5,791 research outputs found
Long-range Ni/Mn structural order in epitaxial double perovskite La2NiMnO6 thin films
We report and compare the structural, magnetic, and optical properties of
ordered La2NiMnO6 thin films and its disordered LaNi0.5Mn0.5O3 counterpart. An
x-ray diffraction study reveals that the B-site Ni/Mn ordering induces
additional XRD reflections as the crystal symmetry is transformed from a
pseudocubic perovskite unit cell in the disordered phase to a monoclinic form
with larger lattice parameters for the ordered phase. Polarized Raman
spectroscopy studies reveal that the ordered samples are characterized by
additional phonon excitations that are absent in the disordered phase. The
appearance of these additional phonon excitations is interpreted as the
clearest signature of Brillouin zone folding as a result of the long-range
Ni/Mn ordering in La2NiMnO6. Both ordered and disordered materials display a
single ferromagnetic-to-paramagnetic transition. The ordered films display also
a saturation magnetization close to 4.8 mB/f.u. and a transition temperature
(FM-TC) around 270 K, while the disordered ones have only a 3.7 mB/f.u.
saturation magnetization and a FM-TC around 138 K. The differences in their
magnetic behaviours are understood based on the distinct local electronic
configurations of their Ni/Mn cations.Comment: 15 pages, 5 fig
Phase formation, phonon behavior, and magnetic properties of novel ferromagnetic La3BAlMnO9 (B = Co or Ni) triple perovskites
In the quest for novel magnetoelectric materials, we have grown, stabilized
and explored the properties of La3BAlMnO9 (B = Co or Mn) thin films. In this
paper, we report the influence of the growth parameters that promote B/Al/Mn
ordering in the pseudo-cubic unit cell and their likely influence on the
magnetic and multiferroic properties. The temperature dependence of the
magnetization shows that La3CoAlMnO9 is ferromagnetic up to 190 K while
La3NiAlMnO9 shows a TC of 130 K. The behavior of these films are compared and
contrasted with related La2BMnO6 double perovskites. It is observed that the
insertion of AlO6 octahedra between CoO6 and MnO6 suppresses significantly the
strength of the superexchange interaction, spin-phonon and spin-polar coupling.Comment: 13 pages, 3 fig
Investigation of phonon behavior in Pr2NiMnO6 by micro-Raman spectroscopy
The temperature dependence of phonon excitations and the presence of spin
phonon coupling in polycrystalline Pr2NiMnO6 samples were studied using
micro-Raman spectroscopy and magnetometry. Magnetic properties show a single
ferromagnetic-to-paramagnetic transition at 228 K and a saturation
magnetization close to 4.95 \muB/f.u.. Three distinct Raman modes at 657, 642,
and 511 cm-1 are observed. The phonon excitations show a clear hardening due to
anharmonicity from 300 K down to 10 K. Further, temperature dependence of the
657 cm-1 mode shows only a small softening. This reflects the presence of a
relatively weak spin-phonon coupling in Pr2NiMnO6 contrary to other double
perovskites previously studied.Comment: 10 pages, 4 fig
Complete control of a matter qubit using a single picosecond laser pulse
We demonstrate for the first time that a matter physical two level system, a
qubit, can be fully controlled using one ultrafast step. We show that the spin
state of an optically excited electron, an exciton, confined in a quantum dot,
can be rotated by any desired angle, about any desired axis, during such a
step. For this we use a single, resonantly tuned, picosecond long, polarized
optical pulse. The polarization of the pulse defines the rotation axis, while
the pulse detuning from a non-degenerate absorption resonance, defines the
magnitude of the rotation angle. We thereby achieve a high fidelity, universal
gate operation, applicable to other spin systems, using only one short optical
pulse. The operation duration equals the pulse temporal width, orders of
magnitude shorter than the qubit evolution life and coherence times.Comment: main text: 4 pages, 3 figures Supplemental material: 3 pages, 1
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