34 research outputs found
Design and experimental implementation of voltage control scheme using the coefficient diagram method based PID controller for two-level boost converter with photovoltaic system
Introduction. Currently, in the solar energy systems and a variety of electrical applications, the power converters are essential part. The main challenge for similar systems is controller design. In the literature, the PID controller has proved its effectiveness in many industrial applications, but determining its parameters remains one of the challenges in control theory field. The novelty of the work resides in the design and experimental implementation of a two-level boost DC-DC converter controlled by a PID controller for photovoltaic (PV) maximum power extraction. Purpose. Analysis and control of the two-level boost topology with renewable energy source and design of the PID controller parameters using simple and accurate method. Methods. PID coefficients are optimized using Coefficient Diagram Method (CDM) in the MATLAB environment. Results. A mathematical model of a two-level boost converter with PID controller and PV energy source was developed and analyzed. The model allows to design the controller parameters of the proposed system. Practical value. A prototype steered by the proposed CDM-PID controller was tested using an Arduino embedded board. A comparison between the simulation results and the experimental one is presented. The obtained results illustrate that the experimental results match the simulation closely, and the proposed CDM-PID controller provides a fast and precise results.Вступ. В даний час перетворювачі потужності є невід’ємною частиною сонячних енергетичних систем та різних електричних пристроїв. Основною проблемою для таких систем є проектування контролера. У літературі ПІД-регулятор довів свою ефективність у багатьох промислових застосуваннях, але визначення його параметрів залишається однією з проблем у галузі теорії управління. Новизна роботи полягає у розробці та експериментальній реалізації дворівневого підвищувального перетворювача постійного струму, керованого ПІД-регулятором, для отримання максимальної потужності фотоелектричних пристроїв. Мета. Аналіз та управління дворівневою топологією підвищення з використанням відновлюваного джерела енергії та розрахунок параметрів ПІД-регулятора простим та точним методом. Методи. Коефіцієнти ПІД оптимізуються за допомогою методу діаграми коефіцієнтів (CDM) у середовищі MATLAB. Отримані результати. Розроблено та проаналізовано математичну модель дворівневого підвищувального перетворювача з ПІД-регулятором та фотоелектричним джерелом енергії. Модель дозволяє спроєктувати параметри контролера пропонованої системи. Практична цінність. Прототип, керований пропонованим контролером CDM-PID, протестували з використанням вбудованої плати Arduino. Наведено порівняння результатів моделювання з експериментальними даними. Отримані результати показують, що експериментальні результати близько відповідають моделюванню, а пропонований CDM-ПІД-регулятор забезпечує швидкі та точні результати
On the influence of the exciton-blocking layer on the organic multilayer cells properties
The performances of organic photovoltaic cells based on the layer couple electron donor/electron acceptor (ED/EA) are significantly improved when an exciton blocking layer (EBL) is inserted between the organic acceptor and the cathode. A new material, the (Z)-5-(4-chlorobenzylidene)-3-(2-ethoxyphenyl)-2-thioxothiazolidin-4-one, that we called (CBBTZ), has been synthesized, characterized and probed as EBL. The energy levels corresponding to the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) of the CBBTZ have been determined from the first oxidation and reduction potential respectively, using cyclic voltametric (CV) measurements. From CV curves, CBBTZ in dichloromethane showed a one electron reversible reduction and oxidation waves. The values of its HOMO and LUMO have been estimated to be 6.42 eV and 3.42 eV respectively. Such values show that CBBTZ could be probed as EBL in organic solar cells based on the ED/EA couple copper phthalocyanine(CuPc)/fullerene (C60). The photovoltaic solar cells have been obtained by sequential deposition under vacuum of the different films. The different thin film thicknesses were measured in situ by a quartz monitor. Multilayer solar cells ITO/Au/CuPc/C60/EBL/Al have been probed, where EBL is the aluminium tris(8-hydroxyquinoline) (Alq3), the CBBTZ, the 2-(4-byphenylyl)-5-(4-tert-buthylphenyl)-1,3,4-oxadiazole (butyl PBD) or the bathocuproine (BCP). The optimum film thickness is 8–9 nm whatever the EBL used. When obtained in the same run, the averaged efficiency of the cells using the CBBTZ is of the same order of magnitude than that obtained with BCP and higher than that achieved with Alq3 or butyl PBD. It is shown by XPS study that some aluminium of the cathode is present in the buffer layer. This aluminium could justify the ability of the electrons to cross the insulating exciton blocking layer thick of 9 nm
