Oxygen non-stoichiometry and defect structure of LaMn1-zCuzO3+δ

The quantitative model analysis of the defect structure of copper doped lanthanum manganites LaMn1-zCuzO3+δ (z = 0.05 and 0.1) was performed. In the framework of the model, the independent course of the three reactions of defect formation, including the electronic exchange between manganese and copper, completion of a lattice by the absorption of oxygen and the disproportionation of manganese was considered. It is shown that the increase in the dopant content leads to a change in the dominant electronic process. This is reflected in the lock and disproportionation and leads to the increase in the concentration of holes and decrease the concentration of electrons localized on the manganese atoms

Ultrafast Collective Dynamics in the Charge-Density-Wave Conductor K0.3_{0.3}MoO3_{3}

Low-energy coherent charge-density wave excitations are investigated in blue bronze (K$_{0.3}$MoO$_{3}$) and red bronze (K$_{0.33}$MoO$_{3}$) by femtosecond pump-probe spectroscopy. A linear gapless, acoustic-like dispersion relation is observed for the transverse phasons with a pronounced anisotropy in K$_{0.33}$MoO$_{3}$. The amplitude mode exhibits a weak (optic-like) dispersion relation with a frequency of 1.67 THz at 30 K. Our results show for the first time that the time-resolved optical technique provides momentum resolution of collective excitations in strongly correlated electron systems.Low-energy coherent charge-density wave excitations are investigated in blue bronze (K$_{0.3}$MoO$_{3}$) and red bronze (K$_{0.33}$MoO$_{3}$) by femtosecond pump-probe spectroscopy. A linear gapless, acoustic-like dispersion relation is observed for the transverse phasons with a pronounced anisotropy in K$_{0.33}$MoO$_{3}$. The amplitude mode exhibits a weak (optic-like) dispersion relation with a frequency of 1.67 THz at 30 K. Our results show for the first time that the time-resolved optical technique provides momentum resolution of collective excitations in strongly correlated electron systems.Comment: 10 pages, 4 figure

Institutional and organizational features of cross-border cargo traffic in the post-soviet space integration terms. Part I

The article covers the technical, technological, institutional, and organizational barriers of cross-border transportation of cargo. The study uses an institutional approach as a methodological alternative to other approaches. The study touches on institutional and organizational problems of border crossing checkpoints arrangement, the consequences of the application of unified transport documents and the introduction of electronic communication forms. Particular attention is paid to the analysis of demonstrative actions and the daily practice of reducing the time of customs procedures and reducing transaction costs of cross-border cargo traffic. Herewith it is indicated that the most effective way to improve the efficiency of cross-border transportation of cargo suggests simultaneous implementation of technical and institutional innovations. Emphasis is placed on identifying the institutional and organizational features of the international road transportation of cargo, in particular, the problems of the evolution of the guaranteed customs duties payment institute, the permission system in the implementation of cross-border cargo traffic. The fact that the state support of national entrepreneurs requires a mechanism to ensure the parity of Russian and foreign carriers, at least in the field of cargo transportation for state needs, with the involvement of credit resources of government-linked banks is highlighted. It is underlined that the first step towards improving the institutional environment of international road transportation should envisage the elimination of all informal (shadow) relations in this sphere. The article identifies institutional features of cargo transportation in specific areas such as deliveries by road to China through Kazakhstan, and the challenges and prospects for the use and development of transit potential of Kaliningrad Region. The article shows institutional and organizational characteristics of combined transportation in cross-border traffic. The article concludes that the development of cross-border transportation of cargo and the implementation of transport and transit potential of EAEU member states may and should become a powerful source of income for business entities, budgets of all levels and households, as well as the driving force of industrial and technological upgrading and institutional and organizational evolution of economic systems of the countries and integration associations.The article has been prepared with the support of the Russian Foundation for Basic Research (Project № 15-06-06939 a «Modelling the cyclical evolution of mutual influence of the national transport system and the state of the markets of goods (services), labor and capital in terms of integration and global instability»)

Implementing Urgent Transport and Transit Projects Based on Public-private Partnership in Russia

The article examines the main areas for implementing urgent transport and transit projects based on Public-Private Partnership (PPP) in Russia. This paper continues the study of theory and practice of using PPP to implement the investment projects aimed at developing and realizing the transport and transit potential of Russia. The authors used the methodological basis of the evolutionary and institutional theory, historical approach, system analysis, and theory of the rm to examine the ongoing projects aimed at developing the transport and transit system in Russia based on PPP, such as construction of high-speed Moscow — Kazan highway with its subsequent extension to the Chinese border, functioning of transport and logistics system in the Chelyabinsk region, infrastructural support for transit cargo shipments along the Northern Sea Route (NSR), participation of foreign investors in the development of Russian sea ports and approaches to them. It is shown that the provision of competitive advantages offered by transit shipping operations on a particular route requires a high speed of cargo transportation with a minimum of stops, handling, and transshipments along the route. The revenues from realizing transport and transit potential can be compared with the amount of resource rent only when Russia builds not just a transit sector but the production and transit sector in its economy. In this regard, the authors focused on defining the opportunity and necessity of organizational transformations associated with building a large public-private transport company that would be able to compete with global sea container companies on Asia—Europe routes. The article elaborated the main areas and measures under the proposed national project “Developing the Transit Economy in Russia: Uniting Eurasia” and its subprogram “Developing the Innovative Rolling Stock for Container and Multimodal Shipping Operations.” The finding of the study presented in the article may be used for preparing the state programs and projects that include a system of measures to develop and realize the transport and transit potential of Russia based on institutional and organizational transformations.The article has been prepared with the support of Russian Science Foundation (Project № 16–18–10149)