Rapid, Precise, and High-Sensitivity Acquisition of Paleomagnetic and Rock-Magnetic Data: Development of a Low-Noise Automatic Sample Changing System for Superconducting Rock Magnetometers

Among Earth sciences, paleomagnetism is particularly linked to the statistics of large sample sets as a matter of historical development and logistical necessity. Because the geomagnetic field varies over timescales relevant to sedimentary deposition and igneous intrusion, while the fidelity of recorded magnetization is modulated by original properties of rock units and by alteration histories, "ideal" paleomagnetic results measure remanent magnetizations of hundreds of samples at dozens of progressive demagnetization levels, accompanied by tests of magnetic composition on representative sister specimens. We present an inexpensive, open source system for automating paleomagnetic and rock magnetic measurements. Using vacuum pick-and-place technology and a quartz-glass sample holder, the system can in one hour measure remanent magnetizations, as weak as a few pAm2, of ~30 specimens in two vertical orientations with measurement errors comparable to those of the best manual systems. The system reduces the number of manual manipulations required per specimen ~8 fold

Magnetofossil Spike During the Paleocene-Eocene Thermal Maximum: Ferromagnetic Resonance, Rock Magnetic, and Electron Microscopy Evidence from Ancora, New Jersey, USA

Previous workers identified a magnetically anomalous clay layer deposited on the northern United States Atlantic Coastal Plain during the Paleocene-Eocene Thermal Maximum (PETM). The finding inspired the highly controversial hypothesis that a cometary impact triggered the PETM. Here we present ferromagnetic resonance (FMR), isothermal and anhysteretic remanent magnetization, first order reversal curve, and transmission electron microscopy analyses of late Paleocene and early Eocene sediments in drillcore from Ancora, New Jersey. A novel paleogeographic analysis applying a recent paleomagnetic pole from the Faeroe Islands indicates that New Jersey during the initial Eocene had a ~6-9 degrees lower paleolatitude (~27.3 degrees for Ancora) and a more zonal shoreline trace than in conventional reconstructions. Our investigations of the PETM clay from Ancora reveal abundant magnetite nanoparticles bearing signature traits of crystals produced by magnetotactic bacteria. This result, the first identification of ancient biogenic magnetite using FMR, argues that the anomalous magnetic properties of the PETM sediments are not produced by an impact. They instead reflect environmental changes along the eastern margin of North America during the PETM that led to enhanced production and/or preservation of magnetofossils

Palaeomagnetic analyses of calcified deposits from the Plio-Pleistocene hominid site of Kromdraai, South Africa

Paleomagnetic data are presented for a set of orientated cores from a talus cone at Kromdraai B, a South African cave deposit associated with early Pleistocene fauna including important hominid remains of Paranthropus Australophitecus) robustus. Polarity interpretations of calcified sediments and flowstones suggest that the cave deposits include episodes of deposition that span the Olduvai Event of the Matuyama chron. Results suggest that matrix of the kind associated with the type specimen of robustus (TM 1517) corresponds closely to the beginning of the Olduvai Event, c. 1.9 Myr ag

Geology and geochronology of the Tana Basin, Ethiopia : LIP volcanism, super eruptions and Eocene-Oligocene environmental change

This work was supported by NERC Grants NE/D012996/1 and NER/B/S/2002/00540 and NIGFSC IP/1024/0508.New geological and geochronological data define four episodes of volcanism for the Lake Tana region in the northern Ethiopian portion of the Afro–Arabian Large Igneous Province (LIP): pre-31 Ma flood basalt that yielded a single 40Ar/39Ar age of 34.05 ± 0.54/0.56 Ma; thick and extensive felsic ignimbrites and rhyolites (minimum volume of 2-3 x 103km3) erupted between 31.108 ± 0.020/0.041 Ma and 30.844 ± 0.027/0.046 Ma (U–Pb CA-ID-TIMS zircon ages); mafic volcanism bracketed by 40Ar/39Ar ages of 28.90 ± 0.12/0.14 Ma and 23.75 ± 0.02/0.04 Ma; and localised scoraceous basalt with an 40Ar/39Ar age of 0.033 ± 0.005/0.005 Ma. The felsic volcanism was the product of super eruptions that created a 60–80 km diameter caldera marked by km-scale caldera-collapse fault blocks and a steep-sided basin filled with a minimum of 180 m of sediment and the present-day Lake Tana. These new data enable mapping, with a finer resolution than previously possible, Afro–Arabian LIP volcanism onto the timeline of the Eocene–Oligocene transition and show that neither the mafic nor silicic volcanism coincides directly with perturbations in the geochemical records that span that transition. Our results reinforce the view that it is not the development of a LIP alone but its rate of effusion that contributes to inducing global-scale environmental change.PostprintPeer reviewe

Geochemical fingerprints of seawater in the Late Mesoproterozoic Midcontinent Rift, North America : life at the marine-land divide

