Assessment of landfill leachate biodegradability and treatability by means of allochthonous and autochthonous biomasses

The biodegradability and treatability of a young (3 years old) municipal landfill leachate was evaluated by means of chemical oxygen demand (COD) fractionation tests, based on respirometric techniques. The tests were performed using two different biomasses: one cultivated from the raw leachate (autochthonous biomass) and the other collected from a conventional municipal wastewater treatment plant after its acclimation to leachate (allochthonous biomass). The long term performances of the two biomasses were also studied. The results demonstrated that the amount of biodegradable COD in the leachate was strictly dependent on the biomass that was used to perform the fractionation tests. Using the autochthonous biomass, the amount of biodegradable organic substrate resulted in approximately 75% of the total COD, whereas it was close to 40% in the case of the allochthonous biomass, indicating the capacity of the autochthonous biomass to degrade a higher amount of organic compounds present in the leachate. The autochthonous biomass was characterized by higher biological activity and heterotrophic active fraction (14% vs 7%), whereas the activity of the allochthonous biomass was significantly affected by inhibitory compounds in the leachate, resulting in a lower respiration rate (SOUR = 13 mg O2 gVSS-1 h-1 vs 37 mg O2 gVSS-1 h-1). The long-term performance of the autochthonous and allochthonous biomasses indicated that the former was more suitable for the treatment of raw landfill leachate, ensuring higher removal performance towards the organic pollutants

Sequential biological and photocatalysis based treatments for shipboard slop purification: A pilot plant investigation

This study investigated the treatment of a shipboard slop containing commercial gasoline in a pilot plant scale consisting of a membrane biological reactor (MBR) and photocatalytic reactor (PCR) acting in series. The MBR contributed for approximately 70% to the overall slop purification. More precisely, the biological process was able to remove approximately 40%, on average, of the organic pollution in the slop. Nevertheless, the membrane was capable to retain a large amount of organic molecules within the system, amounting for a further 30% of the influent total organic content removal. However, this affected the membrane fouling, thus resulting in the increase of the pore blocking mechanism that accounted for approximately 20% to the total resistance to filtration (2.85∙10 13 m −1 ), even if a significant restoration of the original membrane permeability was obtained after chemical cleanings. On the other hand, the biological treatment produced a clear solution for the photocatalytic system, thereby optimizing the light penetration and generation of highly oxidizing active oxygen species that enabled the degradation of bio-recalcitrant compounds. Indeed, low total organic carbon (TOC) values (<10 mg L −1 ) were achieved in the output of the photocatalytic reactor by means of only 60 Einstein (E) of cumulative impinging energy after the addition of K 2 S 2 O 8 . Overall, coupling the two processes enabled very high TOC removal (ca. 95%)

Waste activated sludge dewaterability: comparative evaluation of sludge derived from CAS and MBR systems

Sludge dewatering represents, nowadays, one of the greatest operational cost to wastewater treatment cycle. Physical\u2013chemical and biological parameters are recognized to influence the sludge dewaterability. However, many authors agree in identifying the sludge origin as one of the main aspect involved in sludge dewaterability. Indeed, the sludge origin such as the processes involved in liquid\u2013solid separation, seriously affect the sludge features. In order to elucidate the key factors influencing the dewaterability process, the present work is aimed to investigate the influence of the treatment plant lay-out on sludge dewaterability. The analyzed sludge samples were derived from four conventional activated sludge and two membrane bioreactor wastewater treatment plants. Experimental investigation was focused to highlight difference in sludge dewaterability derived from the application of European Standards adopted for sludge characterization. The achieved results confirmed the complexity of the inter-relationships between many factors affecting the sludge dewaterability

Achieving complete nitrification below the washout SRT with hybrid membrane aerated biofilm reactor (MABR) treating municipal wastewater

This study analyzed the performances of a hybrid membrane aerated biofilm reactor (MABR) pilot plant in terms of nutrients removal of the attached growth and suspended biomass in comparison with a conventional activated sludge (CAS) system at different sludge retention time (SRT) (20−3) days. Overall, the MABR showed better performances than the CAS in terms of TSS (86% vs 79%), COD (89% vs 85%) and total nitrogen (80% vs 65%). The minimum SRT for achieving complete nitrification in the MABR was close to 3 days, corresponding to a SRT in the aerobic compartment of 1.9 days, whereas in the CAS it was equal to 8 days (aerobic SRT of 4.8 days). Nitrification rate in biofilm was on average equal to 0.40 gNH4-N h−1 (2.40 gNH4-N m−2d−1). Its contribution to the overall nitrification in the MABR plant was 25–30% on average, although it increased when the SRT was decreased. Particle size distribution and microscopic analyses showed particles of biofilm detached from the membrane of the MABR. The seeding effect allowed sustaining nitrification of the suspend biomass at very low SRT. The nitrification rate observed in the suspended biomass in the MABR slightly decreased from 3.42 mgNH4-N gVSS−1 h−1 to 2.87 mgNH4-N gVSS−1 h−1 when the SRT was decreased from 20 days and 3 days, whereas in the CAS it collapsed from 2.33 mgNH4-N gVSS−1 h−1 to 0.47 mgNH4-N gVSS−1 h−1, because of nitrifying washout. Moreover, the biofilm detachment involved a positive effect in settling properties of the suspended biomass

