Jahn-Teller effect and stability of the charge-ordered state in La1-xCaxMnO3 (0.5<x<0.9) manganites

The longitudinal ultrasonic sound velocity and attenuation, the resistivity, and lattice parameters were studied as a function of temperature from 30 K to 300 K in La1-xCaxMnO3 (0.5<x<0.9). For all the samples, a dramatic stiffening of the sound velocity below the charge ordering transition temperature TCO was directly driven by distinct changes of the lattice parameters due to the formation of long range ordering of Jahn-Teller distorted MnO6 octahedra. The relative change of the sound velocity (DeltaV/V) below TCO depends on the Ca concentration x and reaches the maximum at x=0.75, implying that the effective strength of electron-lattice interaction with the Jahn-Teller distortion is the strongest at x=0.75 and hence the charge ordered state is mostly stabilized near x=0.75 and insensitive to the application of a magnetic field, which is supported by the charge transport properties under high magnetic fields up to 14T.Comment: 16 pages, 5 figures, PD

Soft spin waves in the low temperature thermodynamics of Pr_{0.7}Ca_{0.3}MnO_{3}

We present a detailed magnetothermal study of Pr(0.7)Ca(0.3)MnO(3), a perovskite manganite in which an insulator-metal transition can be driven by magnetic field, but also by pressure, visible light, x-rays, or high currents. We find that the field-induced transition is associated with an enormous release of energy which accounts for its strong irreversibility. In the ferromagnetic metallic state, specific heat and magnetization measurements indicate a much smaller spin wave stiffness than that seen in any other manganite, which we attribute to spin waves among the ferromagnetically ordered Pr moments. The coupling between the Pr and Mn spins may also provide a basis for understanding the low temperature phase diagram of this most unusual manganite.Comment: 10 pages, LATEX, 5 PDF figures, corrected typo

Interplay of the CE-type charge ordering and the A-type spin ordering in a half-doped bilayer manganite La{1}Sr{2}Mn{2}O{7}

We demonstrate that the half-doped bilayer manganite La_{1}Sr_{2}Mn_{2}O_{7} exhibits CE-type charge-ordered and spin-ordered states below $T_{N, CO}^A = 210$ K and below $T_{N}^{CE} \sim 145$ K, respectively. However, the volume fraction of the CE-type ordering is relatively small, and the system is dominated by the A-type spin ordering. The coexistence of the two types of ordering is essential to understand its transport properties, and we argue that it can be viewed as an effective phase separation between the metallic $d(x^{2}-y^{2})$ orbital ordering and the charge-localized $d(3x^{2}-r^{2})/d(3y^{2}-r^{2})$ orbital ordering.Comment: 5 pages, 4 figures, submitted to Phys. Rev.

Persistent X-Ray Photoconductivity and Percolation of Metallic Clusters in Charge-Ordered Manganites

Charge-ordered manganites of composition $\rm Pr_{1-x}(Ca_{1-y}Sr_{y})_{x}MnO_3$ exhibit persistent photoconductivity upon exposure to x-rays. This is not always accompanied by a significant increase in the {\it number} of conduction electrons as predicted by conventional models of persistent photoconductivity. An analysis of the x-ray diffraction patterns and current-voltage characteristics shows that x-ray illumination results in a microscopically phase separated state in which charge-ordered insulating regions provide barriers against charge transport between metallic clusters. The dominant effect of x-ray illumination is to enhance the electron {\it mobility} by lowering or removing these barriers. A mechanism based on magnetic degrees of freedom is proposed.Comment: 8 pages, 4 figure

Anomalous ferromagnetic spin fluctuations in an antiferromagnetic insulator Pr_{1-x}Ca_{x}MnO_{3}

The high temperature paramagnetic state in an antiferromagnetic (AFM) insulator Pr_{1-x}Ca_{x}MnO_{3} is characterized by the ferromagnetic (FM) spin fluctuations with an anomalously small energy scale. The FM fluctuations show a precipitous decrease of the intensity at the charge ordering temperature T_{CO}, but persist below T_{CO}, and vanish at the AFM transition temperature T_{N}. These results demonstrate the importance of the spin ordering for the complete switching of the FM fluctuation in doped manganites.Comment: REVTeX, 5 pages, 4 figures, submitted to Phys. Rev.

Evolution of spin-wave excitations in ferromagnetic metallic manganites

Neutron scattering results are presented for spin-wave excitations of three ferromagnetic metallic $A_{1-x}A^{\prime}_{x}$MnO$_3$ manganites (where $A$ and $A^\prime$ are rare- and alkaline-earth ions), which when combined with previous work elucidate systematics of the interactions as a function of carrier concentration $x$, on-site disorder, and strength of the lattice distortion. The long wavelength spin dynamics show only a very weak dependence across the series. The ratio of fourth to first neighbor exchange ($J_4/J_1$) that controls the zone boundary magnon softening changes systematically with $x$, but does not depend on the other parameters. None of the prevailing models can account for these behaviors.Comment: Submitted to Phys. Rev. Let

The algebraic combinatorial approach for low-rank matrix completion

We propose an algebraic combinatorial framework for the problem of completing partially observed low-rank matrices. We show that the intrinsic properties of the problem, including which entries can be reconstructed, and the degrees of freedom in the reconstruction, do not depend on the values of the observed entries, but only on their position. We associate combinatorial and algebraic objects, differentials and matroids, which are descriptors of the particular reconstruction task, to the set of observed entries, and apply them to obtain reconstruction bounds. We show how similar techniques can be used to obtain reconstruction bounds on general compressed sensing problems with algebraic compression constraints. Using the new theory, we develop several algorithms for low-rank matrix completion, which allow to determine which set of entries can be potentially reconstructed and which not, and how, and we present algorithms which apply algebraic combinatorial methods in order to reconstruct the missing entries

Signature of Magnetic Phase Separation in the Ground State of Pr1-xCaxMnO3

Neutron scattering has been used to investigate the evolution of the long- and short-range charge-ordered (CO), ferromagnetic (FM), and antiferromagnetic (AF) correlations in single crystals of Pr1-xCaxMnO3. The existence and population of spin clusters as refected by short-range correlations are found to drastically depend on the doping (x) and temperature (T). Concentrated spin clusters coexist with long-range canted AF order in a wide temperature range in x = 0.3 while clusters do not appear in x = 0.4 crystal. In contrast, both CO and AF order parameters in the x = 0.35 crystal show a precipitous decrease below ~ 35 K where spin clusters form. These results provide direct evidence of magnetic phase separation and indicate that there is a critical doping x_c (close to x = 0.35) that divides the phase-separated site-centered from the homogeneous bond-centered or charge-disproportionated CO ground state.Comment: 4 pages, 4 figures, submitted to Phys. Rev. Letter

Temperature dependent d-d excitations in manganites probed by resonant inelastic x-ray scattering

We report the observation of temperature dependent electronic excitations in various manganites utilizing resonant inelastic x-ray scattering (RIXS) at the Mn K-edge. Excitations were observed between 1.5 and 16 eV with temperature dependence found as high as 10 eV. The change in spectral weight between 1.5 and 5 eV was found to be related to the magnetic order and independent of the conductivity. On the basis of LDA+U and Wannier function calculations, this dependence is associated with intersite d-d excitations. Finally, the connection between the RIXS cross-section and the loss function is addressed.Comment: 5 pages, 5 figure