The 1.1 Ga Midcontinent Rift (MCR) is a thick volcanic-sedimentary succession that forms a curvilinear belt through central North America and crops out along its northern apex around Lake Superior. Sedimentary units of the MCR have been long interpreted as fluvial-lacustrine and invited a number of studies on the early evolution of life in non-marine habitats. One of the key units is the siliciclastic Nonesuch Formation, thought to record deposition in a large lake. However, recent sedimentological observations indicate the presence of marine incursions. To further test this interpretation, we analysed trace element abundances in a broad suite of samples from multiple drill cores through the Nonesuch Formation. We aimed to differentiate geochemical influences of sediment provenance from post-depositional hydrothermal overprint and thereby identify authigenic enrichments in fluid-mobile elements that are indicators of primary environmental conditions. Our results reveal discrete enrichments in Mo and U in organic- and sulphide-rich horizons, which are most parsimoniously interpreted as marine signatures. This conclusion is supported by Sr/Ba ratios, which suggest mixing between freshwater and saltwater, and by rare cm-thick gypsum in the upper Copper Harbor Formation immediately below the Nonesuch rocks. The gypsum displays δ34S values of +25.9 ± 0.6‰, consistent with input of marine sulphate at least during parts of the basin's history. Collectively, our geochemical data support the sedimentological interpretation that this portion of the MCR archives a marine-influenced estuarine system. Although this conclusion rules out that microbial life documented from the MCR was living in exclusively freshwater habitats, the Nonesuch Fm and associated rocks still hold important clues about organisms that were capable of withstanding salinity gradients and bridging the gap between the marine and non-marine environments of the mid-Proterozoic.PostprintPeer reviewe

Gigantism in unique biogenic magnetite at the Paleocene-Eocene Thermal Maximum

We report the discovery of exceptionally large biogenic magnetite crystals in clay-rich sediments spanning the Paleocene-Eocene Thermal Maximum (PETM) in a borehole at Ancora, New Jersey. Aside from previously-described abundant bacterial magnetofossils, electron microscopy reveals novel spearhead-like and spindle-like magnetite up to 4 μm long and hexaoctahedral prisms up to 1.4 μm long. Similar to magnetite produced by magnetotactic bacteria, these single-crystal particles exhibit chemical composition, lattice perfection, and oxygen isotopes consistent with an aquatic origin. Electron holography indicates single-domain magnetization despite their large crystal size. We suggest that the development of a thick suboxic zone with high iron bioavailability – a product of dramatic changes in weathering and sedimentation patterns driven by severe global warming – drove diversification of magnetite-forming organisms, likely including eukaryotes

Grand Canyon provenance for orthoquartzite clasts in the lower Miocene of coastal southern California

This research was supported by National Science Foundation (NSF) grants EAR 10-19896 and EAR 14-51055 awarded to B. Wernicke, EAR 17-28690 awarded to J. Stock, and OPP 13-41729 awarded to J. Kirschvink. We also acknowledge NSF grant EAR 16-49254 awarded to G. Gehrels at the University of Arizona for support of the Arizona LaserChron Center.Orthoquartzite detrital source regions in the Cordilleran interior yield clast populations with distinct spectra of paleomagnetic inclinations and detrital zircon ages that can be used to trace the provenance of gravels deposited along the western margin of the Cordilleran orogen. An inventory of characteristic remnant magnetizations (CRMs) from >700 sample cores from orthoquartzite source regions defines a low-inclination population of Neoproterozoic-Paleozoic age in the Mojave Desert-Death Valley region (and in correlative strata in Sonora, Mexico) and a moderate- to high-inclination population in the 1.1 Ga Shinumo Formation in eastern Grand Canyon. Detrital zircon ages can be used to distinguish Paleoproterozoic to mid-Mesoproterozoic (1.84-1.20 Ga) clasts derived from the central Arizona highlands region from clasts derived from younger sources that contain late Mesoproterozoic zircons (1.20-1.00 Ga). Characteristic paleomagnetic magnetizations were measured in 44 densely cemented orthoquartzite clasts, sampled from lower Miocene portions of the Sespe Formation in the Santa Monica and Santa Ana mountains and from a middle Eocene section in Simi Valley. Miocene Sespe clast inclinations define a bimodal population with modes near 15 degrees and 45 degrees. Eight samples from the steeper Miocene mode for which detrital zircon spectra were obtained all have spectra with peaks at 1.2, 1.4, and 1.7 Ga. One contains Paleozoic and Mesozoic peaks and is probably Jurassic. The remaining seven define a population of clasts with the distinctive combination of moderate to high inclination and a cosmopolitan age spectrum with abundant grains younger than 1.2 Ga. The moderate to high inclinations rule out a Mojave Desert-Death Valley or Sonoran region source population, and the cosmopolitan detrital zircon spectra rule out a central Arizona highlands source population. The Shinumo Formation, presently exposed only within a few hundred meters elevation of the bottom of eastern Grand Canyon, thus remains the only plausible, known source for the moderate- to high-inclination clast population. If so, then the Upper Granite Gorge of the eastern Grand Canyon had been eroded to within a few hundred meters of its current depth by early Miocene time (ca. 20 Ma). Such an unroofing event in the eastern Grand Canyon region is independently confirmed by (U-Th)/He thermochronology. Inclusion of the eastern Grand Canyon region in the Sespe drainage system is also independently supported by detrital zircon age spectra of Sespe sandstones. Collectively, these data define a mid-Tertiary, SW-flowing "Arizona River" drainage system between the rapidly eroding eastern Grand Canyon region and coastal California.Publisher PDFPeer reviewe