Adolescent rats are resistant to forming ethanol seeking habits

AbstractEarly age of onset alcohol drinking is significantly more likely to lead to alcohol use disorders (AUDs) than alcohol drinking that begins after the age of 18. Unfortunately, the majority of people in the United States begin drinking in adolescence. Therefore, it is important to understand how early alcohol drinking leads to increased risk for AUDs so that better treatments and prevention strategies can be developed. Adolescents perceive greater rewarding properties of alcohol, and adolescents may be more likely to form alcohol-seeking habits that promote continued use throughout the lifetime. Therefore, we compared the development of alcohol seeking habits in adolescent and adult male, Sprague-Dawley rats. Rats were trained to lever press to receive 10% ethanol+0.1% saccharin on a schedule that promotes habit formation. Rats were tested using a contingency degradation procedure at different points in training. Adult rats formed ethanol-seeking habits with only moderate training, while adolescents remained goal-directed even with extended training. Nevertheless, adolescents consumed more ethanol than adults throughout the experiment and continued to consume more ethanol than adults when they reached adulthood. Therefore, early onset alcohol use may promote AUD formation through establishment of high levels of drinking that becomes habitual in adulthood

BioMAc 2016 Bioreattori a membrane (MBR) e trattamenti avanzati per la depurazione delle acque

Questo volume raccoglie i contributi presentati nella manifestazione BioMAc 2016: Bioreattori a Membrane (MBR) e trattamenti avanzati per la depurazione delle Acque, che ha avuto luogo presso il Dipartimento di Ingegneria Civile, Ambientale, Aerospaziale, dei Materiali dell'Universit\ue0 degli Studi di Palermo, Aula G. Capit\uf2, nei giorni 27 e 28 ottobre 2016

Biomethane production from anaerobic co-digestion of selected organic fraction of municipal solid waste (Ofmsw) with sewage sludge: Effect of the inoculum to substrate ratio (isr) and mixture composition on process performances

The aim of this study was to evaluate the effect of the inoculum to substrate ratio (ISR) and the mixture ratio between organic fraction of municipal solid waste (OFMSW) and sewage sludge (SS) on the methane production potential achievable from anaerobic co-digestion (AcoD). Biochemical Methane Potential (BMP) assays at mesophilic temperature were used to determine the best AcoD configuration for maximizing methane yield and production rate, as well as to address possible synergistic effects. The maximum methane yield was observed at ISR of 1 and 60% OFMSW:40% SS as co-digestion mixture, whereas the highest methane production rate was achieved at ISR of 2 with the same mixture ratio (207 mL/gVS/d). Synergistic effects were highlighted in the mix-tures having OFMSW below 60%, determining an increase of approximately 40% in methane production than the OFMSW and SS digestion as a sole substrate. The experimental data demonstrated that co-digestion of OFMSW and SS resulted in an increase in the productivity of methane than anaerobic digestion using the sole substrates, producing higher yields or production rates while depending on the ISR and the mixture ratio

Treatment of high strength industrial wastewater with membrane bioreactors for water reuse: Effect of pre-treatment with aerobic granular sludge on system performance and fouling tendency

In this study, the treatment of citrus wastewater with membrane bioreactors (MBRs) under different configurations was investigated for water reuse. In particular, one MBR and one aerobic granular sludge MBR (AGS+MBR) bench scale plants were operated for 60 days. The experimental campaign was divided into two periods. In Phase I, a conventional hollow fiber MBR was employed for the treatment of the raw high strength wastewater, whereas in Phase II a combination of in-series reactors (AGS plus MBR) was adopted for the treatment of the high strength citrus wastewater The results demonstrated that both plant configurations enabled very high COD removal, with average values close to 99%. Respirometric batch tests revealed a considerable high metabolic activity of the biomass in both plant configurations, with higher values in the AGS+MBR. It was speculated that the MBR reactor enriched in active biomass deriving from the erosion of the external granule layers in the upstream reactor. In terms of fouling tendency, higher resistance to filtration was observed in the AGS+MBR plant, also characterized by higher irremovable resistance increase compared to the MBR plant that might severely affect the membrane service life

An innovative respirometric method to assess the autotrophic active fraction: Application to an alternate oxic-anoxic MBR pilot plant

An innovative respirometric method was applied to evaluate the autotrophic active fraction in an alternate anoxic/oxic membrane bioreactor (MBR) pilot plant. The alternate cycle (AC) produces a complex microbiological environment that allows the development of both autotrophic and heterotrophic species in one reactor. The present study aimed to evaluate autotrophic and heterotrophic active fractions and highlight the effect of different aeration/non aeration ratios in a AC-MBR pilot plant using respirometry. The results outlined that the autotrophic active fraction values were consistent with the nitrification efficiency and FISH analyses, which suggests its usefulness for estimating the nitrifying population. Intermittent aeration did not significantly affect the heterotrophic metabolic activity but significantly affected the autotrophic biomass development. Finally, the heterotrophic active biomass was strongly affected by the wastewater characteristics, whereas the resultant autotrophic biomass was considerably affected by the duration of the aerated phase