A test-retest study of the keeler pulsair hand-held tonometer

In this study the Keeler Pulsair non-contact tonometer was compaired to itself in a test-retest study. lOP measurements from 20 subjects (age5-42) were utilized. Five groups of four lOP readings were taken 15 minutes apart to minimize massage effect and eliminate diurnal effect. The mean readings were: 13.53 mm Hg with SD 3.6 mm Hg for 00 and 13.39 mm Hg with SO 3.7 mm Hg for OS. The mean difference between tests was significant only for comparisons 00-1 vs.OD-2, 00-1 vs.OD-4 and 00-1 vs.OD-5 due to increased patient apprehension in group 00-1. The design of the Keeler pulsair tonometer provides certain advantages over other tonometers with respect to special patient application and ease of operation. My results indicate there is a need for a future test-retest study which would deal further to alleviate patient apprehension

Phonons in Nanocrystalline 57Fe

We measured the phonon density of states (DOS) of nanocrystalline Fe by resonant inelastic nuclear γ-ray scattering. The nanophase material shows large distortions in its phonon DOS. We attribute the high energy distortion to lifetime broadening. A damped harmonic oscillator model for the phonons provides a low quality factor, Qu, averaging about 5, but the longitudinal modes may have been broadened most. The nanocrystalline Fe also shows an enhancement in its phonon DOS at energies below 15 meV. The difference in vibrational entropy of the bulk and nanocrystalline Fe was small, owing to competing changes in the nanocrystalline phonon DOS at low and high energies

Six-reflection meV-monochromator for synchrotron radiation

A design is presented for a cryogenically stabilized monochromator for 10–40 keV synchrotron radiation that uses six crystal reflections to achieve a meV-bandpass with high efficiency

Local Chemical Environments and the Phonon Partial Densities of States of 57Fe in 57Fe3Al

Inelastic nuclear resonant scattering spectra were measured on alloys of Fe3Al that were chemically disordered, partially ordered, and D03 ordered. The features in the phonon partial density of states of 57Fe were found to change systematically with chemical short-range order in the alloy. Changes in the phonon partial density of states were modeled successfully by assigning vibrational spectra to 57Fe atoms in different first-nearest-neighbor chemical environments

Atom clusters and vibrational excitations in chemically-disordered Pt357Fe

Inelastic nuclear resonant scattering spectra of Fe-57 atoms were measured on crystalline alloys of Pt3Fe-57 that were chemically disordered, partially ordered, and L1(2) ordered. Phonon partial density of states curves for Fe-57 were obtained from these spectra. Upon disordering, about 10% of the spectral intensity underwent a distinct shift from 25 to 19 meV. This change in optical modes accounted for most of the change of the vibrational entropy of disordering contributed by Fe atoms, which was (+0.10 +/- 0.03) k(B) (Fe atom)(-1). Prospects for parametrizing the vibrational entropy with low-order cluster variables were assessed. To calculate the difference in vibrational entropy of the disordered and ordered alloys, the clusters must be large enough to account for the abundances of several of the atom configurations of the first-nearest-neighbor shell about the Fe-57 atoms

Vibrational modes in nanocrystalline iron under high pressure

The phonon density of states (DOS) of nanocrystalline 57Fe was measured using nuclear resonant inelastic x-ray scattering (NRIXS) at pressures up to 28 GPa in a diamond anvil cell. The nanocrystalline material exhibited an enhancement in its DOS at low energies by a factor of 2.2. This enhancement persisted throughout the entire pressure range, although it was reduced to about 1.7 after decompression. The low-energy regions of the spectra were fitted to the function AEn, giving values of n close to 2 for both the bulk control sample and the nanocrystalline material, indicative of nearly three-dimensional vibrational dynamics. At higher energies, the van Hove singularities observed in both samples were coincident in energy and remained so at all pressures, indicating that the forces conjugate to the normal coordinates of the nanocrystalline materials are similar to the interatomic potentials of bulk crystals

New developments in fabrication of high-energy-resolution analyzers for inelastic X-ray spectroscopy

New improvements related to the fabrication of spherical bent analyzers for 1 meV energy-resolution inelastic X-ray scattering spectroscopy are presented

Dynamics of iron atoms across the pressure-induced Invar transition in Pd_3Fe

The ^(57)Fe phonon partial density of states (PDOS) in L1_2-ordered Pd_3Fe was studied at high pressures by nuclear resonant inelastic x-ray scattering (NRIXS) measurements and density functional theory (DFT) calculations. The NRIXS spectra showed that the stiffening of the ^(57)Fe PDOS with decreasing volume was slower from 12 to 24 GPa owing to the pressure-induced Invar transition in Pd_3Fe, with a change from a high-moment ferromagnetic (FM) state to a low-moment (LM) state observed by nuclear forward scattering. Force constants obtained from fitting to a Born–von Kármán model showed a relative softening of the first-nearest-neighbor (1NN) Fe-Pd longitudinal force constants at the magnetic transition. For the FM low-pressure state, the DFT calculations gave a PDOS and 1NN longitudinal force constants in good agreement with experiment, but discrepancies for the high-pressure LM state suggest the presence of short-range magnetic order