Quantum reactive scattering in the long-range ion-dipole potential

An ion and a polar molecule interact by an anisotropic ion-dipole potential scaling as $- \alpha \cos (\theta)/r^2$ at large distances. Due to its long-range character, it modifies the properties of angular wave functions, which are no longer given by spherical harmonics. In addition, an effective centrifugal potential in the radial equation can become attractive for low angular momenta. In this paper, we develop a general framework for an ion-dipole reactive scattering, focusing on the regime of large $\alpha$. We introduce modified spherical harmonics as solutions of the angular part of the Schr\"odinger equation and derive several useful approximations in the limit of large $\alpha$. We present a formula for the scattering amplitude expressed in terms of the modified spherical harmonics and we derive expressions for the elastic and reactive collision rates. The solutions of the radial equation are given by Bessel functions, and we analyse their behaviour in two distinct regimes corresponding, basically, to attractive and repulsive long-range centrifugal potentials. Finally, we study reactive collisions in the universal regime, where the short-range probability of loss or reaction is equal to unity.Comment: 19 pages, 11 figures, 5 appendice

Multipartite-Entanglement Dynamics in Regular-to-Ergodic Transition: a Quantum-Fisher-Information approach

The characterization of entanglement is a central problem for the study of quantum many-body dynamics. Here, we propose the quantum Fisher information as a useful tool for the study of multipartite-entanglement dynamics in many-body systems. We illustrate this by considering the regular-to-ergodic transition in the Dicke model---a fully-connected spin model showing quantum thermalization above a critical interaction strength. We show that the QFI has a rich dynamical behavior which drastically changes across the transition. In particular, the asymptotic value of the QFI, as well as its characteristic timescales, witness the transition both through their dependence on the interaction strength and through the scaling with the system size. Since the QFI also sets the ultimate bound for the precision of parameter estimation, it provides a metrological perspective on the characterization of entanglement dynamics in many-body systems. Here we show that quantum ergodic dynamics allows for a much faster production of metrologically useful states.Comment: 9 pages, 10 figure

Generation of scalable many-body Bell correlations in spin chains with short-range two-body interactions

Dynamical generation of strong and scalable quantum resources, like many-body entanglement and Bell correlations, in spin-$1/2$ chains, is possible with all-to-all interactions, either for constant interaction strength realizing one-axis twisting protocol or for power-law decaying potentials. We show, however, that such quantum resources can also be dynamically generated with a finite range of interactions. We identify a necessary critical range and indicate a critical time when scalable quantum correlations appear. Finally, we show that the certification of generated states is accessible in the modern quantum simulator platforms.Comment: 6 figure