Sport: A Possible Road toward Social Inclusion and Quality of Life

Sport is a universal language, recognized and shared by all. A psychiatric users Association, in collaboration with public Mental Health Department and UISP, Italian Union Promoting Sport for All, proposes the sport as one of the possible strategies within a wider therapeutic project for schizophrenia. Soft gymnastic, swimming, football, and volley are observed from the point of view of users, main recipients of the intervention, trainers, and referees. The perceived quality of life was measured in the users/athletes, using the WHOQOL-brief schedule. To practice sport enhances the adhesion to treatment and the quality of life and can reduce hospitalizations. It is a useful tool for promoting well-being, personal autonomy and an active lifestyle, preventing isolation, and improving self-esteem and social cognition. It may be an important factor preventing poor functional outcome and promoting recovery. Team sports seem to have a greater therapeutic value, producing fun, cohesion, and social inclusion; they can also play an important educational role, preventing social stigma

Investigating Novel Syntheses of a Series of Unique Hybrid PLGA-Chitosan Polymers for Potential Therapeutic Delivery Applications

Discovering new materials to aid in the therapeutic delivery of drugs is in high demand. PLGA, a FDA approved polymer, is well known in the literature to form films or nanoparticles that can load, protect, and deliver drug molecules; however, its incompatibility with certain drugs (due to hydrophilicity or charge repulsion interactions) limits its use. Combining PLGA or other polymers such as polycaprolactone with other safe and positively-charged molecules, such as chitosan, has been sought after to make hybrid systems that are more flexible in terms of loading ability, but often the reactions for polymer coupling use harsh conditions, films, unpurified products, or create a single unoptimized product. In this work, we aimed to investigate possible innovative improvements regarding two synthetic procedures. Two methods were attempted and analytically compared using nuclear magnetic resonance (NMR), fourier-transform infrared spectroscopy (FT-IR), and dynamic scanning calorimetry (DSC) to furnish pure, homogenous, and tunable PLGA-chitosan hybrid polymers. These were fully characterized by analytical methods. A series of hybrids was produced that could be used to increase the suitability of PLGA with previously non-compatible drug molecule

Comet 67P/CG: surface temperature maps from Rosetta/VIRTIS during the pre-landing phase

It was seldom possible, with observations carried out from spaceborne facilities, to derive spatially-resolved thermal maps of small bodies, and even more rarely this result was achieved in the case of close observations of comets. The Visible InfraRed Thermal Imaging Spectrometer (VIRTIS) onboard the Rosetta Orbiter Coradini (2007) is able to obtain hyperspectral images of the observed targets in 864 wavelengths simultaneously, in the overall spectral range 0.25-5.1 μm, with the major goal of inferring and mapping the surface composition and temperature of comet 67P/Churyumov-Gerasimenko. VIRTIS spectra acquired on the dayside of the comet’s nucleus show the thermal emission of the surface at wavelengths ¿ 3.5 μm, which can be ex- ploited to derive and map the surface temperature at different spatial scales and under changing lighting conditions. To do this, we rely on a Bayesian approach that was previously adopted to derive surface temperature maps of the two asteroids 2678 Steins and 21 Lutetia, encountered by Rosetta during its long cruise phase towards the comet Coradini (2011); Keihm (2012), and of the large asteroid Vesta from the entire infrared dataset acquired by the VIR instrument onboard the Dawn spacecraft Tosi (2014). In this paper we summarize the main results concerning the thermal mapping of comet 67P, obtained by VIRTIS in the first months of observation at a reso- lution between 1000 and 1 m, and at a heliocentric distance between 3.6 and 3.4 AU. Comet 67P was shown to be everywhere rich in organic materials with little to no water ice visible on the surface Capaccioni (2015). In the range of heliocentric distances from 3.59 to 2.74 AU, daytime surface temperatures were overall comprised in the range between 180 and 220 K Tosi (2015), which is incompatible with large exposures of water ice and is consistent with a low-albedo, organics-rich surface. Maximum temperature values as high as 230 K were recorded in very few places Tosi (2015). In the above period, the highest values of surface temperature were obtained with observations carried out at small phase angles, implying that the observed surface has a large predominance of small incidence angles, and local solar times centered around the max- imum daily insolation. In all cases, direct correlation with topographic features was observed, i.e. largest temperature values were generally associated with the smallest values of illumination angles, while no evidence was found of thermal anomalies, i.e. places of the surface that are intrinsically warmer or cooler than surrounding terrains observed at the same local solar time and under similar solar illumination

Variations in the amount of water ice on Ceres' surface suggest a seasonal water cycle.

