Highly efficient and stable planar heterojunction solar cell based on sputtered and post-selenized Sb2Se3 thin film

Antimony selenide (Sb2Se3) is regarded as one of the key alternative absorber materials for conventional thin film solar cells due to its excellent optical and electrical properties. Here, we proposed a Sb2Se3 thin film solar cell fabricated using a two-step process magnetron sputtering followed by a post-selenization treatment, which enabled us to optimize the best quality of both the Sb2Se3 thin film and the Sb2Se3/CdS heterojunction interface. By tuning the selenization parameters, a Sb2Se3 thin film solar cell with high efficiency of 6.06% was achieved, the highest reported power conversion efficiency of sputtered Sb2Se3 planar heterojunction solar cells. Moreover, our device presented an outstanding open circuit voltage (VOC) of 494 mV which is superior to those reported Sb2Se3 solar cells. State and density of defects showed that proper selenization temperature could effectively passivate deep defects for the films and thus improve the device performance

The Radiative Decay of Vector Mesons

In this paper, radiative decays $\rho^0 \to \pi^+\pi^-\gamma, \pi^0\pi^0\gamma$ ,$\phi \to K^+K^-\gamma, K^0 \bar{K^0}\gamma$ are studied systematically in the U(3)_L\timesU(3)_R chiral theory of mesons. The theoretical differential spectrum with respect to photon energy and branch ratio for $\rho^0 \to \pi^+\pi^-\gamma$ agree well with the experimental data. Differential spectrums and branch ratios for $\rho^0 \to \pi^0\pi^0\gamma, \phi \to K^+ K^-\gamma,\phi \to K^0\bar{K^0}\gamma$ are predicted. The process $\phi \to K^0 \bar{K^0} \gamma$ is relevant to precision measurment of CP-violation parameters in the kaon systerm at a $\phi$-factory. We give a complete estimate of the branch ratio for this decay process by including scalar resonance $f_0, a_0$ poles, nonresonant smooth amplitude and an abnormal parity process with $K^*$ pole which hasn't been considered before. We conclude that processes with intermediate $K^*$ do not pose a potential background problem for $\phi\to K^0\bar{K}^0$ CP violation experiments.Comment: Revtex file, 12 pages, 9 eps figure

Moyal Representation of the String Field Star Product in the Presence of a B-background

In this paper we show that in the presence of an anti-symmetric tensor $B$-background, Witten's star algebra for open string fields persists to possess the structure of a direct product of commuting Moyal pairs. The interplay between the noncommutativity due to three-string overlap and that due to the $B$-background is our main concern. In each pair of noncommutative directions parallel to the $B$-background, the Moyal pairs mix string modes in the two directions and are labeled, in addition to a continuous parameter, by {\it two} discrete values as well. However, the Moyal parameters are $B$-dependent only for discrete pairs. We have also demonstrated the large-$B$ contraction of the star algebra, with one of the discrete Moyal pairs dropping out while the other giving rise to the center-of-mass noncommutative function algebra.Comment: minor notation chang

Feasibility and reliability analysis of LCC DC grids and LCC/VSC hybrid DC grids

Power system interconnections using high-voltage direct-current (HVDC) technologies between different areas can be an effective solution to enhance system efficiency and reliability. Particularly, the multi-terminal DC grids, that could balance and ensure resource adequacy, increase asset utilization and reduce costs. In this paper, the technical feasibility of building DC grids using the line commutated converter based (LCC) and voltage source converter based (VSC) HVDC technologies are discussed. Apart from presenting the technical challenges of building LCC DC grids and LCC/VSC hybrid DC grids, the reliability modeling and analysis of these DC grids are also presented. First, the detailed reliability model of the modular multi-level converters (MMCs) with series connected high-voltage and low-voltage bridges are developed. The active mode redundancy design is considered for the reliability model. To this end, a comprehensive whole system reliability model of the studied systems is developed. The reliability model of each subsystem is modeled in detail. Various reliability indices are calculated using this whole system reliability model. The impacts of the redundancy design of the MMCs on these indices are presented. The studies of this paper provide useful guidance for DC grid design and reliability analysis

Control strategies of full-voltage to half-voltage operation for LCC and hybrid LCC/MMC based UHVDC systems

With the increasing demand of transmitting bulk-power over long-distance, the ultra high-voltage direct-current (UHVDC) transmission systems become an attractive option. Nowadays, not only the line commutated converter (LCC) based systems, but also the modular multilevel converter (MMC) based systems have reached UHVDC levels. The converter stations of UHVDC systems normally utilize two series-connected valve-groups to reduce the difficulties of device manufacturing and transportation. This high-voltage and low-voltage valve-group configuration allows the UHVDC systems to achieve a full-voltage to half-voltage operation which increases the flexibility of the systems. However, the existing research only focuses on the full-voltage to half-voltage control of LCC-UHVDC systems. The control strategies for hybrid LCC/MMC UHVDC systems are underresearched. Moreover, the approaches to reduce the load-shedding caused by the full-voltage to half-voltage control for both LCC and hybrid LCC/MMC based UHVDC systems have not been investigated. In this paper, full-voltage to half-voltage control strategies for both LCC and hybrid LCC/MMC based UHVDC systems have been proposed. Moreover, to avoid load-shedding caused by the half-voltage operation, a power rescheduling method that re-sets the power references of the half-voltage operating and full-voltage operating poles has been proposed. The proposed full-voltage to half-voltage control strategies and power rescheduling method can achieve a stable and fast control process with a minimum power loss. The proposed methods have been verified through the time-domain simulations conducted in PSCAD/EMTDC

Numerical simulation of electro−thermal coupling process for spent cathode carbon block from aluminum electrolysis cell

