6 research outputs found
Machine Learning-Guided Synthesis of Room-Temperature Phosphorescent Carbon Dots for Enhanced Phosphorescence Lifetime and Information Encryption
Room-temperature phosphorescent (RTP) carbon dots (CDs)
have been
increasingly used in many applications, including anticounterfeiting
and information encryption. However, synthesizing RTP CDs with a specific
average lifetime of phosphorescence remains a formidable challenge.
A breakthrough is needed in formulating the synthesis process to find
a suitable synthesis formulation to produce CDs with an optimal lifetime
of phosphorescence. Machine learning (ML) has recently been successfully
used for guiding material synthesis and offering insight into the
prediction, optimization, and acceleration of the CDs’ synthesis
process. A regression ML model on microwave-assisted CD synthesis
is established to reveal the relationship between various synthesis
parameters and enhance the average lifetime of phosphorescence of
CDs in the solid-state phase. RTP CDs exhibit a blue emission when
irradiating with UV and a green emission afterglow after the UV is
turned off. These green emissions can last for 7 s, are easily observed
by the naked eye, and show an ultralong phosphorescence lifetime of
up to 1.6 s. Moreover, designed and guided by ML, this afterglow feature
was explored to achieve multilevel anticounterfeiting and information
encryption to encrypt and decrypt secret information in dynamic time-dependent
displays. Our results provide a strategy for synthesizing RTP CDs
with a specific lifetime and extending their application scope to
high-level information security
Machine Learning-Guided Synthesis of Room-Temperature Phosphorescent Carbon Dots for Enhanced Phosphorescence Lifetime and Information Encryption
Room-temperature phosphorescent (RTP) carbon dots (CDs)
have been
increasingly used in many applications, including anticounterfeiting
and information encryption. However, synthesizing RTP CDs with a specific
average lifetime of phosphorescence remains a formidable challenge.
A breakthrough is needed in formulating the synthesis process to find
a suitable synthesis formulation to produce CDs with an optimal lifetime
of phosphorescence. Machine learning (ML) has recently been successfully
used for guiding material synthesis and offering insight into the
prediction, optimization, and acceleration of the CDs’ synthesis
process. A regression ML model on microwave-assisted CD synthesis
is established to reveal the relationship between various synthesis
parameters and enhance the average lifetime of phosphorescence of
CDs in the solid-state phase. RTP CDs exhibit a blue emission when
irradiating with UV and a green emission afterglow after the UV is
turned off. These green emissions can last for 7 s, are easily observed
by the naked eye, and show an ultralong phosphorescence lifetime of
up to 1.6 s. Moreover, designed and guided by ML, this afterglow feature
was explored to achieve multilevel anticounterfeiting and information
encryption to encrypt and decrypt secret information in dynamic time-dependent
displays. Our results provide a strategy for synthesizing RTP CDs
with a specific lifetime and extending their application scope to
high-level information security
Synthesis of Submicron-Sized Spherical Silica-Coated Iron Nickel Particles with Adjustable Shell Thickness via Swirler Connector-Assisted Spray Pyrolysis
Silica-coated iron nickel (FeNi@SiO2) particles
have
attracted significant attention because of their potential applications
in electronic devices. In this work, submicron-sized spherical FeNi@SiO2 particles with precisely controllable shell thickness were
successfully synthesized for the first time using a swirler connector-assisted
spray pyrolysis system, comprising a preheater, specific connector,
and main heater. The results indicated that the thickness of the SiO2 shell can be tuned from 3 to 23 nm by adjusting the parameter
conditions (i.e., preheater temperature, SiO2 supplied
amount). Furthermore, our fabrication method consistently yielded
a high coating ratio of more than 94%, indicating an excellent quality
of the synthesized particles. Especially, to gain an in-depth understanding
of the particle formation process of the FeNi@SiO2 particles,
a plausible mechanism was also investigated. These findings highlight
the importance of controlling the preheater and SiO2 supplied
amount to obtain FeNi@SiO2 particles with desirable morphology
and high coating quality
Controllable Synthesis of Porous and Hollow Nanostructured Catalyst Particles and Their Soot Oxidation
The introduction of macroporous structures into three-way
catalysts
(TWCs) through polymer template-assisted spray drying has attracted
attention because of its enhanced gas diffusion and catalytic performance.
However, the surface charge effect of polymeric template components
has not been investigated to control the structure of the TWC particles
during synthesis. Thus, this study investigated the effect of template
surface charges on the self-assembly behavior of TWC nanoparticles
(NPs) during drying. The self-assembly of TWC NPs and polymer particles
with different charges produced a hollow structure, whereas using
the same charges generated a porous one. Consequently, the mechanism
of particle self-assembly during drying and final structure particle
formation is proposed in this study. Here, porous TWC particles demonstrated
a faster oxidation of soot particles than that of hollow-structured
particles. This occurred as a result of the larger contact area between
the catalyst surface and the solid reactant. Our findings propose
a fundamental self-assembly mechanism for the formation of different
TWC structures, thereby enhancing soot oxidation performance using
macroporous structures
One-Step Aerosol Synthesis of SiO<sub>2</sub>‑Coated FeNi Particles by Using Swirler Connector-Assisted Spray Pyrolysis
Silica-coated soft magnetic particles are essential for
some powder
magnetic cores consisting of primary (coarse particles) and secondary
(fine particles) soft magnetic particles in the advancement of electric
devices. Herein, we report the first investigation on the direct synthesis
of submicron-sized silica-coated FeNi (FeNi@SiO2) particles
as the secondary particle using a connector-assisted spray pyrolysis
route. Provided by computational fluid dynamics calculation in applying
different connector types, i.e., T-shaped and swirler, we found that
the mixing performance between FeNi and HMDSO vapor in the swirler
connector played an important role in resulting heterogeneous nucleation,
which is crucial for obtaining the higher coating ratio (CR) and fewer
undesired nanoparticles than that of the T-shaped connector. The as-prepared
submicron-sized FeNi@SiO2 particles (353 nm) with the highest
CR (95.9%) demonstrated a remarkable DC bias characteristic (Isat) and eddy current loss values on a powder
magnetic core, promising the practical application in manufacturing
soft magnetic components
Controlling the Magnetic Responsiveness of Cellulose Nanofiber Particles Embedded with Iron Oxide Nanoparticles
2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO)-oxidized
cellulose
nanofiber (TOCN) particles, an innovative biobased material derived
from wood biomass, have garnered significant interest, particularly
in the biomedical field, for their distinctive properties as biocompatible
particle adsorbents. However, their microscopic size complicates their
separation in liquid media, thereby impeding their application in
various domains. In this study, superparamagnetic magnetite nanoparticles
(NPs), specifically iron oxide Fe3O4 NPs with
an average size of 15 nm, were used to enhance the collection efficiency
of TOCN-Fe3O4 composite particles synthesized
through spray drying. These composite particles exhibited a remarkable
ζ-potential (approximately −50 mV), indicating their
high stability in water, as well as impressive magnetization properties
(up to 47 emu/g), and rapid magnetic responsiveness within 60 s in
water (3 wt % Fe3O4 to TOCN, 1 T magnet). Furthermore,
the influence of Fe3O4 NP concentrations on
the measurement of the speed of magnetic separation was quantitatively
discussed. Additionally, the binding affinity of the synthesized particles
for proteins was assessed on a streptavidin–biotin binding
system, offering crucial insights into their binding capabilities
with specific proteins and underscoring their significant potential
as functionalized biomedical materials