On the influence of the exciton-blocking layer on the organic multilayer cells properties
A possible regulatory link between Twist 1 and PPARγ gene regulation in 3T3-L1 adipocytes
Performance of biocomposites from surface modified regenerated cellulose fibers and lactic acid thermoset bioresin
Soil erodibility mapping using the RUSLE model to prioritize erosion control in the Wadi Sahouat basin, North-West of Algeria
Soil losses must be quantified over watersheds in order to set up protection measures against erosion. The main objective of this paper is to quantify and to map soil losses in the Wadi Sahouat basin (2140 km(2)) in the north-west of Algeria, using the Revised Universal Soil Loss Equation (RUSLE) model assisted by a Geographic Information System (GIS) and remote sensing. The Model Builder of the GIS allowed the automation of the different operations for establishing thematic layers of the model parameters: the erosivity factor (R), the erodibility factor (K), the topographic factor (LS), the crop management factor (C), and the conservation support practice factor (P). The average annual soil loss rate in the Wadi Sahouat basin ranges from 0 to 255 t ha(-1) year(-1), maximum values being observed over steep slopes of more than 25% and between 600 and 1000 m elevations. 3.4% of the basin is classified as highly susceptible to erosion, 4.9% with a medium risk, and 91.6% at a low risk. Google Earth reveals a clear conformity with the degree of zones to erosion sensitivity. Based on the soil loss map, 32 subbasins were classified into three categories by priority of intervention: high, moderate, and low. This priority is available to sustain a management plan against sediment filling of the Ouizert damat the basin outlet. The method enhancing the RUSLE model and confrontation with Google Earth can be easily adapted to other watersheds
Spectroscopic (FT-IR,H-1 and C-13 NMR) characterization and density functional theory calculations for (Z)-5-(4-nitrobenzyliden)-3-N(2-ethoxyphenyl)-2-thioxo-thiazolidin-4-one (ARNO)
In this work, the vibrational spectral analysis is carried out by using FTIR spectroscopy in the range 4000 -400 cm(-1) (2)-5-(4-nitrobenzyliden)-3-N(2-ethoxypheny1)-2-thioxo-thiazolidin-4-one (ARNO) molecule. Theoretical calculations were performed by using density functional theory (DFT) method using 6-31G (d, p) and 6-311G (d, p) basis sets. The results of the calculations were applied to simulated spectra of the title compound, which show excellent agreement with observed spectra. The first order hyperpolarizability and related properties (mu and alpha) for ARNO were also calculated. Stability of the molecule has been analyzed by natural bond orbital (NBO) analysis. Mulliken population analysis on atomic charges of the title compound has been carried out by the same method and basis sets. Finally, molecular electrostatic potential (MEP) and HOMO-LUMO energy levels have been evaluated. (C) 2017 Elsevier B.V. All rights reserved
Optical and electronic proprieties of thin films based on (Z)-5-(4-chlorobenzylidene)-3-(2-ethoxyphenyl)-2 thioxothiazolidin-4-one, (CBBTZ) and possible application as exciton-blocking layer in heterojunction organic solar cells
