Identification of a herbicide-resistant biotype of Echinochloa crus-galli in Ukraine

Ukraine is one of the world’s guarantors of food security and has the potential to further increase agricultural production. However, the vast majority of herbicides used on crops are acetolactate synthase (ALS) inhibitors, which poses a threat of herbicide-resistant weed species. The emergence and spread of herbicide-resistant weed biotypes can significantly increase the cost of growing crops to the point of loss of profitability. Herbicide resistance in barnyardgrass (Echinochloa crus-galli var. crus-galli) has been studied in long-term field and greenhouse experiments. Resistance of E. crus-galli to the ALS herbicide triazolopyrimidine derivative ‒ penoxsulam was identified. Expressed resistance was observed in weed plants grown from seeds collected under production conditions in Kherson region in 2015–2016 and 2020–2021. Cross resistance was observed for imidazolinone and sulfonylurea derivatives. It should be noted that the level of cross resistance to ALS herbicides was slightly higher for plants derived from weed seeds harvested in 2020–2021 compared to those harvested in 2015–2016. The introduction of a herbicidal composition of a herbicide mixture ‒ an inhibitor of 4-hydroxyphenylpyruvate dioxygenase (HPPD) (an enzyme in plants in the chain of carotenoid synthesis) ‒ mesotrione with an ALS-inhibitor (nicosulfuron) allowed effective control of the weed, which indicates the absence of multiple resistance to herbicides ‒ inhibitors of carotenoid synthesis. The high efficiency of E. crus-galli control was established by the application of herbicides ‒ inhibitors of fatty acid synthesis (graminicides). The highest level of efficiency in the experiments was observed with the application of fluazifop-butyl and somewhat less ‒ with pinoxaden. A tendency to reduce phytotoxicity to barnyardgrass from the south of Ukraine was observed with the introduction of tepraloxydim and quizalofop-ethyl. A lower level of phytotoxicity of fenoxaprop-p-ethyl on E. crus-galli should be noted compared to the effect of pinoxaden. No multiple resistance was observed with glyphosate (5-enolpyruvylshikimate-3-phosphate synthase inhibitor) and reglone (photosystem I inhibitor), allowing control of vegetative weeds at the beginning and end of the growing season. It has been established that monocot weed species have significantly increased their presence and harmfulness in agrophytocenoses in Ukraine and in the world since the 1950s with the widespread introduction of selective dicotyledonous species control with aryloxyphenoxyacetic, propionic and benzoic acid derivatives. This trend has been maintained until recently ‒ barnyardgrass is one of the dominant weed species in modern agrophytocenoses of Ukraine. Therefore, the identification of the ALS-resistant biotype of barnyardgrass complicates weed control in the following crops in rotations in the southern regions of the country: in maize crops with cross resistance to nicosulfuron, in sunflower ‒ to imidazolinones (imazamox, imazapyr), and also makes it impossible to use penoxsulam in rice production. Traditionally, the use of synthetic auxins, phenoxyacetic acid derivatives, etc. is used to control ALS-resistance. However, in Kherson region of Ukraine, already in the third year of application of rinskor (florpyrauxifen-benzyl), some weed plants were found on rice fields affected by ALS-resistant barnyardgrass, which recovered after the use of synthetic auxin. Therefore, the control of ALS-resistance (penoxsulam, etc.) in E. crus-galli with the application florpyrauxifen-benzyl in the Kherson region of Ukraine is already limited. An obvious and economically feasible preventive measure against the emergence of resistant weed biotypes is the implementation of GAP (Good Agricultural Practice, FAO) approaches: in particular, the use of high quality seeds without weed impurities, increasing the proportion of agrotechnical weed control measures, restoring and expanding crop rotations with mandatory rotation of herbicides with different modes of action, introducing dicotyledonous/leguminous crops into rotations, and using herbicides with different modes of action in crops separately or in mixtures. At the same time, agrotechnical measures and the preservation of biodiversity in agrophytocenoses should be the main factor in controlling resistance in weeds. The use of herbicides and their mixtures with different modes of action is of secondary importance. The identification of highly damaging ALS-resistant E. crus-galli in southern Ukraine indicates the insufficient effectiveness of weed control exclusively with herbicides with a single mechanism of action and requires a significant revision of the principles of crop rotation and ways of weed control in the country to maintain high levels of profitability and productivity of agrophytocenoses. Solving this problem is urgent for the preservation of Ukraine's potential as one of the guarantors of global food security

Assessment of the impact of the educational process on motor activity and health level of cadets of educational institutions of the ministry of internal affairs of Russia