The dwarf planet Ceres is known to host a considerable amount of water in its interior, and areas of water ice were detected by the Dawn spacecraft on its surface. Moreover, sporadic water and hydroxyl emissions have been observed from space telescopes. We report the detection of water ice in a mid-latitude crater and its unexpected variation with time. The Dawn spectrometer data show a change of water ice signatures over a period of 6 months, which is well modeled as ~2-km2 increase of water ice. The observed increase, coupled with Ceres' orbital parameters, points to an ongoing process that seems correlated with solar flux. The reported variation on Ceres' surface indicates that this body is chemically and physically active at the present time

Thermal stability of water ice in Ceres' crater Oxo

Dwarf planet Ceres, target of the NASA Dawn mission, exhibits evidences of ammoniated phyllosilicates on its surface [1], compatible with a likely outer Solar System origin. Considerable amounts of water ice have recently been detected in some craters by the Visible InfraRed mapping spectrometer (VIR) onboard Dawn in some small fresh crater, such as Oxo, located at about 40° N. The exposure mechanism of water ice is unknown: cryovolcanism, cometary type sublimation/recondensation [2]or impacts with other bodies are likely mechanisms. The evaluation of the time stability of the water ice is crucial to understand the plausible mechanism for its existence. For this purpose, we developed a 3D finite-elements model (FEM) by using the topography given by the shape model of Ceres derived on the basis of images acquired by the Framing Camera in the Survey mission phase. The illumination conditions are provided by the SPICE toolkit. We performed several simulations by analyzing the effect of thermal inertia and albedo on the temperature and rate of ice sublimation. The results of the simulations about the stability of water ice will be presented.[1] De Sanctis et al. NATURE, doi:10.1038/nature16172[2] Formisano et al. MNRAS, doi: 10.1093/mnras/stv234

Thermal Stability of Water Ice on Ceres' Surface: The Juling Case

We study the ice stability on Ceres' surface, by performing numerical simulations in which we tested the effects of thermal inertia and albedo

Artifacts reduction in VIR/Dawn data

Remote sensing images are generally affected by different types of noise that degrade the quality of the spectral data (i.e., stripes and spikes). Hyperspectral images returned by a Visible and InfraRed (VIR) spectrometer onboard the NASA Dawn mission exhibit residual systematic artifacts. VIR is an imaging spectrometer coupling high spectral and spatial resolutions in the visible and infrared spectral domain (0.25-5.0 μm). VIR data present one type of noise that may mask or distort real features (i.e., spikes and stripes), which may lead to misinterpretation of the surface composition. This paper presents a technique for the minimization of artifacts in VIR data that include a new instrument response function combining ground and in-flight radiometric measurements, correction of spectral spikes, odd-even band effects, systematic vertical stripes, high-frequency noise, and comparison with ground telescopic spectra of Vesta and Ceres. We developed a correction of artifacts in a two steps process: creation of the artifacts matrix and application of the same matrix to the VIR dataset. In the approach presented here, a polynomial function is used to fit the high frequency variations. After applying these corrections, the resulting spectra show improvements of the quality of the data. The new calibrated data enhance the significance of results from the spectral analysis of Vesta and Ceres

First mineralogical maps of 4 Vesta

Before Dawn arrived at 4 Vesta only very low spatial resolution (~50 km) albedo and color maps were available from HST data. Also ground-based color and spectroscopic data were utilized as a first attempt to map Vesta’s mineralogical diversity [1-4]. The VIR spectrometer [5] onboard Dawn has ac-quired hyperspectral data while the FC camera [6] ob-tained multi-color data of the Vestan surface at very high spatial resolutions, allowing us to map complex geologic, morphologic units and features. We here re-port about the results obtained from a preliminary global mineralogical map of Vesta, based on data from the Survey orbit. This map is part of an iterative map-ping effort; the map is refined with each improvement in resolution