High-Resolution Late Devonian Magnetostratigraphy From the Canning Basin, Western Australia: A Re-Evaluation

Late Devonian time was a period of rapid upheaval in the Earth system, including climate change, sea level changes, widespread ocean anoxia, and the Frasnian-Famennian mass extinction; the cause(s) of these changes remain(s) uncertain. The Lennard Shelf of the Canning Basin in Western Australia contains carbonate reef sections spanning much of the Late Devonian Epoch and has been sampled for paleomagnetic analysis with studies by Hansma and colleagues in 2015 and Playton and colleagues in 2016. However, previous paleomagnetic directions were scattered and their use for magnetostratigraphy has been questioned. Here, rock magnetic data and magnetostratigraphy for a late Devonian drill-core from the Lennard Shelf were analyzed. Three magnetostratigraphic interpretations were made using different paleopoles that showed good correlation with each other and the earlier interpretations by Playton and colleagues in 2016. Additionally, the rock magnetic data revealed the samples contain various mixtures of detrital and diagenetic minerals, the former of which should be viable recorders of primary magnetic signatures. Even in samples with these detrital phases, paleomagnetic data were often noisy and produced ambiguous polarity assignments, likely due to the anomalously weak Devonian field. Because of this ambiguity and the absence of a robust paleopole, broader correlations for this critical time-period will be difficult without additional paleomagnetic data from the late Devonian Period. Expanded data for this interval could eventually shed light on the timing, causes, and rates of the Frasnian-Famennian mass extinction and other environmental shifts in the late Devonian Epoch

Carbonate assemblages in Cold Bokkeveld CM chondrite reveal complex parent body evolution

Funder: Royal Astronomical Society; Id: http://dx.doi.org/10.13039/501100000698Abstract: The paragenesis of carbonates in the Cold Bokkeveld CM chondrite is determined from a detailed petrographic, chemical, spectroscopic, and isotopic study of nine associations of carbonates (aragonite, calcite, and dolomite) with other secondary minerals that occur within the meteorite. Our study reveals the existence of carbonates displaying petrographic features that are distinct from those of type 1 and type 2 carbonates commonly observed in CM2 meteorites. These include carbonates interstitial to octahedral magnetite crystals, for which a new designation of “type 1c” is suggested. The O isotopic values of dolomite (δ18O ranging from +21.1 to +25.8‰ and Δ17O from −4.9 to −4.0‰) are similar to those measured in dolomites from other CM chondrites. The presence of complex carbonates with a CaCO3 core and Mg‐enriched rim implies several generations of fluids and/or their evolving composition on the CM parent body(ies). Petrographic characteristics indicate at least six stages of potentially overlapping carbonate and phyllosilicate formation events. We show that type 1 and type 2 calcite have distinct Raman spectral characteristics. Type 1 calcite is characterized by very broad peaks, whereas type 2 calcite displays narrow peaks similar to those of typical abiotic terrestrial calcite, suggesting high crystallinity. A carbonate Raman spectrum showing features characteristic of both aragonite and calcite likely documents an aragonite‐calcite phase transition. Raman spectroscopy also reveals the presence of organic matter in the majority of carbonates. This indicates that organic carbon was mobilized by aqueous fluids for extended periods

An Appalachian Amazon? Magnetofossil evidence for the development of a tropical river-like system in the mid-Atlantic United States during the Paleocene-Eocene thermal maximum

On the mid-Atlantic Coastal Plain of the United States, Paleocene sands and silts are replaced during the Paleocene-Eocene Thermal Maximum (PETM) by the kaolinite-rich Marlboro Clay. The clay preserves abundant magnetite produced by magnetotactic bacteria and novel, presumptively eukaryotic, iron-biomineralizing microorganisms. Using ferromagnetic resonance spectroscopy and electron microscopy, we map the magnetofossil distribution in the context of stratigraphy and carbon isotope data and identify three magnetic facies in the clay: one characterized by a mix of detrital particles and magnetofossils, a second with a higher magnetofossil-to-detrital ratio, and a third with only transient magnetofossils. The distribution of these facies suggests that suboxic conditions promoting magnetofossil production and preservation occurred throughout inner middle neritic sediments of the Salisbury Embayment but extended only transiently to outer neritic sediments and the flanks of the embayment. Such a distribution is consistent with the development of a system resembling a modern tropical river-dominated shelf