The important components of the physical training of internal affairs officers, as well as other specialists, are the level of physical activity and quality health indicators. These components will determine the physical fitness of law enforcement specialists, not to mention the effectiveness of their duties. Graduates of general educational institution entering the educational organizations of the Ministry of Internal Affairs of Russia make the first step towards the development of the identity of a law enforcement officer. Therefore, the level of future professional knowledge, skills, and abilities, as well as competencies during their study at a higher education institution will determine the ability of a police officer to cope with his/her official dutie

STUDY OF THE TARGET EFFICIENCY AND TOXICITY OF THE INSECTICIDE WITH NEW PREPARATIVE FORM

We studied the efficiency and toxicity of new insecticide "GET Dry" (active ingredients of alpha-cypermethrin and imidacloprid). The target efficiency as acute and residual impact was studied, when agent was applied against the tropic and bed bugs (Cimex hemipterus), German cockroach (Blatella germanica), false stable flies (Musca domestica) and larvae of the leather beetles (Attagenus smirnovi).This work was supported by the Russian Foundation for Basic Research (grant # 20-48-660041 р_а)

Study of the Target Efficiency and Toxicity of the Insecticide with New Preparative Form

We studied the efficiency and toxicity of new insecticide "GET Dry"(active ingredients of alpha-cypermethrin and imidacloprid). The target efficiency as acute and residual impact was studied, when agent was applied against the tropic and bed bugs (Cimex hemipterus), German cockroach (Blatella germanica), false stable flies (Musca domestica) and larvae of the leather beetles (Attagenus smirnovi). The agent demonstrated strong acute effect (about 100%), when applied against the cockroaches, bugs and flies. Moreover, the agent demonstrates the residual impact on the cockroaches, flies, fleas during 45 days, and on the bugs during 30 days. The slight insecticidal activity was observed, when the agent was applied against the larvae. We studied toxicity of the agent - DL50, when swallowed (moderately hazardous substances, class III) and when applied to the skin (low-hazard substance, class IV), as well as we studied its inhalation hazard according to its volatility C20°C, irritant action, when applied to the skin (slight) and eye irritation (moderate). Sensibilizing action was not observed. © 2021 Author(s)

Geometric Random Inner Products: A New Family of Tests for Random Number Generators

We present a new computational scheme, GRIP (Geometric Random Inner Products), for testing the quality of random number generators. The GRIP formalism utilizes geometric probability techniques to calculate the average scalar products of random vectors generated in geometric objects, such as circles and spheres. We show that these average scalar products define a family of geometric constants which can be used to evaluate the quality of random number generators. We explicitly apply the GRIP tests to several random number generators frequently used in Monte Carlo simulations, and demonstrate a new statistical property for good random number generators

Decay of metastable current states in one-dimensional resonant tunneling devices

Current switching in a double-barrier resonant tunneling structure is studied in the regime where the current-voltage characteristic exhibits intrinsic bistability, so that in a certain range of bias two different steady states of current are possible. Near the upper boundary V_{th} of the bistable region the upper current state is metastable, and because of the shot noise it eventually decays to the stable lower current state. We find the time of this switching process in strip-shaped devices, with the width small compared to the length. As the bias V is tuned away from the boundary value V_{th} of the bistable region, the mean switching time \tau increases exponentially. We show that in long strips \ln\tau \propto (V_{th} -V)^{5/4}, whereas in short strips \ln\tau \propto (V_{th} -V)^{3/2}. The one-dimensional geometry of the problem enables us to obtain analytically exact expressions for both the exponential and the prefactor of \tau. Furthermore, we show that, depending on the parameters of the system, the switching can be initiated either inside the strip, or at its ends.Comment: 12 pages, 5 figures, update to published versio

Lifetime of metastable states in resonant tunneling structures

We investigate the transport of electrons through a double-barrier resonant-tunneling structure in the regime where the current-voltage characteristics exhibit bistability. In this regime one of the states is metastable, and the system eventually switches from it to the stable state. We show that the mean switching time grows exponentially as the voltage across the device is tuned from the its boundary value into the bistable region. In samples of small area we find that the logarithm of the lifetime is proportional to the voltage (measured from its boundary value) to the 3/2 power, while in larger samples the logarithm of the lifetime is linearly proportional to the voltage.Comment: REVTeX 4, 5 pages, 3 EPS-figure

Building Heat-insulating Materials Based on the Products of the Transesterification of Polyethylene Terephthalate and Dibutyltin Dilaurate

In this paper, we offered a technological basis for production of heat-insulating polyurethane materials based on the aromatic polyester - the product of transesterification of polyethylene terephthalate and corrective additive - dibutyltin dilaurate. Also, we presented the formulation and properties of the developed polyurethanes