12,029 research outputs found
Simulation of the Oxygen Reduction Reaction (ORR) Inside the Cathode Catalyst Layer (CCL) of Proton Exchange Membrane Fuel Cells Using the Kinetic Monte Carlo Method
In this paper, a numerical model of the kinetic Monte Carlo (KMC) method has been developed to study the oxygen reduction reaction (ORR) that occurs inside the cathode catalyst layer (CCL). Firstly, a 3-D model of the CCL that consists of Pt and carbon spheres is built using the sphere packing method; secondly, an efficient procedure of the proton-oxygen reaction process is developed and simulated. In the proton-oxygen reaction process, all of the continuous movements of protons and oxygen are considered. The maximum reaction distance is determined to be 8 â„«. The input pressures of protons and oxygen are represented by the number of spheres of the species. The value of the current density is calculated based on the amount of reaction during the interval time. Indications are that the results of the present model match reasonably well with the published results. A new way to apply the KMC method in the proton exchange membrane fuel cell (PEMFC) research field is developed in this paper
A new geometric approach to problems in birational geometry
A classical set of birational invariants of a variety are its spaces of
pluricanonical forms and some of their canonically defined subspaces. Each of
these vector spaces admits a typical metric structure which is also
birationally invariant. These vector spaces so metrized will be referred to as
the pseudonormed spaces of the original varieties. A fundamental question is
the following: given two mildly singular projective varieties with some of the
first variety's pseudonormed spaces being isometric to the corresponding ones
of the second variety's, can one construct a birational map between them which
induces these isometries? In this work a positive answer to this question is
given for varieties of general type. This can be thought of as a theorem of
Torelli type for birational equivalence.Comment: 13 pages, to appear in PNA
Economic Growth and Government Size in OECD Countries: New Evidence from the Quantile Regression Approach
The purpose of this paper is to employ the quantile regression methodology to investigate the relationship between government size and economic growth using a panel data set for 24 OECD countries. We find that the magnitude of the effect of government size on economic growth varies through the quantiles. When the economic growth is low, increasing the size of the government may have a positive effect and stimulate economic growth. However, as the economic growth rate increases, such an effect declines and has a negative effect on economic growth.Economic growth; Government size; Quantile regression
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Standardized maximim D-optimal designs for enzyme kineticinhibition models
Locally optimal designs for nonlinear models require a single set of nominal values for the unknown parameters.An alternative is the maximin approach that allows the user to specify a range of values for each parameter ofinterest. However, the maximin approach is difficult because we first have to determine the locally optimal designfor each set of nominal values before maximin types of optimal designs can be found via a nested optimizationprocess. We show that particle swarm optimization (PSO) techniques can solve such complex optimizationproblems effectively. We demonstrate numerical results from PSO can help find, for the first time, formulae forstandardized maximin D-optimal designs for nonlinear model with 3 or 4 parameters on the compact andnonnegative design space. Additionally, we show locally and standardized maximin D-optimal designs for inhibitionmodels are not necessarily supported at a minimum number of points. To facilitate use of such designs, wecreate a web-based tool for practitioners to find tailor-made locally and standardized maximin optimal designs
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