In this work, organic thin film solar cells with structures based on CuPc/C60 bulk heterojunctions, have been fabricated and characterized. The effect of introducing an exciton blocking layer (EBL) between the active layer and the metal layer in the solar cell was investigated. For that (Z)-5-(4-chlorobenzylidene)-3-(2-ethoxyphenyl)-2-thioxothiazolidin-4-one, that we called (CBBTZ) has been synthesized, characterized and probed as EBL. It was shown that optimized structures containing EBLs resulted in an improvement in solar cell conversion efficiencies. The energy levels corresponding to the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) of the CBBTZ have been determined from the first oxidation and reduction potential respectively, using cyclic voltametric (CV) measurements. From CV curves, CBBTZ in dichloromethane showed a one electron reversible reduction and oxidation waves. The values of its HOMO and LUMO have been estimated to be 6.42 eV and 3.42 eV respectively. Such values show that CBBTZ could be probed as EBL in organic solar cells based on the ED/EA couple copper phthalocyanine(CuPc)/fullerene (C60). The photovoltaic solar cells have been obtained by sequential deposition under vacuum of the different films where their thicknesses were measured in situ by a quartz monitor. When obtained, the averaged efficiency of the cells using the CBBTZ is higher than that achieved without EBL layer
On the influence of the exciton-blocking layer on the organic multilayer cells properties
The performances of organic photovoltaic cells based on
the layer couple electron donor/electron acceptor (ED/EA) are significantly
improved when an exciton blocking layer (EBL) is inserted between the
organic acceptor and the cathode. A new material, the
(Z)-5-(4-chlorobenzylidene)-3-(2-ethoxyphenyl)-2-thioxothiazolidin-4-one,
that we called (CBBTZ), has been synthesized, characterized and probed as
EBL. The energy levels corresponding to the highest occupied molecular
orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) of the
CBBTZ have been determined from the first oxidation and reduction potential
respectively, using cyclic voltametric (CV) measurements. From CV curves,
CBBTZ in dichloromethane showed a one electron reversible reduction and
oxidation waves. The values of its HOMO and LUMO have been estimated to be
6.42 eV and 3.42 eV respectively. Such values show that CBBTZ could be
probed as EBL in organic solar cells based on the ED/EA couple copper
phthalocyanine(CuPc)/fullerene (C60). The photovoltaic solar cells have
been obtained by sequential deposition under vacuum of the different films.
The different thin film thicknesses were measured in situ by a quartz
monitor. Multilayer solar cells ITO/Au/CuPc/C60/EBL/Al have been
probed, where EBL is the aluminium tris(8-hydroxyquinoline) (Alq3), the
CBBTZ, the 2-(4-byphenylyl)-5-(4-tert-buthylphenyl)-1,3,4-oxadiazole (butyl
PBD) or the bathocuproine (BCP). The optimum film thickness is 8–9 nm
whatever the EBL used. When obtained in the same run, the averaged
efficiency of the cells using the CBBTZ is of the same order of magnitude
than that obtained with BCP and higher than that achieved with Alq3 or
butyl PBD. It is shown by XPS study that some aluminium of the cathode is
present in the buffer layer. This aluminium could justify the ability of the
electrons to cross the insulating exciton blocking layer thick of 9 nm
Optical and electronic proprieties of thin films based on (Z)-5-(4-chlorobenzylidene)-3-(2-ethoxyphenyl)-2 thioxothiazolidin-4-one, (CBBTZ) and possible application as exciton-blocking layer in heterojunction organic solar cells
In this work, organic thin film solar cells with structures based on CuPc/C60 bulk heterojunctions, have been fabricated and characterized. The effect of introducing an exciton blocking layer (EBL) between the active layer and the metal layer in the solar cell was investigated. For that (Z)-5-(4-chlorobenzylidene)-3-(2-ethoxyphenyl)-2-thioxothiazolidin-4-one, that we called (CBBTZ) has been synthesized, characterized and probed as EBL. It was shown that optimized structures containing EBLs resulted in an improvement in solar cell conversion efficiencies. The energy levels corresponding to the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) of the CBBTZ have been determined from the first oxidation and reduction potential respectively, using cyclic voltametric (CV) measurements. From CV curves, CBBTZ in dichloromethane showed a one electron reversible reduction and oxidation waves. The values of its HOMO and LUMO have been estimated to be 6.42 eV and 3.42 eV respectively. Such values show that CBBTZ could be probed as EBL in organic solar cells based on the ED/EA couple copper phthalocyanine(CuPc)/fullerene (C60). The photovoltaic solar cells have been obtained by sequential deposition under vacuum of the different films where their thicknesses were measured in situ by a quartz monitor. When obtained, the averaged efficiency of the cells using the CBBTZ is higher than that achieved without EBL layer