69 research outputs found

    Vacuum-ultraviolet frequency-modulation spectroscopy

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    Frequency-modulation (FM) spectroscopy has been extended to the vacuum-ultraviolet (VUV) range of the electromagnetic spectrum. Coherent VUV laser radiation is produced by resonance-enhanced sum-frequency mixing (νVUV=2νUV+ν2\nu_{\mathrm{VUV}}=2\nu_{\mathrm{UV}}+\nu_2) in Kr and Xe using two near-Fourier-transform-limited laser pulses of frequencies νUV\nu_{\mathrm{UV}} and ν2\nu_2. Sidebands generated in the output of the second laser (ν2\nu_2) using an electro-optical modulator operating at the frequency νmod\nu_{\mathrm{mod}} are directly transfered to the VUV and used to record FM spectra. Demodulation is demonstrated both at νmod\nu_{\mathrm{mod}} and 2νmod2\nu_{\mathrm{mod}}. The main advantages of the method are that its sensitivity is not reduced by pulse-to-pulse fluctuations of the VUV laser intensity, compared to VUV absorption spectroscopy is its background-free nature, the fact that its implementation using table-top laser equipment is straightforward and that it can be used to record VUV absorption spectra of cold samples in skimmed supersonic beams simultaneously with laser-induced-fluorescence and photoionization spectra. To illustrate these advantages we present VUV FM spectra of Ar, Kr, and N2_2 in selected regions between 105000cm−1^{-1} and 122000cm−1^{-1}.Comment: 23 pages, 10 figure
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