64 research outputs found

    A Historiometric Examination of Machiavellianism and a New Taxonomy of Leadership

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    Although researchers have extensively examined the relationship between charismatic leadership and Machiavellianism (Deluga, 2001; Gardner & Avolio, 1995; House & Howell, 1992), there has been a lack of investigation of Machiavellianism in relation to alternative forms of outstanding leadership. Thus, the purpose of this investigation was to examine the relationship between Machiavellianism and a new taxonomy of outstanding leadership comprised of charismatic, ideological, and pragmatic leaders. Using an historiometric approach, raters assessed Machiavellianism via the communications of 120 outstanding leaders in organizations across the domains of business, political, military, and religious institutions. Academic biographies were used to assess twelve general performance measures as well as twelve general controls and five communication specific controls. The results indicated that differing levels of Machiavellianism is evidenced across the differing leader types as well as differing leader orientation. Additionally, Machiavellianism appears negatively related to performance, though less so when type and orientation are taken into account.Yeshttps://us.sagepub.com/en-us/nam/manuscript-submission-guideline

    Interacting Like a Body

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    Hybrid Aromatic Fluoro Amine Modified SnO2 Electron Transport Layers in Perovskite Solar Cells for Enhanced Efficiency and Stability

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    SnO2 is a widely used electron transporting layer in perovskite solar cells. Despite the high compatibility with the perovskite absorber layers the presence of traps at the perovskite SnO2 interface results in performance losses, hence their modification to improve the performance and stability of PSCs is therefore important. In this study, we enhanced the SnO2 ETL by incorporating a bi functional aromatic amino fluorine molecule into the SnO2 precursor solution. The fluorine molecule was found to partially substitute the Sn and alter the energy levels while the aniline group aided in regulating the nucleation growth rate of the perovskite crystalline films. In this work, a hole transporting material free carbon based PSCs CPSCs was fabricated. We found that perovskite absorber layers deposited on these modified SnO2 hybrid layers have higher optoelectronic quality, resulting in enhanced photovoltaic performance, device stability, and reduced hysteresis in CPSCs. Devices made with the modified hybrid SnO2 layers exhibited PCEs of 15.6 significantly better than unmodified SnO2 with 13.5 . CPSCs with these modified SnO2 films also exhibited remarkable retention of 88.7 of their initial power conversion efficiency for a shelf life period ISOS D1I exceeding 1200 h. This study presents a generic approach to enhance the stability and performance of CPSCs by modifying the properties of the electron transport layer and, consequently, regulating the quality of the perovskite materia
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