On the origin of extrusion instabilities: Linear stability analysis of the viscoelastic die swell

It is well-known that, increasing the flow rate in polymer extrusion, the flow becomes unstable and the smooth extrudate surface becomes wavy and disordered to an increasing degree. In order to investigate the mechanisms responsible for these instabilities we perform a linear stability analysis of the steady extrusion of a viscoelastic fluid flowing through a planar die under creeping flow conditions. We consider the Phan-Thien-Tanner (PTT) model to account for the viscoelasticity of the material. We employ the mixed finite element method combined with an elliptic grid generator to account for the deformable shape of the interface. The generalized eigenvalue problem is solved using Arnoldi’s algorithm. We perform a thorough parametric study in order to determine the effects of all material properties and rheological parameters. We investigate in detail the effect of the interfacial tension and the presence of a deformable interface. It is found that the presence of a finite surface tension destabilizes the flow as compared to the case of the stick-slip flow. We recognize two modes, which become unstable beyond a critical value of the Weissenberg number and perform an energy analysis to examine the mechanisms responsible for the destabilization of the flow and compare against the mechanisms that have been suggested in the literature

Dynamic Heterogeneity in Ring-Linear Polymer Blends

We present results from a direct statistical analysis of long molecular dynamics (MD) trajectories for the orientational relaxation of individual ring molecules in blends with equivalent linear chains. Our analysis reveals a very broad distribution of ring relaxation times whose width increases with increasing ring/linear molecular length and increasing concentration of the blend in linear chains. Dynamic heterogeneity is also observed in the pure ring melts but to a lesser extent. The enhanced degree of dynamic heterogeneity in the blends arises from the substantial increase in the intrinsic timescales of a large subpopulation of ring molecules due to their involvement in strong threading events with a certain population of the linear chains present in the blend. Our analysis suggests that the relaxation dynamics of the rings are controlled by the different states of their threading by linear chains. Unthreaded or singly-threaded rings exhibit terminal relaxation very similar to that in their own melt, but multiply-threaded rings relax much slower due to the long lifetimes of the corresponding topological interactions. By further analyzing the MD data for ring molecule terminal relaxation in terms of the sum of simple exponential functions we have been able to quantify the characteristic relaxation times of the corresponding mechanisms contributing to ring relaxation both in their pure melts and in the blends, and their relative importance. The extra contribution due to ring-linear threadings in the blends becomes immediately apparent through such an analysis

Patterns on liquid surfaces: cnoidal waves, compactons and scaling

Localized patterns and nonlinear oscillation formation on the bounded free surface of an ideal incompressible liquid are analytically investigated . Cnoidal modes, solitons and compactons, as traveling non-axially symmetric shapes are discused. A finite-difference differential generalized Korteweg-de Vries equation is shown to describe the three-dimensional motion of the fluid surface and the limit of long and shallow channels one reobtains the well known KdV equation. A tentative expansion formula for the representation of the general solution of a nonlinear equation, for given initial condition is introduced on a graphical-algebraic basis. The model is useful in multilayer fluid dynamics, cluster formation, and nuclear physics since, up to an overall scale, these systems display liquid free surface behavior.Comment: 14 pages RevTex, 5 figures in p

Nonlinear Modes of Liquid Drops as Solitary Waves

The nolinear hydrodynamic equations of the surface of a liquid drop are shown to be directly connected to Korteweg de Vries (KdV, MKdV) systems, giving traveling solutions that are cnoidal waves. They generate multiscale patterns ranging from small harmonic oscillations (linearized model), to nonlinear oscillations, up through solitary waves. These non-axis-symmetric localized shapes are also described by a KdV Hamiltonian system. Recently such ``rotons'' were observed experimentally when the shape oscillations of a droplet became nonlinear. The results apply to drop-like systems from cluster formation to stellar models, including hyperdeformed nuclei and fission.Comment: 11 pages RevTex, 1 figure p