Spent cathode carbon block (SCCB) is considered to be a kind of hazardous waste, because it contains a large amount of soluble fluoride salts and toxic cyanides. The life of an aluminum electrolytic cell is generally 5−8 years, and the SCCB would be produced during the overhaul of the cell. Currently, most SCCBs are piled in landfills or stored for disposal in China. The unreasonable disposal of SCCBs will cause serious pollution and damage to the ecological environment, and wastage of valuable carbon material and fluoride salts. The key to the safe disposal and resource utilization of SCCBs is to separate the carbon and fluoride salts deeply. In this study, SCCB was treated by the pyrometallurgical process, and the characteristics of volatilization temperature of fluoride salts were firstly experimentally determined. For a laboratory-scale self-designed high temperature resistance furnace, a three-dimensional model was built and numerical calculation was performed. The heat transfer characteristics, temperature control law and effective volatilization region of fluoride salts were analyzed in detail. The experimental results demonstrate that the effective volatilization temperature of fluoride is higher than 1700 ℃, and the volatilization rate is higher than 93.1%. By simulating the evolution of the temperature field in the furnace under different power supply modes, it is obtained that under the power supply condition of heating at 12 V for 24 h and holding 9 V for 12 h, the maximum temperature in the furnace during the heating phase can reach 2250 ℃, and the theoretical volatilization volume of fluoride salts can reach 98%. After optimization, a step-by-step decreasing mode of power supply can improve the efficiency of treating SCCBs. Moreover, the treating temperature can be maintained for 20 h at 1700 ℃, which is beneficial to the deep separation of carbon material and fluoride salts in SCCB

6-Methyl­pyridine-2(1H)-thione

There are two unique mol­ecules in the asymmetric unit of the title pyridine­thione derivative, C6H7NS, each of which adopts the thione rather than the mercaptan form. The rings in both mol­ecules are essentially planar, with maximum deviations from the least-squares planes through all non-H atoms of 0.021 (2) and 0.017 (2) Å. In the crystal structure, the mol­ecules form centrosymmetric cyclic dimers through inter­molecular N—H⋯S hydrogen bonds. Additional C—H(meth­yl)⋯S inter­actions generate a three-dimensional network

Analysis of shared ceRNA networks and related-hub genes in rats with primary and secondary photoreceptor degeneration

IntroductionPhotoreceptor degenerative diseases are characterized by the progressive death of photoreceptor cells, resulting in irreversible visual impairment. However, the role of competing endogenous RNA (ceRNA) in photoreceptor degeneration is unclear. We aimed to explore the shared ceRNA regulation network and potential molecular mechanisms between primary and secondary photoreceptor degenerations.MethodsWe established animal models for both types of photoreceptor degenerations and conducted retina RNA sequencing to identify shared differentially expressed long non-coding RNAs (lncRNAs), microRNAs (miRNAs), and messenger RNAs (mRNAs). Using ceRNA regulatory principles, we constructed a shared ceRNA network and performed function enrichment and protein–protein interaction (PPI) analyses to identify hub genes and key pathways. Immune cell infiltration and drug–gene interaction analyses were conducted, and hub gene expression was validated by quantitative real-time polymerase chain reaction (qRT-PCR).ResultsWe identified 37 shared differentially expressed lncRNAs, 34 miRNAs, and 247 mRNAs and constructed a ceRNA network consisting of 3 lncRNAs, 5 miRNAs, and 109 mRNAs. Furthermore, we examined 109 common differentially expressed genes (DEGs) through functional annotation, PPI analysis, and regulatory network analysis. We discovered that these diseases shared the complement and coagulation cascades pathway. Eight hub genes were identified and enriched in the immune system process. Immune infiltration analysis revealed increased T cells and decreased B cells in both photoreceptor degenerations. The expression of hub genes was closely associated with the quantities of immune cell types. Additionally, we identified 7 immune therapeutical drugs that target the hub genes.DiscussionOur findings provide new insights and directions for understanding the common mechanisms underlying the development of photoreceptor degeneration. The hub genes and related ceRNA networks we identified may offer new perspectives for elucidating the mechanisms and hold promise for the development of innovative treatment strategies

Acute primary angle closure during the Omicron outbreak

AIM: To investigate Omicron's impact on clinical presentation of acute primary angle closure (APAC) in China. METHODS: A consecutive case series with historical controls was conducted at Shenzhen Eye Hospital, the largest specialized hospital in Shenzhen, China. Medical records from a two-month period during the Omicron pandemic (December 1, 2022, to January 31, 2023) were compared with records from two control groups (12/2018–1/2019 and 12/2021–1/2022) before pandemic. Patients with APAC were included, and the prevalence of APAC and demographic characteristics in Omicron-infected and non-infected patients were compared. RESULTS: Seventy-one (23.43%) out of 303 patients were diagnosed with APAC in the pandemic cohort, which was 2.98 and 2.61 times higher than that in control cohorts (7.87% in 2019, 8.96% in 2022, P<0.001). The pandemic cohort has significantly higher Omicron-infected rate (78.87% vs 0 vs 0; P<0.001), lower proportion of glaucoma history (16.90% vs 42.86% vs 41.67%, P=0.005), higher surgical rate (95.77% vs 83.33% vs 78.57%, P=0.024), higher total medical costs and larger pupil diameter (5.63±0.15 vs 4.68±0.15 vs 4.69±0.22 mm, P<0.01). In 83% Omicron-infected patients, ocular symptoms appeared within 3d after systemic symptoms onset. In multivariate analysis, Omicron infection (P<0.001) was the only independent predictor of pupil diameter. CONCLUSION: In the Omicron epidemic in China, there is an increase of prevalence and severity of APAC, particularly focusing on the first 3d following infection