of fact, EU regulations encourage the use of RDF as a source of energy in the frameworks of sustainability and the circular economy. Pyrolysis and gasification are promising thermochemical processes for RDF treatment, since, compared to incineration, they ensure an increase in energy recovery efficiency, a reduction of pollutant emissions and the production of value-added products as chemical platforms or fuels. Despite the growing interest towards RDFs as feedstock, the literature on the thermochemical treatment of RDFs under pyrolysis and gasification conditions still appears to be limited. In this work, results on pyrolysis and gasification tests on a real RDF are reported and coupled with a detailed characterization of the gaseous, condensable and solid products. Pyrolysis tests have been performed in a tubular reactor up to three different final temperatures (550, 650 and 750 °C) while an air gasification test at 850 °C has been performed in a fluidized bed reactor using sand as the bed material. The results of the two thermochemical processes are analyzed in terms of yield, characteristics and quality of the products to highlight how the two thermochemical conversion processes can be used to accomplish waste-to-materials and waste-to-energy targets. The RDF gasification process leads to the production of a syngas with a H2/CO ratio of 0.51 and a tar concentration of 3.15 g/m3